Inorganic pollutants in the Padma River, Bangladesh

The water and bed-sediment pollution status of the Padma River was determined by analysis of representative samples for selected metals and ions. Water and bed-sediment samples were collected at a T-dam, Rajshahi, Bangladesh, for 7 months. Water and silt-metal content analysis was performed using atomic absorption spectrophotometry or other analytical methods. The data showed the variation of the metal ion-levels in water as follows: Ca 17.11–48.37 ppm, Na 17.51–20.09 ppm, K 1.00–3.60 ppm, Cr 2.80–7.00 ppm, and SO₄ 4.17–5.48 ppm; in bed sediment, the levels were Cr 35–1050 ppm and Pb 12–48 ppm. The occurrence of Na, K and Ca was in the normal range (US EPA permissible limit), but the levels of Cr in water were much higher than the permissible limit. The SO₄ ion content was well below the pollution level. The concentration of Pb in the bed sediment was within the permissible limit for the standard International Atomic Energy Agency (IAEA) Soil-5a, but the concentration of Cr in the bed sediment was significantly higher than the permissible limit for the standard IAEA Soil-5a. Thus the Padma river water was polluted with Cr. The occurrence of some ions showed a monthly variation. Received: 19 August 1999 · Accepted: 12 October 1999     

Denitrification in coastal Louisiana: A spatial assessment and research needs

By transforming fixed nitrogen (N) into nitrogen gas, the biochemical processes that support denitrification provide a function critical to maintaining the integrity of ecosystems subjected to increased loading of N from anthropogenic sources. The Louisiana coastal region receives high nitrate (NO₃^?) concentrations (> 100 µM) from the Mississippi–Ohio–Missouri River Basin and is also an area undergoing high rates of wetland loss. Ongoing and anticipated changes in the Louisiana coastal region promise to alter biogeochemical cycles including the net rate of denitrification by ecosystems. Projecting what these changes could mean for coastal water quality and natural resources requires an understanding of the magnitude and patterns of variation in denitrification rates and their connection to estuarine water quality at large temporal and spatial scales under current conditions. We compile and review denitrification rates reported in 32 studies conducted in a variety of habitats across coastal Louisiana during the period 1981– 2008. The acetylene inhibition and ¹⁵N flux were the preferred techniques (95%); most of the studies used sediment slurries rather than intact sediment cores. There are no estimates of denitrification rates using the N₂/Ar ratio and isotope pairing techniques, which address some of the problems and limitations of the acetylene inhibition and ¹⁵N flux techniques. These studies have shown that sediments from estuaries, lakes, marshes, forested wetlands, and the coastal shelf region are capable of high potential denitrification rates when exposed to high NO₃^? concentrations (> 100 µM). Maximum potential denitrification rates in experimental and natural settings can reach values > 2500 µmol m² h^? 1. The lack of contemporary studies to understand the interactions among critical nitrogen transformations (e.g., organic matter mineralization, immobilization, aquatic plant assimilation, nitrification, nitrogen fixation, dissimilatory nitrate reduction to ammonium (DNRA) and anaerobic ammonium oxidation (annamox) limits our understanding of nitrogen cycling in coastal Louisiana, particularly the role of respiratory and chemolithoautotrophic denitrification in areas undergoing wetland restoration.     

Effects of vegetation cover on summer climate in China during 1982–2001

In this paper, we apply lagged correlation analysis to study the effects of vegetation cover on the summer climate in different zones of China, using NOAA/AVHRR normalized difference vegetation index (NDVI) data during the time period from 1982 to 2001 and climate data of 365 meteorological stations across China (precipitation from 1982 to 2001 and temperature from 1982 to 1998). The results show that there are positive correlations between spring NDVI and summer climate (temperature and precipitation) in most zones of China; these suggest that, when the vegetation cover increases, the summer precipitation will increase, and the lagged correlations show a significant difference between zones. The stronger correlations between NDVI in previous season and summer climate occur in three zones (Mid-temperate zone, Warm-temperate zone and Plateau climate zone), and this implies that vegetation changes have more sensitive feedback effects on climate in the three zones in China. Supported by the National 973 Program of China (No.2006CB701300), the National Natural Science Foundation of China (No.40721001), the Sino-Germany Joint Project (No. 2006DFB91920), the Open Fund of Shanghai Leading Academic Discipline Project (T0102) and the Open Fund of LIESMARS, Wuhan University.     

Pétrographie et géochimie comparées des pellets phosphatés et de leur gangue dans le gisement phosphaté de Ras-Draâ (Tunisie). Implications sur la genèse des pellets phosphatés

Paléocène-Early Eocene phosphate outcrop in the Ras-Draâ deposit (Tunisia) comprises alternances of P-rich strata (P₂O₅ ≥ 18%) and P-poor ones (P₂O₅ ≤ 2%). In phosphate rich strata, P is concentrated in rounded grains—so-called pellets—(28% ≤ P₂O₅ ≤ 38%) embedded in a matrix—so-called exogangue—much poorer in P (P₂O₅ # 7%) than pellets. The study of pellets (whose size lies mainly between 100 and 500 μm), of their surrounding matrix and of poorly phosphatic sediments, interlayered between the phosphatic strata, has been performed by optical microscopy and various chemical analyses, ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectroscopy) and punctual chemical analyses by EDS (Energy Dispersive Spectroscopy). Mineralogical and chemical studies of the Tunisian phosphatic pellets show that the basic mineralogical component of these grains is carbonate-fluor-apatite, or francolite. The structural formula of a representative specimen of francolite in the basin is as follows: (Ca_4.63Mg_0.13Na_0.22)(PO₄)_2.51(CO₃)_0.48(OH_0.77F_0.23). The mineralogy of the constituents of the sediment surrounding pellets comprises carbonates, clays, silica (opal, quartz). Microscopic observations of Ras-Draâ phosphorites, added to geochemical results, establish that pellets are small bodies, allochtonous to their matrix and whose composition is independent of that of this matrix. Fecal cylindrical bodies and subspherical pellets, the latest being supposed to proceed from the fecal bodies by fragmentation, are considered to have been formed by fishes, as P-rich and organic matter-rich faeces. These faeces turn out to be resistant to mechanical dispersion and to chemical diffusion of soluble elements from and in direction of sea water. This closeness is responsible for the strong reducing conditions having prevailed inside and during the pellets diagenesis.     

Geochemical behaviour of the Tunisian background aerosols in Sirocco wind circulations

This study examines spatial and time evolutions of the principal constituents of the Tunisian background aerosols under Sirocco wind circulations. Aerosols coming from the Sahara Desert were found to be loaded with particulate matter, especially silicon. The aerosols were shown to have varying geochemical behaviour along the ``South-North" displacement of the Saharan plumes, depending on the wind flow characteristics, geomorphologic features and the nature of soils swept by the wind. In the south and the center part of the country, the transfer of aerosol constituents to the soil (by gravity and/or impaction) was probably predominated by localized enrichment phenomena. The latter are reinforced by the effect of turbulent winds over bare soils, wind wakes and probably selective disintegration, especially in the vicinity of the geomorphologic features of central Tunisia. These relatively high features, extending over important distances, appear to be of paramount importance for the phenomena of redistribution of aerosol constituents even during periods without Sirocco wind circulations. In the northern section of the country, aerosol constituent concentrations dropped to almost 50%, in spite of the abundance of localized turbulent winds. This may be explained by the effect of forests and the relatively dense vegetation cover, which clearly reinforces the transfer phenomena to the soil and the attenuate of dust entrainment.     

Tillage and farm manure affect root growth and nutrient uptake of wheat and rice under semi-arid conditions

Tillage systems affect soil properties, crop growth and nutrient uptake under various agro-ecological conditions. The uptake of water and nutrients are largely dependent on the root systems of wheat (Triticum aestivum L.) and rice (Oryza sativa L.). The application of manure has direct influence on the nutrient uptake by the crop plants. A 2 year field experiment was conducted to evaluate the impact of tillage and farm manure on root growth by measuring the root length density on a sandy clay loam (Typic calciargid soil). Three tillage systems were used; (i) minimum tillage (MT), (ii) deep tillage (DT) and (iii) conventional tillage (CT). Three farm manure levels were used; (i) FM₀ (only chemical fertilizers), (ii) FM₁₅ (farm manure at 15 Mg ha^?1) and (iii) FM₃₀ (farm manure at 30 Mg ha^?1). The incorporation of farm manure into soil markedly improved the root length density (RLD) of both wheat and rice crops. For wheat, the application of FM₃₀ increased RLD by 16% and 9% in cases of deep tillage and minimum tillage, respectively. For rice, the increase in RLD at the same farm manure rate (FM₃₀) was 13% and 17%, during first and second year, respectively. Averaged across tillage, the trend of RLD for both wheat and rice was DT > CT > MT. The incorporation of FM has increased the uptake of N, P and K significantly (P < 0.05), thereby increasing the agronomic parameters. The manure may be used to ameliorate the deleterious effects of tillage for sustainable crop yield.     

Saltwater intrusion modelling in Jorf coastal aquifer,South‐eastern Tunisia: geochemical,geoelectrical and geostatistical application

Marine intrusion is the most serious problem facing the coastal Jorf shallow aquifer, located in south‐eastern Tunisia on the Mediterranean Sea. Jorf Aquifer is intensively exploited to supply the growing needs of agriculture and domestic sectors. This work proposes a multidisciplinary investigation, involving hydro‐geochemical, geoelectrical survey and geostatistical techniques for modelling the saltwater intrusion. For this purpose, 36 water samples were conducted and analysed. Electric conductivity, pH, total dissolved solids and major ions were measured and analysed. Pie and Durov Diagrams, Q‐mode hierarchical cluster and geostatistical analysis were considered to identify the main groundwater mineralization processes. Results revealed that the Na‐Cl‐Ca‐SO₄ is the dominant water type suggesting that dissolution of halite and gypsum was the main mineralization source of groundwater in the central and southern part of study area. However, saltwater intrusion was shown to control groundwater quality essentially in coastal areas. Variographic analyses were used to select the variographic model that best fits the spatial development of apparent resistivity. Kriged apparent resistivity profiles showed an abnormal decrease of resistivity values in the coastal zone, implying highly saline water because of seawater intrusion. Apparent resistivity values also decrease considerably in the faulted areas, suggesting a contribution of faults to seawater intrusion. Finally, saltwater mixing ratio was computed for each sample, and a refined seawater intrusion map was developed. Copyright © 2012 John Wiley & Sons, Ltd.     

Sea level in the Mediterranean Sea: seasonal adjustment and trend extraction within the framework of SSA

The sea level change is a crucial indicator of our climate. The spatial sampling offered by satellite altimetry and its continuity during the past years are the major assets to provide an improved vision of the Mediterranean sea level changes. In this paper, an automatic signal extraction approach, based on Singular Spectrum Analysis (SSA), is utilized for analysis and seasonal adjustment of the Mediterranean Sea level series. This automatic approach enables us to overcome the difficulties of visual identification of trend constituents that sometimes we encounter when using the conventional SSA method. The results indicate that the Mediterranean mean sea level is dominated by several harmonic components. The annual signal is particularly strong and almost covers 73.62 % of the original sea level series variation whiles its amplitude is about 15 cm. The extracted trend also indicates that the Mediterranean main sea level has significantly been raised during the period 1993–2012 by 2.44?±?0.4 mm yr^?1. As an important consequence, considering the current situation, if this trend continues, the Mediterranean Sea level will be raised about 22 cm by the end of this century, which makes a dramatic effect on several issues such as land, flora, fauna, and people activities established along the Mediterranean coastlines.