Selective detection of Fe and Mn species at mineral surfaces in weathered granite by conversion electron yield X-ray absorption fine structure

A new method for the speciation of Fe and Mn at mineral surfaces is proposed using X-ray absorption fine structure in conversion electron yield mode (CEY-XAFS). This method generally reflects information on the species at the sub-μm scale from the particle surface due to the limited escape depth of the inelastic Auger electron. The surface sensitivity of this method was assessed by experiments on two samples of granite showing different degrees of weathering. The XANES spectra of the Fe-K and Mn-K edge clearly gave different information for CEY and fluorescence (FL) modes. These XANES spectra of Fe and Mn show a good fit upon application of least-squares fitting using ferrihydrite/MnO₂ and biotite as the end members. The XANES spectra collected by CEY mode provided more selective information on the secondary phases which are probably present at the mineral surfaces. In particular, CEY-XANES spectra of Mn indicated the presence of Mn oxide in unweathered granite despite a very small contribution of Mn oxide being indicated by FL-XANES and selective chemical-extraction analyses. Manganese oxide could not be detected by micro-beam XANES (beam size: 5 × 5 μm²) in unweathered granite, suggesting that Mn oxide thinly and ubiquitously coats mineral surface at a sub-μm scale. This information is important, since Mn oxide can be the host for various trace elements. CEY-XAFS can prove to be a powerful tool as a highly sensitive surface speciation method. Combination of CEY and FL-XAFS will help identify minor phases that form at mineral surfaces, but identification of Fe and Mn oxides at mineral surfaces is critical to understand the migration of trace elements in water-rock interaction.     

Experiment and simulation of turbulent flow in local scour around a spur dyke

The turbulent flow in the local scour hole around a single non-submerged spur dyke is investigated with both experimental and numerical methods. The experiments are conducted under clear-water scour regime with an impermeable spur dyke. The scour geometry and flow velocities are measured in details with a high-resolution laser displacement meter, electro-magnetic velocimetries and PIV （Particle image velocimetry）. A 3D non-linear k-ε model is developed to simulate the complex local flow field around the scour area. The numerical model is formulated using FVM （Finite volume method） on a collocated unstructured mesh, capable of resolving complex geometries and boundaries. It is found that the simulation results are reasonably consistent with those of the experimental measurements. Based on the study results, the nature of the flow structure around a spur dyke with local scour hole is analyzed.     

Features and formation processes of multiple deposition layers from the 2004 Indian Ocean Tsunami at Ban Nam Kem,southern Thailand

Multiple‐layered tsunami deposits have been frequently reported from coastal stratigraphic sequences, but the formation processes of these layers remain uncertain. A terrestrial sandy deposit formed by the 2004 Indian Ocean Tsunami was investigated at Ban Nam Kem, southern Thailand. Four internal layers induced by two tsunami waves were identified in the tsunami deposit. Sedimentary structures indicated that two units were formed by run‐up currents caused by the tsunami and the other two units were deposited by the backwash flows. Graded bedding was common in the layers, but inverse grading was observed at limited intervals on the surveyed transects. The characteristics of the multiple‐layered tsunami deposit vary remarkably over a very short distance (<1 m) in response to the local topography. Remarkable asymmetries in thickness and grain‐size distribution are recognized between the run‐up and backwash flow deposits. On the basis of the interpretation of sedimentary structures, the formation process of the multiple‐layered tsunami deposit observed in this study can be explained in a schematic model as the modification of the ideal tsunami sequence by local erosion and the asymmetric hydraulic properties of tsunami waves, such as the maximum shear velocity and the heterogeneity of the flow velocity field.     

Comparison of carbon cycle between the western Pacific subarctic and subtropical time-series stations: highlights of the K2S1 project

A comparative study of ecosystems and biogeochemistry at time-series stations in the subarctic gyre (K2) and subtropical region (S1) of the western North Pacific Ocean (K2S1 project) was conducted between 2010 and 2013 to collect essential data about the ecosystem and biological pump in each area and to provide a baseline of information for predicting changes in biologically mediated material cycles in the future. From seasonal chemical and biological observations, general oceanographic settings were verified and annual carbon budgets at both stations were determined. Annual mean of phytoplankton biomass and primary productivity at the oligotrophic station S1 were comparable to that at the eutrophic station K2. Based on chemical/physical observations and numerical simulations, the likely “missing nutrient source” was suggested to include regeneration, meso-scale eddy driven upwelling, meteorological events, and eolian inputs in addition to winter vertical mixing. Time-series observation of carbonate chemistry revealed that ocean acidification (OA) was ongoing at both stations, and that the rate of OA was faster at S1 than at K2 although OA at K2 is more critical for calcifying organisms.     

Mixed layer in the Sea of Japan: numerical simulation and long-term data analysis

Seasonal variation and topography of the mixed layer in the Sea of Japan are studied by comparison of results from long-term observation data analysis and from numerical simulation with the MHI oceanic model (Shapiro. 1998. Marine Hydrophysical Journal, 6:26～40). The data are retrieved from Oceanographic Atlas of the Bering Sea, Okhotsk Sea, and Japan/East Sea (Rostov, Rostov, Dmitrieva, et al. 2003. Pacific Oceanography, 1 (1):70-72). The simulated and long-term patterns are compared. An impact of surface buoyancy flux, wind, and convergence/divergence of surface currents upon the mixed layer in the Sea of Japan is analyzed.     

土工袋加固地基新技术

介绍了研究开发的土工袋加固地基新技术,内容包括土工袋加固地基的基本原理、基本特性及在日本应用于房屋地基加固、公路路基加固、堤防加固及构筑挡墙等的工程实例。土工袋加固地基的原理在于利用了由于在外荷载作用下袋子周长的伸长而产生的袋子张力, 袋子张力引起了一个附加凝聚力。     

Glacial hazards in the Rolwaling valley of Nepal and numerical approach to predict potential outburst flood from glacial lake

In recent years, climate change and retreating glaciers constitute a major hazard in the Himalaya of South Asia. Glacial lakes are rapidly developing or increasing due to climate change. The rapid development of the lake may cause outburst of the lake. The outburst discharge from the glacial lake can cause catastrophic flooding and disaster in downstream area. Therefore, it is necessary to investigate the impact of climate change on glacial lakes and to understand the characteristics of the glacial lake outburst. In this study, the field assessment of Tsho Rolpa Glacial Lake in the Himalaya of Nepal has been presented and the impact of climate change on this glacial lake has been discussed. The Tsho Rolpa Glacial Lake is the largest and most potentially dangerous glacial lake in Nepal. In addition, a numerical model has been also developed for computing the characteristics of glacial lake outburst due to moraine dam failure by seepage and water overtopping. The numerical model is tested for the flume experimental cases. The simulated results of the outburst discharge, the dam surface erosion, and the temporal variation of the moisture movement in the dam are compared with those obtained from the hydraulic model experiments. The moisture profile calculated by numerical model was agreeable with the experimental moisture profile. The simulated failure surface of the dam due to seepage by considering the suction in slope stability analysis gave more agreeable results than the Janbu's simplified method. The results of the outburst discharge and dam surface erosion also agreed with the experimental results.     

Particle-tracking simulation for the drift/diffusion of spilled oils in the Sea of Okhotsk with a three-dimensional, high-resolution model

To conduct the simulation of oil spills in the Sea of Okhotsk, we developed a three-dimensional, high-resolution ocean circulation model. The model particularly improved the reproducibility of velocity field during the strong stratification period. Particle-tracking experiments with the effects of evaporation and biodegradation were performed using the combined data of daily ocean currents from the present model and the hourly diurnal tidal currents from the tidal model. The results are shown by the relative concentration of the particles averaged over the 8 years of 1998–2005 based on the ensemble forecast idea. For the case of particles released from the Sakhalin II oil field, the particles deployed in September–January are carried southward by the East Sakhalin Current, finally arriving at the Hokkaido coast, after 60–90 days. The particles deployed in March–August are diffused offshore by the synoptic wind drift, and hardly transported to regions south of Sakhalin. For the case of particles released from the region off Prigorodnoye, the oil export terminal, after the diffusion by the synoptic wind drift, a part of them are carried offshore of Hokkaido by the Soya Warm Current. The particles released in November–April flow out to the Japan Sea through the Soya Strait, mainly by the synoptic wind drift and secondly by the diffusion due to strong tidal currents around the Soya Strait. By considering the effects of evaporation and biodegradation, the relative concentration of the particles is considerably decreased before arriving at the Hokkaido coast, particularly in the case of drift from the Sakhalin II oil field.     

Numerical model and flume experiments of single- and two-layered hillslope flow related to slope failure

A hillslope flow model is developed considering 3D saturated and unsaturated flow of water during rainfall events. A finite difference-based numerical model of hillslope flow processes is developed. Four different experiments are done to see the effects of a single- and double-layered soil in pore-water pressure dynamics and slope failure. Results from the numerical model are verified with experimental results. The numerical and experimental values of the pore-water pressure and moisture contents are in good agreement. The results show that the hillslope heterogeneity caused by multiple layers of soil has greater influence on hillslope pore-pressure dynamics and slope failure patterns. The depth of slope failure shows high dependency on layering characteristics of the soil slope and pattern of rainfall. The proposed model provides a perspective on failure mechanism of a single- or double-layered slope under rainfall infiltration.