Oxygen and strontium isotopic characteristics of calc-alkalic volcanic rocks from the central and western Japan arcs: Evaluation of contribution of crustal components to the magmas

¹⁸O/¹⁶O and ⁸⁷Sr/⁸⁶Sr ratios were determined for Quaternary calc-alkalic volcanic rocks from six volcanic rock suites in the central and western Japan arcs. The δ¹⁸O values relative to SMOW and ⁸⁷Sr/⁸⁶Sr ratios range from +6.3 to +9.9⁰/₀₀ and 0.70357 to 0.70684, respectively. Both the O- and Sr-isotopic compositions are higher than those for island-arc primitive magmas and their differentiates. The isotopic compositions of the calc-alkalic rocks cannot be derived by a simple fractional crystallization of the primitive magmas. On the other hand, the ¹⁸O- and ⁸⁷Sr-enrichment is confined to the rock suites located in well-developed island arcs having thick continental-type crust with low or negative Bouguer anomalies. Involvement of ¹⁸O- and ⁸⁷Sr-rich crustal material in the magma formation is suggested.The isotopic compositions vary remarkably within individual rock suites as well as from volcano to volcano. The data points in δ¹⁸O vs. ⁸⁷Sr/⁸⁶Sr plot accord with a mixing model between primitive magmas and crustal material of dioritic composition on an average, assuming their comparative Sr contents. The primitive magmas involved could not be low-Sr tholeiites, but magmas more or less enriched in incompatible elements including Sr, which correspond to high-alkali tholeiites or alkali basalts and their evolved magmas. The nature of the primitive magmas seems to change from tholeiitic to more alkalic with progressing island-arc evolution.Mixing of crust-derived melts is more plausible than assimilation of solid-rocks for involving 20 to 30% crustal material in the magmas along simple mixing curves. Isotopic variations between the rock suites are ascribed to variable Sr concentration radio of the end-members, variable isotopic compositions of crustal material or variable mixing ratio of the end-members. Extremely high-δ ¹⁸O rocks with moderate increase in ⁸⁷Sr/⁸⁶Sr ratio suggest another mixing process in shallower magma chambers between andesite magmas and metasedimentary rocks having high δ ¹⁸O and ⁸⁷Sr/⁸⁶Sr values but low Sr content. Subsequent fractional crystallization of once-derived magmas would be the prominent process for the rock suites showing gradual increase in ¹⁸O up to 1⁰/₀₀ with uniform ⁸⁷Sr/⁸⁶Sr ratios.     

Speciation of Chromium in Artificially Contaminated Soil Reference Material GSJ JSO-2 Using XANES and Chemical Extraction Methods

The oxidation states of chromium in GSJ JSO-2 (artificially contaminated soil) and three other geochemical reference materials (GSJ JSO-1, JLS-1 and JMS-1) were observed using X-ray near edge structure (XANES). For comparison, other artificially contaminated soil materials (mimic-JSO-2) were prepared by adding Cr(VI) into JSO-1. Their oxidation states of chromium were determined using XANES. The chromium contents were 1118 μg g^-1 for JSO-2, 1352 μg g^-1 for mimic-JSO-2 and 69-113 μg g^-1 for the other reference materials. Most chromium was present as hexavalent in mimic-JSO-2. No hexavalent species were detected in other samples. These results for chromium oxidation state in JSO-2 and mimic-JSO-2 obtained with XANES resembled those obtained from a chemical extraction method. The present JSO-2 has no trace of Cr(VI), although Cr(VI) was added as a major species during preparation. On the other hand, the content of Cr(VI) obtained in mimic-JSO-2 agreed with the original Cr(VI) content. A time-elapse study showed that Cr(VI) contents in mimic-JSO-2 decreased gradually to 70% of the original abundance during 240-day preservation in dry conditions. Moreover, the abundance of Cr(VI) decreased markedly to 15% after 240 days in the wet mimic-JSO-2 containing 20% m/m of water. These experiments suggested that soil humidity enhanced the reduction of Cr(VI) and that Cr(VI) was reduced even in dry conditions. Consequently, it is reasonable to infer that Cr(VI) doped into JSO-2 was completely reduced to Cr(III) during the preservation period of 5 years. The certification of the long-term stability of the chemical form in reference materials will be much more important in future.     

Star formation in the circumnuclear environment of NGC 1068

We present near-infrared emission-line images of the circumnuclear ring in NGC 1068. We have measured the Brγ fluxes in a number of star-forming complexes and derived the extinction for each of these by comparison with Hα. We investigate the star-forming histories of these regions and find that a short burst of star formation occurred coevally throughout the ring within the last 30–40 Myr, and perhaps as recently as 4–7 Myr ago. The 1–0 S(1) flux and S(1)/Brγ ratios indicate that as well as fluorescence, shock-excited H₂ emission contributes to the total flux. There is excess H₂ flux to the north-west where the ionization cone crosses the ring, and we show that it is possible that the non-stellar continuum from the Seyfert nucleus which produces the high-excitation lines could also be causing fluorescence at the edges of molecular clouds in the ring. The nuclear 1–0 S(1) is more extended than previously realized but only along the bar's major axis, and we consider mechanisms for its excitation.     

Study on hydraulic characteristics of sabo dam with a flap structure for debris flow

The front part of the flow is very important and complex in the case of debris flow where there is an accumulation of large boulders. It is important to control or dampen the energy of the frontal part of a debris flow for the safety of the downstream area because the impact pressure of debris flow is much greater than that of clear fluid. The main objective of this study is to analyze the hydraulic characteristics of the proposed dam (i.e. closed-type dam with flap). The vertical pressure distribution of this type is compared with conventional dam types. In the experiments, the total pressure associated with major debris flows was recorded in real time by a system consisting of four dynamic pressure sensors installed on different types of dam. The results from experimental data clearly show that the dam with the flap has advantages of capturing the debris flow with large boulders and controls the total pressure by flow circulation due to presence of the flap structure compared to a closed-type dam without flap. Further-more, the empirical coefficients of hydrodynamic and solid collision models were proposed and com-pared with available coefficients.     

Estimation of debris flow discharge coefficient considering sediment concentration

A sabo dam has a purpose to block the path of debris flow. However, when overflow occurs, a sabo dam works as a weir, a vertical obstruction, where the fluid must flow over. Many empirical formulas and discharge coefficients for weirs relating flow depth to discharge have been proposed to calculate overflow discharges. However, only a few studies about overflow discharge coefficients are available in the case of debris flow. In this paper, experiments and numerical simulations were done to estimate debris flow discharge coefficients by considering the sediment concentration. In the numerical simulation, a complete overflow equation and a free overfall equation were implemented to calculate debris overflow discharges at a sabo dam. To determine the discharge coefficients for each equation, single factor regression analysis was used. Laboratory experiments were done to calibrate and to compare with the simulation. Study results showed that the discharge coefficients increase as the sediment concentration increases. This finding suggests debris flow discharge coefficients are derived to calculate the debris overflow discharges at a sabo dam.     

Wave set-up in the storm surge along open coasts during Typhoon Anita

Wave set-up in storm surges is studied using a numerical model for coasts in Tosa Bay, Japan, open to the Pacific Ocean. Simulation models employing only atmospheric pressures and winds as external forces are unable to properly simulate open coast storm surge heights, such as those due to Typhoon Anita (1970). However, the present study shows that a numerical model incorporating wave-induced radiation stresses, as well as wind stresses and pressure gradients, is able to account for the open coast surge heights. There is a maximum contribution of 40% by the radiation stresses to the peak sea level rises. This study also evaluates the effects of the tides; including the tides improves the agreement between the predicted water surface elevations and the observations. The difference in predictions between one-way coupling from wave to surge models and two-way coupling of the surge and wave models is found to be small.     

Relationship between sinking organic matter and minerals in the shallow zone of the western Subarctic Pacific

We used time-series sediment trap data for four major components, organic matter and ballast minerals (CaCO₃, opal, and lithogenic matter) from 150, 540, and 1000 m in the western subarctic Pacific (WSAP), where opal is the predominant mineral in sinking particles, to develop four simple models for settling particles, including the “ballast model”. The ballast model is based on the concept that most of the organic matter “rain” in the deep sea is carried by the minerals. These four models are designed to simultaneously reproduce the flux of each major component of settling particles at 540 and 1000 m by using the data for each component at 150 m as initial values. Among the four models, the ballast model, which considers the sinking velocity increase with depth, was identified as the best using the Akaike information criterion as a measure of the model fit to data. This model successfully reproduced the flux of organic matter at 540 and 1000 m, indicating that the ballast model concept works well in the shallow zone of the WSAP on a seasonal timescale. This also suggests that ballast minerals not only physically protect the organic matter from degradation during the settling process but also enhance the sinking velocity and reduce the degree of decomposition.     

Application of spectral decomposition algorithm for mapping water quality in a turbid lake (Lake Kasumigaura,Japan) from Landsat TM data

The remote sensing of Case 2 water has been far less successful than that of Case 1 water, due mainly to the complex interactions among optically active substances (e.g., phytoplankton, suspended sediments, colored dissolved organic matter, and water) in the former. To address this problem, we developed a spectral decomposition algorithm (SDA), based on a spectral linear mixture modeling approach. Through a tank experiment, we found that the SDA-based models were superior to conventional empirical models (e.g. using single band, band ratio, or arithmetic calculation of band) for accurate estimates of water quality parameters. In this paper, we develop a method for applying the SDA to Landsat-5 TM data on Lake Kasumigaura, a eutrophic lake in Japan characterized by high concentrations of suspended sediment, for mapping chlorophyll-a (Chl-a) and non-phytoplankton suspended sediment (NPSS) distributions. The results show that the SDA-based estimation model can be obtained by a tank experiment. Moreover, by combining this estimation model with satellite-SRSs (standard reflectance spectra: i.e., spectral end-members) derived from bio-optical modeling, we can directly apply the model to a satellite image. The same SDA-based estimation model for Chl-a concentration was applied to two Landsat-5 TM images, one acquired in April 1994 and the other in February 2006. The average Chl-a estimation error between the two was 9.9%, a result that indicates the potential robustness of the SDA-based estimation model. The average estimation error of NPSS concentration from the 2006 Landsat-5 TM image was 15.9%. The key point for successfully applying the SDA-based estimation model to satellite data is the method used to obtain a suitable satellite-SRS for each end-member.