Adsorption characteristics of perchloroethylene in natural sandy materials with low organic carbon content

Laboratory batch tests were conducted to investigate the sorption isotherms and sorption kinetics of the chlorinated hydrocarbon perchloroethylene (PCE) in five natural sandy materials with an organic carbon content (f _oc) in the range 0.080–0.540%. The amended non-linear dual-mode model can describe the sorption isotherms in materials with f _oc in the range 0.080–0.090%. For a sample with a much higher f _oc of 0.54%, the absorption isotherm was found to fit a linear model. These results may indicate that organic carbon is not the main factor influencing the sorption isotherm. The sorption kinetics of PCE in samples with f _oc in the range 0.080–0.090% are not first-order and are different from those observed in the samples with higher f _oc. The sorption process in the materials with lower f _oc involves fast sorption, fast desorption and an equilibrium stage. The results may imply that the factors affecting sorption kinetics of PCE in low f _oc media are pore filling and capillary condensation rather than organic carbon content.     

Spatial pattern of Karst rock desertification in the Middle of Guizhou Province,Southwestern China

Karst rocky desertification is a typical type of land degradation in the Southwestern China. It has great ecological and economical implications for the local people. Landsat images from the middle of Guizhou Province collected in 1974, 1993 and 2001 were used for change detection of the pattern of Karst rocky desertification. The results show the following findings: (1) Desertification area expanded drastically in 27 years, at an increasing rate about 116.2 km²/year. (2) High areas (900–1,500 m) are the most affected. (3) Areas with the slope <5° or >25° are also easily tend to be Karst rocky deserted. (4) The process of Karst rocky desertification is nearly irreversible. Few areas of Karst rocky desertification could be meliorated to non-desertification land. (5) Most of the degraded lands are located in the south and the central of the study region, and the meliorated land areas are sparsely located in the east and the west part of the region. All these findings would provide bases for the decision-making of the local government to improve the Karst rocky desertification     

Geochemistry of Flooded Underground Mine Workings Influenced by Bacterial Sulfate Reduction

Unlike the majority of the water in the flooded mine complex of Butte Montana, which includes the highly acidic Berkeley pit lake, groundwater in the flooded West Camp underground mine workings has a circum-neutral pH and contains at least 8 μM aqueous sulfide. This article examines the geochemistry and stable isotope composition of this unusual H₂S-rich mine water, and also discusses problems related to the colorimetric analysis of sulfide in waters that contain FeS_(aq) cluster compounds. The West Camp mine pool is maintained at a constant elevation by continuous pumping, with discharge water that contains elevated Mn (90 μM), Fe (16 μM), and As (1.3 μM) but otherwise low metal concentrations. Dissolved inorganic carbon in the mine water is in chemical and isotopic equilibrium with rhodochrosite in the mineralized veins. The mine water is under-saturated with mackinawite and amorphous FeS, but is supersaturated with Cu- and Zn-sulfides. However, voltammetry studies show that much of the dissolved sulfide and ferrous iron are present as FeS_(aq) cluster molecules: as a result, the free concentration of the West Camp water is poorly constrained. Concentrations of dissolved sulfide determined by colorimetry were lower than gravimetric assays obtained by AgNO₃ addition, implying that the FeS_(aq) clusters are not completely extracted by the Methylene Blue reagent. In contrast, the clusters are quantitatively extracted as Ag₂S after addition of AgNO₃. Isotopic analysis of co-existing aqueous sulfide and sulfate confirms that the sulfide was produced by sulfate-reducing bacteria (SRB). The H₂S-rich mine water is not confined to the immediate vicinity of the extraction well, but is also present in flooded mine shafts up to 3 km away, and in samples bailed from mine shafts at depths up to 300 m below static water level. This illustrates that SRB are well established throughout the southwestern portion of the extensive (>15 km³) Butte flooded mine complex.     

High-Resolution Vertical Profile Measurements for Carbon Dioxide and Water Vapour Concentrations Within and Above Crop Canopies

We present a portable elevator-based facility for measuring \(\hbox {CO}_{2}\), water vapour, temperature and wind-speed profiles between the soil surface and the atmospheric surface layer above crop canopies. The end of a tube connected to a closed-path gas analyzer is continuously moved up and down over the profile range (in our case, approximately 2 m) while concentrations are logged at a frequency of \(20 \hbox { s}^{-1}\). Using campaign measurements in winter wheat, winter barley and a catch crop mixture (spring 2015 to autumn 2016) during different stages of crop development and different times of the day, we demonstrate a simple approach to correct for time lags, and the resulting profiles of 30-min mean mole fractions of \(\hbox {CO}_{2}\) and \(\hbox {H}_{2}\hbox {O}\) over height increments of 0.025 m. The profiles clearly show the effects of soil respiration and photosynthetic carbon assimilation, varying both during the diurnal cycle and during the growing season. Profiles of temperature and wind speed are based on a ventilated finewire thermocouple and a hot-wire anemometer, respectively. Measurements over bare soil and a short plant canopy were analyzed in the framework of Monin–Obukhov similarity theory to check the validity of the measurements and raw-data-processing approach. Derived fluxes of \(\hbox {CO}_{2}\), latent and sensible heat and momentum show good agreement with eddy-covariance measurements.     

Effect of Surface Heterogeneity on the Boundary-Layer Height: A Case Study at a Semi-Arid Forest

We investigate the effects of an isolated meso-\(\gamma \)-scale surface heterogeneity for roughness and albedo on the atmospheric boundary-layer (ABL) height, with a case study at a semi-arid forest surrounded by sparse shrubland (forest area: \(28~\text{ km }^2\), forest length in the main wind direction: 7 km). Doppler lidar and ceilometer measurements at this semi-arid forest show an increase in the ABL height over the forest compared with the shrubland on four out of eight days. The differences in the ABL height between shrubland and forest are explained for all days with a model that assumes a linear growth of the internal boundary layer of the forest through the convective ABL upwind of the forest followed by a square-root growth into the stable free atmosphere. For the environmental conditions that existed during our measurements, the increase in ABL height due to large sensible heat fluxes from the forest (\(600~\text {W~m}^{-2}\) in summer) is subdued by stable stratification in the free atmosphere above the ABL, or reduced by high wind speeds in the mixed layer.     

Downscaling future climate change projections over Puerto Rico using a non-hydrostatic atmospheric model

We present results from 20-year “high-resolution” regional climate model simulations of precipitation change for the sub-tropical island of Puerto Rico. The Japanese Meteorological Agency Non-Hydrostatic Model (NHM) operating at a 2-km grid resolution is nested inside the Regional Spectral Model (RSM) at 10-km grid resolution, which in turn is forced at the lateral boundaries by the Community Climate System Model (CCSM4). At this resolution, the climate change experiment allows for deep convection in model integrations, which is an important consideration for sub-tropical regions in general, and on islands with steep precipitation gradients in particular that strongly influence local ecological processes and the provision of ecosystem services. Projected precipitation change for this region of the Caribbean is simulated for the mid-twenty-first century (2041–2060) under the RCP8.5 climate-forcing scenario relative to the late twentieth century (1986–2005). The results show that by the mid-twenty-first century, there is an overall rainfall reduction over the island for all seasons compared to the recent climate but with diminished mid-summer drought (MSD) in the northwestern parts of the island. Importantly, extreme rainfall events on sub-daily and daily time scales also become slightly less frequent in the projected mid-twenty-first-century climate over most regions of the island.     

Perceptions of climate engineering in the South Pacific,Sub-Saharan Africa,and North American Arctic

Nearly all research on public perceptions of climate engineering has been conducted in wealthy, developed countries. However, understanding perspectives from vulnerable populations is critical to inclusive, democratic debate on both research and governance. This study utilized in-depth interviews to explore the perspectives of vulnerable populations in the South Pacific, Sub-Saharan Africa, and the North American Arctic. Interviewees in this study were desperate for solutions to climate change and therefore willing to consider climate engineering. However, their willingness to consider climate engineering could be characterized as both deeply reluctant and highly conditional. Interviewees expressed a number of concerns about potential social and political implications of engineering the climate. They also described conditions that may need to be met to ensure that future climates (engineered or otherwise) are more equitable.     

Global carbon budgets and the viability of new fossil fuel projects

Policy-makers of some fossil fuel-endowed countries wish to know if a given fossil fuel supply project is consistent with the global carbon budget that would prevent a 2 °C temperature rise. But while some studies have identified fossil fuel reserves that are inconsistent with the 2 °C carbon budget, they have not shown the effect on fossil fuel production costs and market prices. Focusing on oil, we develop an oil pricing and climate test model to which we apply future carbon prices and oil consumption from several global energy-economy-emissions models that simulate the energy supply and demand effects of the 2 °C carbon budget. Our oil price model includes key oil market attributes, notably upper and lower market share boundaries for different oil producer categories, such as OPEC. Using the distribution of the global model results as an indicator of uncertainty about future carbon prices and oil demand, we estimate the probability that a new investment of a given oil source category would be economically viable under the 2 °C carbon budget. In our case study of Canada’s oil sands, we find a less than 5% probability that oil sands investments, and therefore new oil pipelines, would be economically viable over the next three decades under the 2 °C carbon budget. Our sensitivity analysis finds that if OPEC agreed to reduce its market share to 30% by 2045, a significant reduction from its steady 40–45% of the past 25 years, then the probability of viable oil sands expansion rises to 30%.     

Is public awareness and perceived threat of climate change associated with governmental mitigation targets?

Social scientists and science communicators are concerned about the apparent discrepancy between the scientific consensus on climate change (Anderegg et al. Proc Natl Acad Sci 107:12107–12109, 2010; Doran and Zimmerman EOS Trans Am Geophys Union 90:22–3, 2009) and the general public’s views (Knight Environ Sociol 2:101–113, 2016; Lee et al. Nat Clim Chang 5:1014–1020, 2015). It is reasoned that increased public awareness and perceived threat of climate change may pressure governments to enact policy to counteract climate change (e.g. setting stringent carbon emissions targets). Despite a logical link between public awareness and government-set emissions targets, this relationship remains untested. We examined the relationship between public awareness about and perceived threat of climate change and governmental emissions targets across 71 countries and 1 region. We found a positive association between the proportions of a country’s population that are aware of climate change and the unconditional emissions reduction targets set by that country in the Paris Agreement (Rogelj et al. Nature 534:631–639, 2016). However, the proportion of people in a country who perceive climate change as a personal threat was not associated with higher emissions reduction targets. Our results suggest that public awareness may be an important part of garnering the public support required for policies designed to mitigate climate change to succeed.