The use of three physico-chemical methods in the study of the organic matter associated with the sedimentary phosphorites in Djebel Onk Basin, Algeria

The study of the organic matter (OM) associated with the phosphate ore of Kef Essennoun deposit (Djebel Onk mining basin, Algeria) was with a view to determine the decomposition degree of the OM within the pellets and the matrix, and the conditions of diagenesis. The sedimentary phosphates of this deposit are constituted of sub-rounded, phosphate-rich grains (pellets) dispersed in a surrounding, much poorer than pellets in P, matrix (or gangue). The survey of the OM associated with both pellets and matrix used several types of analyses: scanning electron microscopy (SEM), scanning electron microscope with energy-dispersive X-ray analysis, Fourier transform infrared spectroscopy and nuclear magnetic resonance spectroscopy. The results show the OM, dispersed approximately homogeneously, in the form of large flat particles, within the gangue and within the phosphatic pellets in the form of small particles. The O/C ratio showed that the OM is more oxidised in the matrix than within the pellets. The oxidation increased with the phosphatisation rate of the pellets and more with the carbonation rate of the matrix, but it decreased with the silicification degree in the siliceous carbonated matrix. Two major functional classes were distinguished within pellets: aliphatic and oxygenated ones, the latter being fundamentally present in humic OM. The presence and abundance of these humic compounds in pelletal phosphorites are known from the 1980s and considered as witnessing a formation of apatite in a strictly closed environment, inside the pellet.     

Ground roll attenuation using the S and x-f-k transforms

Ground roll, which is characterized by low frequency and high amplitude, is an old seismic data processing problem in land‐based seismic acquisition. Common techniques for ground roll attenuation are frequency filtering, f‐k or velocity filtering and a type of f‐k filtering based on the time‐offset windowed Fourier transform. These techniques assume that the seismic signal is stationary. In this study we utilized the S, x‐f‐k and t‐f‐k transforms as alternative methods to the Fourier transform. The S transform is a type of time‐frequency transform that provides frequency‐dependent resolution while maintaining a direct relationship with the Fourier spectrum. Application of a filter based on the S transform to land seismic shot records attenuates ground roll in a time‐frequency domain. The t‐f‐k and x‐f‐k transforms are approaches to localize the apparent velocity panel of a seismic record in time and offset domains, respectively. These transforms provide a convenient way to define offset or time‐varying reject zones on the separate f‐k panel at different offsets or times.     

Simple formulas for the dynamic stiffness of pile groups

Simple formulas are derived for the dynamic stiffness of pile group foundations subjected to horizontal and rocking dynamic loads. The formulations are based on the construction of a general model of impedance matrices as the condensation of matrices of mass, damping, and stiffness, and on the identification of the values of these matrices on an extensive database of numerical experiments computed using coupled finite element–boundary element models. The formulations obtained can be readily used for the design of both floating piles on homogeneous half‐space and end‐bearing piles and are applicable for a wide range of mechanical and geometrical parameters of the soil and piles, in particular for large pile groups. For the seismic design of a building, the use of the simple formulas rather than a full computational model is shown to induce little error on the evaluation of the response spectra and time histories. Copyright © 2009 John Wiley & Sons, Ltd.     

Shake table study on an ordinary low‐rise building seismically isolated with SU‐FREIs (stable unbonded‐fiber reinforced elastomeric isolators)

This paper reports on the investigation of novel fiber reinforced elastomeric isolator (FREI) bearings, which do not have thick end plates, and are used in an unbonded application. Owing to the stable lateral load‐displacement response exhibited by the unbonded FREI bearings, the proposed bearings are referred to as stable unbonded (SU)‐FREIs. A shake table test program was conducted on a two‐story test‐structure having well‐defined elastic response characteristics. Compared with the results for the corresponding fixed base (FB) structure, the peak response values, distribution of lateral response throughout the height of the structure, and response time histories of the tested base isolated (BI) structure indicate that significantly improved response can be achieved. This study clearly indicates that SU‐FREI bearings can provide an effective seismic isolation system. Copyright © 2009 John Wiley & Sons, Ltd.     

绿洲耕地变化趋势及其驱动力——塔里木盆地南部策勒绿洲为例

以多年的野外实地调查资料和统计资料,分析了塔里木盆地南部策勒绿洲50年以来耕地面积变化的总体趋势、空间差异和驱动因子。基于GPS现场定位,应用GIS进行空间分析,通过建立多元回归模型,最终对该绿洲2010年和2020年的耕地数量进行了初步的预测。分析结果表明社会经济发展动态、农业科技进步和水土资源的限制等3大类因素是影响耕地数量的3个主成分,其结果将为进一步研究整个塔里木盆地南部绿洲耕地变化提供借鉴,为合理利用和保护耕地、为干旱区可持续发展提供科学依据。     

Imagery in the Presence of Turbulence Using Slit Aperture Telescope With Partial Adaptive Corrections

The objective of this communication is to study and totest numerically the concept of partial adaptive correction with arotating Slit Aperture Telescope (SAT). After a brief summary of theprinciple of image reconstruction with the rotating SAT operating withoutthe atmospheric turbulence, we describe the simulations of imagereconstruction when a partial atmospheric correction is performed in onedimension only, along the long axis of the rotating SAT. Thereconstruction algorithm performs the inversion of the Radon transform.The SAT can use a small adaptive optics system with far fewer actuatorsthan conventional two-dimensional devices, but a relatively high degree ofone-dimensional correction is needed to recover a satisfactorytwo-dimensional image. The effect of additive noise on the reconstructedimage is also investigated.     

Predicting TBM penetration rate in hard rock condition: A comparative study among six XGB-based metaheuristic techniques

A reliable and accurate prediction of the tunnel boring machine(TBM) performance can assist in minimizing the relevant risks of high capital costs and in scheduling tunneling projects.This research aims to develop six hybrid models of extreme gradient boosting(XGB) which are optimized by gray wolf optimization(GWO), particle swarm optimization(PSO), social spider optimization(SSO), sine cosine algorithm(SCA), multi verse optimization(MVO) and moth flame optimization(MFO), for estimation of the TBM penetration rate(PR).To do this, a comprehensive database with 1286 data samples was established where seven parameters including the rock quality designation, the rock mass rating, Brazilian tensile strength(BTS), rock mass weathering, the uniaxial compressive strength(UCS), revolution per minute and trust force per cutter(TFC), were set as inputs and TBM PR was selected as model output.Together with the mentioned six hybrid models, four single models i.e., artificial neural network, random forest regression, XGB and support vector regression were also built to estimate TBM PR for comparison purposes.These models were designed conducting several parametric studies on their most important parameters and then, their performance capacities were assessed through the use of root mean square error, coefficient of determination, mean absolute percentage error, and a10-index.Results of this study confirmed that the best predictive model of PR goes to the PSO-XGB technique with system error of(0.1453, and 0.1325), R~2 of(0.951, and 0.951), mean absolute percentage error(4.0689, and 3.8115), and a10-index of(0.9348, and 0.9496) in training and testing phases, respectively.The developed hybrid PSO-XGB can be introduced as an accurate, powerful and applicable technique in the field of TBM performance prediction.By conducting sensitivity analysis, it was found that UCS, BTS and TFC have the deepest impacts on the TBM PR.     

Application of multivariate statistical methods to indicate the origin and geochemical behavior of potentially hazardous elements in sediment around the Sarcheshmeh copper mine,SE Iran

Multivariate statistical techniques, i.e., correlation coefficient analysis, principal components analysis (PCA), and hierarchical cluster analysis (CA), were applied to the total and water-soluble concentrations of potentially hazardous metals in sediments associated with the Sarcheshmeh mine, one of the largest Oligo-Miocene porphyry copper deposits in the world. The samples were analyzed for hazardous metal concentration levels by inductively coupled plasma mass spectrometry method. Results indicate that the contaminant metals As, Cd, Cu, Mo, S, Sb, Sn, Se, Pb, and Zn were positively correlated with the total concentrations. These hazardous metals also have strong association in the PCA and CA results. Different anthropic versus natural sources of contaminant metals were distinguished by using CA method. Water-soluble fraction of hazardous metals showed that the hydro-geochemical behavior of these metals in sediments is different considerably. Elements such as Cd, Co, Cr, Cu, Fe, Mn, Ni, S, and Zn are readily water soluble from contaminated samples, especially from evaporative mineral phases, while the release of As, Mo, Sb, and Pb into the water is limited by adsorption processes. Results obtained from the application of multivariate techniques on the water-soluble fraction data set show that the hazardous metals are categorized into three groups including (1) Ni, S, Co, Cu, Cr, and Fe; (2) Se, Mn, Cd, and Zn; and (3) Sb, As, Mo, and Sn. This classification describes the hydro-geochemical behavior of hazardous metals in water–sediment environments of the Sarcheshmeh porphyry copper mine and can be used as a basis in remedial and treatment strategies.     

Ionic conductivity in gem-quality single-crystal alkali feldspar from the Eifel: temperature,orientation and composition dependence

We measured the ion conductivity of single-crystal alkali feldspar originating from two different locations in the Eifel/Germany, named Volkesfeld and Rockeskyller sanidine and having potassium site fractions \(C_\mathrm{K}\) of 0.83 and 0.71, respectively. The dc conductivities resulting from electrochemical impedance spectroscopy over the temperature range of 300–900 \(^{\circ }\hbox {C}\) show a weak composition dependence but pronounced differences between the b-direction [\(\perp (010)\)] and \(c^{*}\)-direction [\(\perp (001)\)] of the monoclinic feldspar structure. Conductivity activation energies obtained from the observed linear Arrhenius plots are close to 1.2 eV in all cases, which is closely similar to the activation energies of the \(^{22}\mathrm{Na}\) tracer diffusivity in the same crystals. Taking into account literature data on K tracer diffusion and diffusion correlation effects, the present results point to a predominance of the interstitialcy mechanism over the vacancy mechanism in mass and charge transport on the alkali sublattice in potassium-rich alkali feldspar.     

Estimation of sediment load and erosion of different geological units: A case study from a basin of north-eastern Iran

Erosion of geological units and sediment load in rivers can be considered as the serious problems in recent decades.Increasing sediment loads generate major hazards for water resources development,particularly in terms of loss of reservoir storage due to sedimentation and siltation of water distribution systems.In this paper,the performance of four sediment rating curve (SRC) development methods was evaluated for the Shirin Darreh River(SDR) basin (1750 km2),located in North Khorasan Province,Iran.Data of flow discharge (Q) and suspended sediment flux (SSF)(Q-SSF pairs,N=957)and daily flow discharge,recorded by the Regional Water Company of North Khorasan (RWCNK) at the Qaleh-Barbar (QB) gauging site during 1989-2018were used.The flow discharge classification method performed best by meeting the desired criteria of most statistical indices,including normalized root mean square error (NRMSE),mean bias error (MBE),mean absolute error (MAE),index of agreement (d),and coefficient of determination (R~2).Based on the optimized method,the rate of suspended sediment transportation at the study site was estimated about2.7×10~6 ton year~(-1).Erodibility of the exposed formations in the study area was estimated based on a factorial scoring model (FSM).Three indices,focused on the outcrop and erodibility,were calculated for the geological units at sub-basin and total scales.Marl deposits are the most extensive geological unit in the three sub-basins and the maximum formation outcrop ratio (FOR) and participation in erosion (PCE)were obtained for these rocks at total scale.In fact,marl unit can be regarded as the main source to supply the suspended sediments in the study basin.