Groundwater investigation in the southern part of Gabes using resistivity sounding, southern Tunisia

The groundwater hydrogeology of southern Tunisia emphasizes two main groundwater bodies so-called Zeuss-Koutine and south Gabes. These groundwater bodies yielding economically important storage of useful water present complex internal architecture and heterogeneity allowing exchange flows throughout permeable or/and fractured bodies. A geophysical survey using resistivity soundings was carried out along this area to describe in detail the field structure and the 3D extent of these groundwater bodies by the hydrogeological new data and detailed subsurface mapping based on resistivity sounding and seismic data. This survey discusses also the potentialities of some permeable layer in water storage and purposes potential favorable areas for optimum groundwater mining.     

Anhydrite pseudomorphs and the origin of stratiform Cu–Co ores in the Katangan Copperbelt (Democratic Republic of Congo)

The stratiform Cu–Co ore mineralisation in the Katangan Copperbelt consists of dispersed sulphides and sulphides in nodules and lenses, which are often pseudomorphs after evaporites. Two types of pseudomorphs can be distinguished in the nodules and lenses. In type 1 examples, dolomite precipitated first and was subsequently replaced by Cu–Co sulphides and authigenic quartz, whereas in type 2 examples, authigenic quartz and Cu–Co sulphides precipitated prior to dolomite and are coarse-grained. The sulphur isotopic composition of the copper–cobalt sulphides in the type 1 pseudomorphs is between −10.3 and 3.1‰ relative to the Vienna Canyon Diablo Troilite, indicating that the sulphide component was derived from bacterial sulphate reduction (BSR). The generation of during this process caused the precipitation and replacement of anhydrite by dolomite. A second product of BSR is the generation of H₂S, resulting in the precipitation of Cu–Co sulphides from the mineralising fluids. Initial sulphide precipitation occurred along the rim of the pseudomorphs and continued towards the core. Precipitation of authigenic quartz was most likely induced by a pH decrease during sulphide precipitation. Fluid inclusion data from quartz indicate the presence of a high-salinity (8–18 eq. wt.% NaCl) fluid, possibly derived from evaporated seawater which migrated through the deep subsurface. ⁸⁷Sr/⁸⁶Sr ratios of dolomite in type 1 nodules range between 0.71012 and 0.73576, significantly more radiogenic than the strontium isotopic composition of Neoproterozoic marine carbonates (⁸⁷Sr/⁸⁶Sr = 0.7056–0.7087). This suggests intense interaction with siliciclastic sedimentary rocks and/or the granitic basement. The low carbon isotopic composition of the dolomite in the pseudomorphs (−7.02 and −9.93‰ relative to the Vienna Pee Dee Belemnite, V-PDB) compared to the host rock dolomite (−4.90 and +1.31‰ V-PDB) resulted from the oxidation of organic matter during BSR.     

One-dimensional consolidation of soil under multistage load based on continuous drainage boundary

In engineering practice, a rapid loading rate can result in ground failure when the strength of soft soils is relatively low, and a multistage loading scheme is always utilized to deal with this situation. Firstly, under a multistage load and the continuous drainage boundary, an analytical solution of excess pore-water pressure and consolidation degree is obtained by virtue of the superposition formula of excess pore-water pressure, and a more general continuous drainage boundary under arbitrary time-dependent load is developed. Then, a comparison with existing analytical solutions is conducted to verify the present solution. A preliminary attempt on applying the continuous drainage boundary into the finite element model is made, and the feasibility of the numerical model for the one-dimensional consolidation under the continuous drainage boundary is verified by comparing the results calculated by FEM with that from present analytical solution. Finally, the consolidation behavior of soil is investigated in detail for different int erface parameters or loading scheme. The results show that, in land reclamation projects, a horizontal drain should be placed close to the boundary with a smaller interface parameter to improve the consolidation efficiency. The degree of consolidation is also related to the applied time-dependent load and interface parameters.     

Threshold of motion of bivalve and gastropod shells under oscillatory flow in flume experiments

The threshold of motion of non-fragmented mollusc shells was studied for the first time under oscillatory flow. In this regard, flume experiments were used to investigate the threshold of motion of three bivalve and three gastropod species, two typical mollusc classes of coastal coquina deposits. The sieve diameters ranged from 2·0 to 15·9 mm. These experiments were performed on a flat-bottom setup under regular non-breaking waves (swell) produced by a flap-type wave generator. The critical Shields values for each species of mollusc were plotted against the sieve and nominal diameter. Moreover, the dimensionless Corey shape factor of the shells was evaluated in order to investigate the effect of mollusc shell shapes on the threshold of motion. According to their critical Shields parameter, the mollusc threshold data under oscillatory flow present smaller values than the siliciclastic sediments when considering their sieve diameter. In addition, the mollusc datasets are below the empirical curves built from siliciclastic grain data under current and waves. When considering the nominal diameter, the critical Shields parameter increases and the mollusc data are closer to siliciclastic sediments. Bivalves, which have a flat-concave shape (form factor: 0·27 to 0·37), have a higher critical Shields parameter for smaller particles and more uniform datasets than the gastropod scattered data, which have a rounded shape (form factor: 0·58 to 0·62) and have varied morphologies (ellipsoidal, conical and cubic). The comparison between previous current-driven threshold data of bioclastic sediment motion and the data of mollusc whole shells under oscillatory flow shows a fair correlation on the Shields diagram, in which all datasets are below the mean empirical curves for siliciclastic sediments. These findings indicate that the shape effect on the transport initiation is predominant for smaller shells. The use of the nominal diameter is satisfactory to improve the bioclastic and siliciclastic data correlation.     

Contribution of remote sensing and GIS to analysis of the risk of flooding in the Zat basin (High Atlas-Morocco)

Natural Hazards - Despite the controversy regarding their use, school buildings are often assigned as emergency evacuation shelters, temporary accommodation and aid distribution hubs following...     

A comparative study of four vulnerability mapping methods in a detritic aquifer under mediterranean climatic conditions

This paper presents the results of a comparative study relating to the application of four vulnerability mapping methods, GOD, AVI, DRASTIC and SINTACS, in a pilot detritic aquifer situated in NW Morocco, known as the Martil–Alila aquifer. The principal objective of this work is to determine the most suitable such methods for this aquifer type within a Mediterranean context, and to show the effect of the rainfall variations that are characteristic of the Mediterranean climate on the degree of vulnerability. The methods applied distinguish five classes of vulnerability, these being irregularly divided up in space, with the division varying according to the method in question. The vulnerability maps obtained by the different methods strongly suggest that the eastern half of the aquifer is more vulnerable to contamination than the western half, for all hydrological situations. The effect of climatic conditions on the degree of vulnerability is well represented by the DRASTIC, according to which the aquifer is moderately to strongly vulnerable during humid hydrological years and weakly to moderately vulnerable during dry ones. For the other methods, this climatic effect is limited to the area occupied by the two predominant classes (“High” and “Low” for GOD and “High” and “Moderate” for SINTACS) while it is null for AVI. In conclusion, DRASTIC appears the most suitable for mapping the vulnerability to contamination of Mediterranean coastal detritic aquifers such as the Martil–Alila aquifer.     

Platinum group minerals in podiform chromitites of the Bou Azzer ophiolite, Anti Atlas, Central Morocco

Summary The Neoproterozoic Bou Azzer ophiolite complex hosts numerous, small lenticular bodies of massive and disseminated chromite. Metallurgical-grade high-Mg and high-Cr spinels (cores with 48–62 wt% Cr₂O₃) reveal complex alteration patterns of successive Cr and Mn enrichment and loss of Al towards the rims, while the Mg# ratios [(Mg/(Mg + Fe²⁺)] remain almost constant. Concentration patterns of platinum-group elements are typical for ophiolitic chromitite poor in sulfides, with predominance of the IPGE, variable Rh, and low Pt and Pd. The most abundant platinum-group mineral is Rh-bearing laurite that occurs either included in spinel or in silicate matrix, whereas Os-Ir-Ru alloy is always included in spinel. Laurite inclusions reveal complex intergrowth textures with Rh-Ru-Pt rich alloy, and with Rh-rich sulfide. Most laurites display trends to sulfur-poor compositions leading to local formation of very fine-grained Ru-Os-Ir alloy phases. Ni-Co-Fe sulfides, arsenides and sulfarsenides devoid of PGE are associated with the alteration of chromite. Textural position and chemical composition of the base metal inclusions, as well as comparison of alteration features between chromite and accessory chromian spinel in the Co-Ni-As ores of the Bou Azzer ophiolite indicate a close connection. It is suggested that hydrothermal fluids percolated through the marginal zones of the ophiolite belt during greenschist facies metamorphism and deposited Ni-Co-Fe arsenides, sulfarsenides and minor sulfides as accessories within altered chromitites, and also in structurally favourable zones as Ni-Co-As ores. Author’s address: Dr. Frank Melcher, Federal Institute for Geosciences and Natural Resources, Stilleweg 2, 30655 Hannover, Germany     

Sorption Characteristics of Rare Earth Element Eu^3＋ onto Silica-Water Interfaces Studied by Fluorescence Spectroscopy

The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ～1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=～5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献   

Environmental impact of an urban landfill on a coastal aquifer (El Jadida, Morocco)

The El Jadida landfill is one among many uncontrolled dumping sites in Morocco with no bottom liner. About 150 tons/day of solid wastes from mixed urban and industrial origins are placed directly on the ground. At the site of this landfill, the groundwaters circulate deeply (10–15 m) in the Cenomanian rock (calcareous–marl), which is characterised by an important permeability from cracks. The soil is sand–clay characterized by a weak coefficient of retention.The phreatic water ascends to the bottom of three quarries, which are located within the landfill. These circumstances, along with the lack of a leachate collection system, worsen the risks for a potential deterioration of the aquifer.To evaluate groundwater pollution due to this urban landfill, piezometric level and geochemical analyses have been monitored since 1999 on 60 wells. The landfill leachate has been collected from the three quarries that are located within the landfill. The average results of geochemical analyses show an important polluant charge vehiculed by landfill leachate (chloride = 5680 mg l⁻¹, chemical oxygen demand = 1000 mg l⁻¹, iron = 23 000 μg l⁻¹). They show also an important qualitative degradation of the groundwater, especially in the parts situated in the down gradient area and in direct proximity to the landfill. In these polluted zones, we have observed the following values: higher than 4.5 mS cm⁻¹ in electric conductivity, 1620 and 1000 mg l⁻¹ respectively in chlorides and sulfate (), 15–25 μg l⁻¹ in cadmium, and 60–100 μg l⁻¹ in chromium. These concentrations widely exceed the standard values for potable water.Several determining factors in the evolution of groundwater contamination have been highlighted, such as (1) depth of the water table, (2) permeability of soil and unsaturated zone, (3) effective infiltration, (4) humidity and (5) absence of a system for leachate drainage. So, to reduce the pollution risks of the groundwater, it is necessary to set a system of collection, drainage and treatment of landfill leachates and to emplace an impermeable surface at the site of landfill, in order to limit the infiltration of leachate.     

阿尔泰额尔齐斯带东段酸性岩墙群地球化学特征及其地质意义

野外地质调查发现在阿尔泰南缘额尔齐斯构造带东段、额尔齐斯活动断裂与富蕴-锡泊渡断裂之间发育了一套未变形的酸性岩墙群.岩墙群侵位于海西期片麻岩化花岗岩和上石炭统深变质的额尔齐斯组岩层中,薄片鉴定和岩石地球化学分析确定为具有细晶结构的流纹斑岩.岩石的SiO2含量为70.9%～75.38%,K2O＋Na2O含量为7.55%～8.99%;大部分样品Na2O＞K2O,里特曼指数值为1.8～2.5之间,Al2O3=12.80%～14.53%,A/CNK=0.9～1.1,NK/A=0.7～0.9,具有准铝质-弱过铝质、低镁、高钾钠、低钙和锶、高（Fe）mol/（Mg）mol特点,具A型花岗岩类特点,属于亚碱性脉岩.岩石轻稀土富集,大离子亲石元素相对富集,具有明显的中等负铕异常,壳源特征明显.锆石U-Pb二次粒子微探针测年显示岩墙群形成于277～286Ma.推断岩墙是阿尔泰海西期造山运动结束后,在拉张构造环境下的地壳局部熔融产物.