Study of galvanic interactions between pyrite and chalcopyrite in a flowing system: implications for the environment

When galvanic interactions between pyrite and chalcopyrite occur in solution, pyrite, with the higher rest potential, acts as a cathode and is protected whereas chalcopyrite, with the lower rest potential, acts as an anode and its oxidation is increased. In this work a three-electrode system was used to investigate the corrosion current density and mixed potential of a galvanic cell comprising a pyrite cathode and a chalcopyrite anode in a flowing system. The results showed that with increasing concentration of ferric ion in the solution, with increasing acidity, and with increasing flow rate of the solution, the corrosion current density increased and the mixed potential of the galvanic cell became more positive. These experimental results are of direct significance to the control of environmental pollution in mining activity. By using the galvanic model, mixed potential theory, and the Butler–Volmer equation, the experimental results were explained theoretically.     

海积软土的工程地质研究现状

我国沿海地区,广泛分布着性质极为软弱的近代沉积的欠固结软土。近年来,由于经济发展及对外开放的需要,巨型的工程建筑多修筑于软土地基之上,这样就带地多复杂的工程地质及岩土工程问题,同时也促进了软土和吹填土的开发和利用以及填海造陆工程的不断发展,就目前其研究现状进行了总结和介绍。     

临南地区石油运移方向与成藏期次研究

根据原油及油砂抽提物中含氮化合物分析、原油生物标志成熟度参数及储层流体包裹体烃类成分分析,研究了临南地区石油运移的方向、距离、成藏期次。结果表明临南油田仅有一期油气运聚成藏过程,属中新世末形成的成熟原油,4 甲基甾烷含量较高。曲堤油田存在两期油气运聚成藏过程,早期原油成熟度低,4 甲基甾烷含量低,运移距离较远,成藏后大部分散失 ;晚期充注的原油成熟度较高,4 甲基甾烷含量也较高,并保存至今。     

Primary melt from Sannome-gata volcano,NE Japan arc: constraints on generation conditions of rear-arc magmas

The conditions under which rear-arc magmas are generated were estimated using primary basalts from the Sannome-gata volcano, located in the rear of the NE Japan arc. Scoriae from the volcano occur with abundant crustal and mantle xenoliths, suggesting that the magma ascended rapidly from the upper mantle. The scoriae show significant variations in their whole-rock compositions (7.9–11.1 wt% MgO). High-MgO scoriae (MgO > ~9.5 wt%) have mostly homogeneous ⁸⁷Sr/⁸⁶Sr ratios (0.70318–0.70320), whereas low-MgO scoriae (MgO < ~9 wt%) have higher ⁸⁷Sr/⁸⁶Sr ratios (>0.70327); ratios tend to increase with decreasing MgO content. The high-MgO scoriae are aphyric, containing ~5 vol% olivine microphenocrysts with Mg# [100 × Mg/(Mg + Fe²⁺)] of up to 90. In contrast, the low-MgO scoriae have crustal xenocrysts of plagioclase, alkali feldspar, and quartz, and the mineralogic modes correlate negatively with whole-rock MgO content. On the basis of these observations, it is inferred that the high-MgO scoriae represent primary or near-primary melts, while the low-MgO scoriae underwent considerable interaction with the crust. Using thermodynamic analysis of the observed petrological features of the high-MgO scoriae, the eruption temperature of the magmas was constrained to 1,160–1,220 °C. Given that the source mantle was depleted MORB-source mantle, the primary magma was plausibly generated by ~7 % melting of a garnet-bearing spinel peridotite; taking this into consideration, and considering the constraints of multi-component thermodynamics, we estimated that the primary Sannome-gata magma was generated in the source mantle with 0.5–0.6 wt% H₂O at 1,220–1,230 °C and at ~1.8 GPa, and that the H₂O content of the primary magma was 6–7 wt%. The rear-arc Sannome-gata magma was generated by a lower degree of melting of the mantle at greater depths and lower temperatures than the frontal-arc magma from the Iwate volcano, which was also estimated to be generated by ~15 % melting of the source mantle with 0.6–0.7 wt% H₂O at ~1,250 °C and at ~1.3 GPa.     

蒸馏水中蒙脱石晶层间膨胀压力理论研究

蒙脱石颗粒周围的溶液浓度对其膨胀性有较大影响,传统的双电层模型可以对电解质环境下蒙脱石的膨胀特性做出较好的模拟,但并不适于蒸馏水的情况。针对膨润土在蒸馏水或纯水中已有的膨胀特性试验,本文在前人的研究基础上详细推导了蒸馏水中蒙脱石晶层间的膨胀压力模型,并给出一种简便算法。运用此算法可以避免非线性方程的求解,从而可以较方便的将膨胀力和晶层间距联系起来。     

准噶尔盆地西北缘克百地区二叠系沉积特征及沉积模式

准噶尔盆地西北缘二叠系是重要的产油层和储集层,通过岩心观察、薄片分析,结合测井和录井资料,对西北缘克百断裂下盘二叠系砂砾岩的沉积环境和沉积特征进行了深入研究。研究表明,该区砂砾岩既有水上冲积扇沉积环境沉积的,也有水下扇三角洲前缘沉积环境形成的。前者主要为棕褐色、泥质杂基含量高、分选和磨圆差,储层物性相对较差;后者经过了稳定水流的淘洗,杂基含量少,钙质或沸石类胶结发育,分选性和磨圆度也较高,其物性条件也明显较好。并据此建立了研究区冲积扇与扇三角洲有机结合的沉积模式,该模式突出了湖岸线的重要性,同时模糊冲积扇与扇三角洲之间的界限。并对冲积扇与扇三角洲各亚相的岩性特征、沉积结构和沉积序列进行了归纳和总结,为该区寻找二叠系优质储层提供借鉴和思路。     

2010年度地理学基金项目评审与成果分析

着重分析了2010年度面上项目、青年基金项目及地区基金项目的申请情况,在研项目的进展情况,以及2009年底结题项目完成情况,同时介绍了2009年度主要学科方向取得的研究进展。     

中国若干下寒武统高硒地层的有机地球化学特征及生物樗物研究

通过中国若干下寒武统高硒地层的有机地球化学及生物标志物研究,主伙高硒地层中有机质的先质母体为菌藻类生物,某些生物樗物指标指示了沉积环境为封闭的缺氧环境。同时,文章结合地质实际讨论还原的沉积环境有利于菌藻类生物的生长和保存,硒的富集与菌藻生物的繁盛有关。     

天山山区近40a夏季降水变化及与南北疆的比较

利用新疆1959-1998年的降水资料,分析了天山山区近40a来夏季降水变化特征,并与南疆、北疆进行了比较.结果表明:天山山区近40a来的夏季降水在干湿阶段、最干最湿年份、降水变化的周期方面均与南北疆有别;天山山区夏季降水空间上的同步性变化比南疆及北疆弱一些;天山山区近40a来夏季降水年代际变化与北疆较为相近.新疆近40a来夏季降水最多的年代是90年代,天山山区偏多12%,南疆偏多25%,北疆偏多21%.     

郯庐断裂带张八岭隆起北段的左旋走滑挤压变形及其40Ar/39Ar定年

郯庐断裂带张八岭隆起北段,自西向东分别出露北北东向的韧性滑脱变形带、脆-韧性过渡带和脆性的前陆褶断带。韧性滑脱变形带内的张八岭群片岩,广泛发生了低绿片相背景下的糜棱岩化。其中呈现为平缓的糜棱面理和近南北向的矿物拉伸线理。显微构造及石英C轴组构分析显示,该韧性滑脱带一致为上盘向南的运动。该带以东依次变为上盘向南南东→南东的逆冲活动,总体上为左旋走滑挤压变形带。张八岭群所在的韧性变形带为深部陡立走滑构造与浅部脆性构造之间的滑脱变形带,其间的差异走滑变形,造成了该滑脱层在总体向北运动中出现上盘向南的剪切变形。对6处张八岭群片岩中15个不同粒级白云母的40Ar/39Ar定年指示,变形发生在(236.2±0.5)~(238.0±0.4)Ma的中三叠世晚期。这表明郯庐断裂带的左行平移发生在华北与华南板块碰撞的深俯冲阶段,起源于陆内转换断层。