Mutual replacement reactions in alkali feldspars I: microtextures and mechanisms

Intracrystal microtextures formed by a process of mutual replacement in alkali feldspars record fluid–rock reactions that have affected large volumes of the Earth’s crust. Regular, ≤1 μm-scale ‘strain-controlled’ perthitic microtextures coarsen, by up to 10³, by a dissolution–reprecipitation process, producing microporous patch or vein perthites on scales >100 μm. We have developed earlier studies of such reactions in alkali feldspar cm-scale primocrysts in layered syenites from the Klokken intrusion, South Greenland. We present new hyperspectral CL, SEM images, and laser ICPMS analytical data, and discuss the mechanism of such replacement reactions. The feldspars grew as homogeneous sodic sanidines which unmixed and ordered by volume diffusion during cooling into the microcline field at ~450°C, giving regular, fully coherent ‘braid’ cryptoperthite. At ≤450°C the crystals reacted with a circulating post-magmatic aqueous fluid. The braid perthite behaved as a single reactant ‘phase’ which was replaced by two product phases, incoherent subgrains of low albite and microcline, with micropores at their boundaries. The driving force for the reactions was coherency strain energy, which was greater than the surface energy in the subgrain mosaic. The external euhedral crystal shapes and bulk major element composition of the primocrysts were unchanged but they became largely pseudomorphs composed of subgrains usually with the ‘pericline’ and ‘adularia’ habits (dominant {110} and subordinate {010} morphology) characteristic of low T growth. The subgrains have an epitactic relationship with parent braid perthite. Individual subgrains show oscillatory zoning in CL intensity, mainly at blue wavelengths, which correlates with tetrahedral Ti. Regular zoning is sometimes truncated by irregular, discordant surfaces suggesting dissolution, followed by resumption of growth giving regular zoning. Zones can be traced through touching subgrains, of both albite and microcline, for distances up to ~500 μm. At ≤340°C, the microcline subgrains underwent a third stage of unmixing to give straight lamellar film perthites with periodicities of ~1 μm, which with further cooling became semicoherent by the development of spaced misfit dislocations. Sub-grain growth occurred in fluid films that advanced through the elastically strained braid perthite crystals, which dissolved irreversibly. Braid perthite was more soluble than the strain-free subgrain mosaics which precipitated from the supersaturated solution. Some volumes of braid texture have sharp surfaces that suggest rapid dissolution along planes with low surface energies. Others have complex, diffuse boundaries that indicate a phase of coherent lamellar straightening by volume diffusion in response to strain relief close to a slowly advancing interface. Nucleation of strain-free subgrains was the overall rate-limiting step. To minimise surface energy subgrains grew with low energy morphologies and coarsened by grain growth, in fluid films whose trace element load (reflected in the oscillatory zoning) was dictated by the competitive advance of subgrains over a range of a few tens of mm. The cross-cutting dissolution surfaces suggest influxes of fresh fluid. Removal of feldspar to give 2 vol% porosity would require a feldspar:fluid ratio of ~1:26 (by wt). The late reversion to strain-controlled exsolution in microcline subgrains is consistent with loss of fluid above 340°C following depressurization of the intrusion. A second paper (Part II) describes trace element partitioning between the albite and microcline subgrains, and discusses the potential of trace elements as a low-T geothermometer. This paper and the Part II are dedicated in memory of J.V. Smith and W.L. Brown, both of whom died in 2007, in acknowledgement of their unrivalled contributions to the study of the feldspar minerals over more than half a century.     

Assimilation of Indian Doppler Weather Radar observations for simulation of mesoscale features of a land-falling cyclone

In this paper, impact of Indian Doppler Weather Radar (DWR) data, i.e., reflectivity (Z), radial velocity (Vr) data individually and in combination has been examined for simulation of mesoscale features of a land-falling cyclone with Advance Regional Prediction System (ARPS) Model at 9-km horizontal resolution. The radial velocity and reflectivity observations from DWR station, Chennai (lat. 13.0°N and long. 80.0°E), are assimilated using the ARPS Data Assimilation System (ADAS) and cloud analysis scheme of the model. The case selected for this study is the Bay of Bengal tropical cyclone NISHA of 27–28 November 2008. The study shows that the ARPS model with the assimilation of radial wind and reflectivity observations of DWR, Chennai, could simulate mesoscale characteristics, such as number of cells, spiral rain band structure, location of the center and strengthening of the lower tropospheric winds associated with the land-falling cyclone NISHA. The evolution of 850 hPa wind field super-imposed vorticity reveals that the forecast is improved in terms of the magnitude and direction of lower tropospheric wind, time, and location of cyclone in the experiment when both radial wind and reflectivity observations are used. With the assimilation of both radial wind and reflectivity observations, model could reproduce the rainfall pattern in a more realistic way. The results of this study are found to be very promising toward improving the short-range mesoscale forecasts.     

Multifunctional intervention and market rationality in agricultural governance: a comparative study of England and South Australia

Critiques of the neoliberal governance of agricultural systems have led to a number of political responses which attempt to address the socio-environmental consequences of the dominant regime. In this paper two case study regions (South Australia and England) have been chosen to represent variations in agricultural policy and to highlight subsequent outcomes on the sustainability of agriculture. Interviewed governance stakeholders highlighted issues in regard to the agricultural governance of each area, from social and environmental consequences of minimal policy intervention in South Australia, to issues created by greater economic support in England. As such, the distinct variations in agricultural regimes will continue to demand scholarly attention, in order for the value of diversity within the sector to be more widely understood. The study concludes that it is likely agricultural support will continue to decline in both case study regions. Importantly, however, innovative policy mechanisms that aim to reduce local risks and value local agricultural priorities, without requiring significant financial support, might be the most promising way forward in regard to agricultural system sustainability.     

Reduction of future disaster damages by learning from disaster experiences

This paper examines the effect of a country’s own past disaster experiences and nearby countries’ past experiences on subsequent disaster damage. We use global disaster data from 1990 to 2010, which include disaster-related death tolls for both natural and technological disasters that are further divided into sub-categories. Overall, we find evidence of a reduction effect of past disaster damage on future disaster damage. More detailed analyses show that an adaptation effect seems to be present for certain combinations of disaster types and levels of economic development. The results show that a country’s own experiences reduce future damage for natural disasters but that the marginal effect is larger for lower-income countries. On the other hand, for technological disasters, a robust impact of experiences was found only in higher-income countries. In terms of the disaster experiences of nearby countries, the adaptation effect was found only for natural disasters, and the marginal impact was relatively higher for higher-income countries.     

Tsunami hazard in the Eastern Mediterranean: strong earthquakes and tsunamis in Cyprus and the Levantine Sea

A modern tsunami catalogue has been compiled for the region of Cyprus-Levantine Sea in which 24 certain or possible local tsunamis are listed from antiquity up to the present time, while six regional tsunamis, generated in the Hellenic arc, are documented which affected the region. Another set of 13 doubtful events not included in the catalogue are discussed. Tsunami intensities k and K were re-evaluated using the classic 6-grade and the new 12-grade intensity scales, respectively. The strongest tsunamis reported in the region of interest are those of 551 AD, 749, 1068, 1201, 1222, 1546 and 1759, all occurring along the Levantine coast from Gaza northward, with the exception of the 1222 wave which occurred in the Cyprean arc. The causative earthquakes, however, occur on land and are associated with the left-lateral strike-slip Levantine rift and, as such, remain unexplained. In this paper we speculate on the mechanism of these events. A second tsunami zone follows the Cyprean arc, where the situation of subaqueous seismogenic sources favours the generation of tsunamis by co-seismic fault displacements. Submarine or coastal earth slumping, however, may be an additional tsunamigenic component. Based on historical data, the average tsunami recurrence in the Cyprus-Levantine Sea region is roughly estimated to be around 30 years, 120 years and 375 years for moderate (k/K ≥ 2/3), strong (k/K ≥ 3/5) and very strong (k/K ≥ 5/8) events, respectively. The rate of tsunami occurrence equals 0.033, 8.3 × 10⁻³ and 2.7 × 10⁻³ events/year for intensity k/K ≥ 2/3, 3/5 and 5/8, respectively. For a Poissonian (random) process the probabilities of observing at least one moderate, strong or very strong tsunami are 0.28, 0.01 and 3 × 10⁻³ within 1 year, 0.81, 0.34 and 0.13 within 50 years and 0.96, 0.56 and 0.24 within 100 years, respectively. The tsunami potential in the Cyprus-Levantine Sea area is low relative to other Mediterranean tsunamigenic regions. However, the destructiveness of some historical events indicates the need to evaluate tsunami hazard by all available means. In addition, remote tsunamigenic sources, such as those of 1303 and 1481 in the eastern Hellenic arc, are able to threaten the coasts of the Cyprus-Levantine region and, therefore, such regional tsunamis should be taken into account in the evaluation of the tsunami risk of the region.     

3-D GRACE gravity model for the 2011 Japan earthquake

The GRACE mission has contributed to the seismic characterization of major earthquakes in offshore regions of the world. Here, we isolate satellite gravity signal (μGal range) for the Japan Earthquake of 2011 using a difference method. Contrary to the existing gravity models, we propose a unit vertical pyramid based five-layer 3-D thrust fault model, which extends to the hypocenter and honors the ocean water layer and sea floor upheaval also. Our model partly uses existing seismological information (hypocenter depth of 32 km, rupture length of 300 km and vertical slip of 4 m), provides a snapshot of episodic subduction of the Pacific Plate below the Atlantic Plate and its gravity response closely matches the observed gravity (RMS error of 3.4012×10^?13μGal), fully accounting for co-seismic mass redistribution including sea surface deformation. Our inferred rupture length, rupture velocity, average seismic moment magnitude and momentum, respectively, are 300 km, 4.49 km/s, 1.152×10²¹?1.8816×10²¹ N m and 2.319×10⁶ GNs, which fairly agree with the literature. Further, our model inferred momentum at the sea floor corresponds to an area pulse that led to Tsunami generation.     

Decadal Changes in Water Quality and Net Productivity of a Shallow Danish Estuary Following Significant Nutrient Reductions

We utilized an extensive data set (1977–2013) from a water quality monitoring program to investigate the recovery of a Danish estuary following large reductions in total phosphorus (TP) and total nitrogen (TN) loading. Monthly rates of net transport and biogeochemical transformation of dissolved inorganic nitrogen (DIN) and phosphorus (DIP) were computed in two basins of the estuary using a box model approach, and oxygen-based rates of net ecosystem production (NEP) were determined. Since 1990, nutrient loading was reduced by 58 % for nitrogen and 80 % for phosphorus, causing significant decreases in DIN (60 %) and DIP (85 %) concentrations. Reductions in nutrient loadings and concentrations reduced annual chlorophyll levels by 50 % in the inner estuary and improved Secchi depth by approximately 1 m during the same period, particularly in the summer period. In the outer, deeper region of the estuary trends in water quality was less evident. Improvements in the inner estuary were strongly coupled to declines in DIN. Thresholds of DIN and DIP concentrations limiting phytoplankton growth indicated that both regions of the estuary were nitrogen limited. NEP rates indicated the development of more net autotrophic conditions over time that were likely associated with higher benthic primary production stimulated by improved light conditions. Box model computations revealed a modest reduction in summer net production of DIP over time, despite the persistence of elevated fluxes for several years after external loads were reduced. Since the mid-1990s, nutrient loading and transformation were stable while nutrient concentrations continued to decline and water quality improved in the inner estuary. The oligotrophication trajectory involved an initial fast transformation and modest retention of nutrients followed by a gradual decline in the rate of improvement towards a new stable condition.     

Regional modeling of dust storm of February 8, 2015 in the southwest of Iran

According to World Meteorological Organization report in 2015, the southwest of Iran has become one of the dust sources in the region. And the objective of this research is to study the dust storms originating in this region. For this purpose, based on the weather data of 14 stations, the dust storms of the region were investigated, and the dust storm of February 7, 2015, was selected due to its very high concentration of dust particles (66 times the normal values). For the analysis of source areas and storm paths, the FNL data was used. The regional models of Navy Aerosol Analysis and Prediction System (NAAPS), Barcelona Supercomputing Centre-Dust Regional Atmospheric Model 8b (DREAM 8b), Non-hydrostatic Multiscale Model Barcelona Supercomputing Center (NMMB/BSC), and hybrid single-particle Lagrangian integrated trajectory (HYSPLIT) were used to study and analyze the selected storm. The results showed that the dust event in February 8, 2016, has been the result of the polar front jet stream (PJF) caused by western immigrant system that had been over the Sahara in Africa, the deserts of Iraq, Syria, Saudi Arabia, and finally southwest of Iran in making the extreme dust event. According to the Moderate Resolution Imaging Spectroradiometer data and point models of NAAPS, optical depth was very high. The DREAM 8b and NMMB/BSC models confirmed the impact of the local factors and closeness to the dust source regions. The backward tracking of the model with the HYSPLIT model showed three tracks transporting the dust particles to the region. This software also showed that the dust particles occupied an atmospheric tunnel of 1.5 km in diameter.     

Review of water and soil contamination in and around Salihli geothermal field (Manisa,Turkey)

The town of Salihli is situated in Gediz Graben in the western Anatolia. This region is important in terms of industry, mining, geothermal energy, water sources, and agricultural production. Geothermal flow and anthropogenic activities in Salihli threaten the surrounding environment due to the contamination of cold groundwater, surface water, and soil. The goal of the present study is to determine the environmental effects of the geothermal and anthropogenic activities in Salihli on soil, stream sediments, and water. Stream sediments and farm soil have been contaminated by substances derived from geothermal and industrial effluents. To this end, the quality review of the water was completed and the heavy metal levels in stream sediment samples were measured to determine the extent of contamination. The elements As, B, Br, Fe, and Ni are the major contaminants present in surface water and groundwater in the study area. The concentrations of these elements excess tolerance limits of international water standards. Gibbsite, K-mica, kaolinite, sepiolite, halite, sulfur, willemite, and Pb(OH)₂ might be precipitated as scales at low temperatures on the soil; this could be interpreted as a resultant from soil contamination. The concentrations of 17 elements (As, Ba, B, Cd, Co, Cr, Cu, Fe, Hg, Li, Mo, Mn, Ni, Pb, Sb, Sr, and Zn) were measured in samples from stream sediments and surface soils. In the study area, especially geothermal and anthropogenic activities give rise to environmental pollution.