Detection of deep water benthic macroalgae using image-based classification techniques on multibeam backscatter at Cashes Ledge,Gulf of Maine,USA

Benthic macroalgae form an important part of temperate marine ecosystems, exhibiting a complex three-dimensional character which represents a vital foraging and spawning ground for many juvenile fish species. In this research, image-based techniques for classification of multibeam backscatter are explored for the detection of benthic macroalgae at Cashes Ledge in the Gulf of Maine, USA. Two classifications were performed using QTC-Multiview, differentiated by application of a threshold filter, and macroalgal signatures were independently extracted from the raw sonar datagrams in Matlab. All classifications were validated by comparison with video ground-truth data. The unfiltered classification shows a high degree of complexity in the shallowest areas within the study site; the filtered demonstrates markedly less variation by depth. The unfiltered classification shows a positive agreement with the video ground-truth data; 82.6% of observations recording Laminaria sp., 39.1% of Agarum cribrosum and 100.0% (n = 3) of mixed macroalgae occur within the same acoustically distinct group of classes. These are discrete from the 8.1% recorded agreement with absences and nulls (>40 m) of macrophytes (n = 32) from a total of 86 ground-truth locations. The results of the water column data extraction (WCDE) show similar success, accurately predicting 78.3% of Laminaria sp. and 30.4% of A. cribrosum observations.     

<Superscript>57</Superscript>Fe Mössbauer spectroscopy,X-ray single-crystal diffractometry,and electronic structure calculations on natural alexandrite

Natural alexandrite Al₂BeO₄:Cr from Malyshevo near Terem Tschanka, Sverdlovsk, Ural, Russia, has been characterized by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine oxidation state and location of iron. The sample contains 0.3 wt% of total iron oxide. The ⁵⁷Fe Mössbauer spectrum can be resolved into three doublets. Two of them with hyperfine parameters typical for octahedrally coordinated high-spin Fe³⁺ and Fe²⁺, respectively, are assigned to iron substituting for Al in the octahedral M2-site. The third doublet is attributed to Fe³⁺ in hematite. Electronic structure calculations in the local spin density approximation are in reasonable agreement with experimental data provided that expansion and/or distortion of the coordination octahedra are presumed upon iron substitution. The calculated hyperfine parameters of Fe³⁺ are almost identical for the M1 and M2 positions, but the calculated ligand-field splitting is by far too large for high-spin Fe³⁺ on M1.     

<Superscript>57</Superscript>Fe Mössbauer measurements and electronic structure calculations on natural lawsonites

Three natural lawsonites from Syke Rock, Mendocino Co., Reed Ranch, Marin Co., and Blake Gardens, Sonoma Co., all from the Coast Range Region in California, were studied by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe analysis, and X-ray powder diffraction. The samples contain about 0.6, 1.0, and 1.4 wt% of total iron oxide, respectively. ⁵⁷Fe Mössbauer spectra are consistent with the assumption that high-spin Fe³⁺ substitutes for Al in the octahedrally coordinated site. The Mössbauer spectrum of lawsonite from Syke Rock exhibits a second doublet with ⁵⁷Fe hyperfine parameters typical for octahedrally coordinated high-spin Fe²⁺. Electronic structure calculations in the local spin density approximation yield quadrupole splittings for Fe³⁺ in quantitative agreement with experiment indicating, however, that substitution of Al by Fe³⁺ must be accompanied by local distortion around the octahedral site. Model calculations also reproduce the room temperature hyperfine parameters of ferrous high-spin iron assuming the substitution of Ca by Fe²⁺. However, it cannot be excluded that Fe²⁺ may occupy a more asymmetric site within the microstructural cavity occupied by Ca and a H₂O molecule.     

Lake Winnipeg: geological setting and sediment seismostratigraphy

Lake Winnipeg, the seventh largest lake in North America, is located at the boundary between the Interior Plains and the Canadian Shield in Manitoba, Canada. Seismic profiles were obtained in Lake Winnipeg on two geoscientific cruises in 1994 and 1996. These data indicate the morphology of the bedrock surface. In most cases, a clear distinction between low relief Paleozoic carbonate rock and high relief Precambrian rock can be made. In northern Lake Winnipeg, the eastern limit of Paleozoic rock is clearly demarcated 30 km west of the previous estimate of its position. In southern Lake Winnipeg, all or most of the Paleozoic sequence terminates at a prominent buried escarpment in the centre of the lake. This indicates that Paleozoic rock on the eastern shore, known from drilling and outcrops, is an outlier. Major moraines are apparent as abrupt, large ridges having a chaotic internal reflection pattern. These include the Pearson Reef Moraine, the George Island Moraine and the offshore extension of The Pas Moraine. Little evidence for extensive or thick till was observed. Instead, fine-grained sediments deposited in glacial Lake Agassiz rest directly on bedrock over most of the lake basin. Hence an episode of erosion to bedrock was associated with glaciation and/or deglaciation. The Agassiz Sequence sediments are well-stratified, drape underlying relief and in some areas are over 100 m thick. In places, stratification in these sediments is disrupted, perhaps by dewatering. Evidence of erosion of Agassiz Sequence sediments by recent currents was observed. The contact between the Agassiz Sequence and the overlying Winnipeg Sequence sediments is a marked angular unconformity. The Agassiz Unconformity indicates up to 10 m of erosion in places. The low-relief character of this unconformity precludes subaerial erosion and the lack of till, moraines, or extensive deformation precludes glacial erosion. Waves appear to be the most likely erosional agent, either in waning Lake Agassiz or early Lake Winnipeg time. Winnipeg Sequence sediments, in places very thin, mantle most of the lakefloor. These sediments were deposited in the present Lake Winnipeg and are faintly stratified to massive and reach about 10 m in thickness in deep water. On the surface of the Winnipeg Sequence, vigorous, episodic currents are thought to contribute to the construction of flow-transverse sand waves as much as 6 m high in a deep, narrow constriction in the lake.     

Spatial and temporal variation of sunshine in the Federal Republic of Germany

Summary The annual amount of sunshine during the 37-year period from 1951 through 1987 has been analyzed for 54 stations in the Federal Republic of Germany. Sunshine generally decreased during this period over the eastern half of the country and in the central German hills. For some stations, the loss amounts to more than 300 hours per year, more than 18% of total received sunshine. Mountain tops in the central German hills show the greatest decline; this may result from increased cyclonic episodes over Central Europe. The decrease in sunshine over central and northeastern Germany was not accompanied by increased precipitation, or by number of days of precipitation.With 5 Figures     

Zur Auswertung des ebenen Dreischichtenfalles in der Reflexionsseismik durch Potenzreihenentwicklung

Zusammenfassung Ein Verfahren zur Bestimmung der im Sinne der Methode der kleinsten Quadrate bestangepassten Schichtparameter an eine gemessene Laufzeitkurve wird angegeben. Es können höchstens drei Parameter berechnet werden, die drei übrigen Parameter müssen bekannt sein. Die Brechung wird exakt berücksichtigt. Das Verfahren ist für Berechnung durch Computer geeignet. Einfache Formeln gestatten eine angenäherte Bestimmung der unbekannten Parameter.

---

Summary A procedure for determining the best fitted parameters of a three layer case to a given travel time curve by the least squares method is described. At most three parameters can be calculated, the other three have to be known. Refraction is taken into account exactly. The calculations have to be made with the aid of a computer. The unknown parameters can be determined approximatively by simple formulas.

     

Alternative Validation of a LC-MS/MS-Multi-Method for Pesticides in Drinking Water

The development of instrumental analytics such as the LC-MS/MS has made it possible to quickly determine many component concentrations in a single chromatogram. However, the validation of such multi-methods needs new strategies for robustness and optimization. Statistical execution of analytical tests is one tool that can be utilized to meet this requirement. A Central Composite Design (CCD) was utilized for the validation of an LC-MS/MS multi-method for 84 analytes. The experimental design includes six design variables and two non-design variables (response variables). Concentration, ionization temperature, dwell time, gradient, flow (of eluent), and spraying/curtain gas (continuous design variables) were varied on five different levels; the whole design encompassed 91 runs. To investigate the robustness of a LC-MS/MS method both peak sensitivity and chromatographic separation had to be verified. Therefore, two non-design variables were necessary. The distribution of the peaks over analysis time was applied to describe the quality of the chromatographic separation. The sensitivity was described with the signal to noise ratio (S/N). The evaluation of the measured data was accomplished with the Analysis of Variance (ANOVA) and the Response Surface Methodology (RSM). Three main effects (concentration, ionization temperature, dwell time) and no significant interaction effect were found for the response variable “S/N”. The variables of concentration, ionization temperature, and dwell time had no significant effects for the response variable “S/N”. The ANOVA of the response variable chromatographic separation abandoned no significant effects as well. Therefore, robustness of the method can be guaranteed for all non significant design variables.