Experimental insights into the formation of high-Mg basaltic andesites in the trans-Mexican volcanic belt

High-Mg basaltic andesites and andesites occur in the central trans-Mexican volcanic belt, and their primitive geochemical characteristics suggest equilibration with mantle peridotite. These lavas may represent slab melts that reequilibrated with overlying peridotite or hydrous partial melts of a peridotite source. Here, we experimentally map the liquidus mineralogy for a high-Mg basaltic andesite (9.6 wt% MgO, 54.4 wt% SiO₂, Mg# = 75.3) as a function of temperature and H₂O content over a range of mantle wedge pressures. Our results permit equilibration of this composition with a harzburgite residue at relatively high water contents (>7 wt%) and low temperatures (1,080–1,150°C) at 11–14 kbar. However, in contrast to the high Ni contents characteristic of olivine phenocrysts in many such samples from central Mexico, those of olivine phenocrysts in our sample are more typical of mantle melts that have fractionated a small amount of olivine. To account for this and the possibility that the refractory mantle source may have had olivine more Fo-rich than Fo₉₀, we numerically evaluated alternative equilibration conditions, using our starting bulk composition adjusted to be in equilibrium with Fo₉₂ olivine. This shifts equilibration conditions to higher temperatures (1,180–1,250°C) at mantle wedge pressures (11–15 kbar) for H₂O contents (>3 wt%) comparable to those analyzed in olivine-hosted melt inclusions from this region. Comparison with geodynamic models shows that final equilibration occurred shallower than the peak temperature of the mantle wedge, suggesting that basaltic melts from the hottest part of the wedge reequilibrated with shallower mantle as they approached the Moho.     

The New SCIAMACHY Reference Solar Spectral Irradiance and Its Validation

This paper describes a new reference solar spectrum retrieved from measurements of the satellite instrument SCIAMACHY in the wavelength region from \(0.24~\upmu\mbox{m}\) to \(2.4~\upmu\mbox{m}\) and its comparison with several other established solar reference spectra. The SCIAMACHY reference spectrum was recorded early in the mission before substantial optical degradation due to the harsh space environment sets in. The radiometric calibration of SCIAMACHY, applied in this study, includes a physical model of the scanner unit. Furthermore, SCIAMACHY’s internal white light source (WLS) is used to correct for on-ground to in-flight changes. The resultant calibrated solar spectrum from SCIAMACHY is in good agreement with several available solar spectral irradiance (SSI) references in the visible spectral range. Strong throughput losses due to detector icing in the near infrared (NIR) are now adequately accounted for. Nevertheless, a deficit with respect to the ATLAS-3 composite and SORCE/SIM SSI is observed in the NIR. However, the SCIAMACHY solar reference spectrum agrees well with the recently re-evaluated SOLAR/SOLSPEC-ISS and recent ground measurements taken at Mauna Loa in the NIR.     

Effect of weather conditions on the incidence of Lophodermium yellow needle blight in the dwarf mountain pine in the Karkonosze and Izerskie Mountains (Poland)

The study aimed to determine, by using a statistical model, the effect of weather conditions on the incidence of Lophodermium yellow needle blight causing by new species for science- Lophodermium corconticum, in the mountain dwarf pine growing in the subalpine Karkonosze Mountains and the Izerskie Mountains(Poland). Needles showed symptoms of yellow spots, gradual discolouration and premature fall in July. The assessment of healthiness of infected mountain dwarf pine needles spanned three years(2011- 2013) and was conducted in several test sites in the Karkonosze and Izerskie Mountains. The results were analyzed by taking into account the meteorological conditions. Field observations seem to indicate that the highest infestation of mountain dwarf pine occurs in June and July, while September and October see a significantly lower disease index in the Karkonosze Mountains. The lower indices of the infestation of mountain dwarf pine are characteristic for the vegetation in the Hala Izerska high mountain pasture; whereas the environmental conditions prevailing in the Kocio? Ma?ego Stawu cirque and above the Samotnia hostel are conducive to the development of Lophodermium yellow needle blight.     

Comparison of atmospheric turbulence characteristics and turbulent fluxes from two urban sites in Essen, Germany

From September 2006 to September 2007, the intersite variability of turbulence characteristics and turbulent heat fluxes was analysed at two urban stations in Essen, Germany. One site was situated within an urban residential setting while the other was located at the border of an urban park and suburban/urban residential housing. Therefore, the surroundings at both sites contributing to surface–atmosphere exchange differed in terms of surface cover and surface morphology. During the 1-year measurement period, 19% of data were characterised by stable atmospheric stratification. Since observations of urban turbulence characteristics under stable stratification are scarce, so far, this work adds additional input to this discussion. Turbulence characteristics, i.e. normalised standard deviations of wind components, were in agreement to empirical fits from other urban observations under both instable and stable atmospheric stratification. However, differences in magnitude of turbulence characteristics between sites were observable. Comparison of turbulent heat fluxes indicated typical urban features in the site located in the urban setting with increased surface heating and higher surface heat fluxes by about 30%. Also the temporal evolution of heat fluxes on the diurnal course was affected. Differences in momentum flux were of minor magnitude with about 6% variation on average between sites. Findings indicate that multiple urban flux measurements within one city may be characterised by general similarities in terms of turbulent characteristics but are still significantly influenced by differences in the surface cover of the flux footprint.     

An evolutionary model of the western churchill province and western margin of the superior province in Canada and the North-Central United States

Regional-scale geophysical information, which includes aeromagnetic, gravity, seismic refraction, multi-channel seismic reflection and electromagnetic induction data, is used to extend our knowledge of the Canadian Shield beneath the Phanerozoic Williston basin of south-central Canada and the north-central United States. A new tectonic map based on this information shows the Proterozoic Flin Flon-Snow Lake and La Ronge-Lynn Lake volcanic island arcs and their associated fore-arc (Kisseynew belt) and back-arc (Reindeer-South Indian Lakes belt) basins wedged between the Archean Superior craton on the east and the Archean parts of the Churchill and Wyoming cratons on the west. Along the western margin of the Superior craton the Thompson nickel belt, including its extension southwards beneath the Williston basin, is interpreted to have been successively the site of continental rifting and rupturing, an evolving continental margin, a continent-volcanic island arc “suture” zone and eventually a continental-scale strike-slip fault. The North American Central Plains electrical conductivity anomaly and closely related seismic low-velocity zones are explained by the presence in the lower crust of buried slices of hydrated oceanic-type material, situated within the southward extension of the Reindeer-South Indian Lakes remnant back-arc basin and adjoining tectonic units. A new plate tectonic model is proposed for this region that involves the rifting and rupturing of the Archean continents and the opening and closing of one or more oceanic basins. This model is shown to be consistent with most of the geological, geophysical and geochronological data that pertains to the Proterozoic evolution of the exposed Shield and similar geophysical data and subsurface geochronological information from further south.     

Progress in understanding the age and origin of the alpha ridge, arctic ocean

Multiparameter geophysical measurements and geological samples from CESAR suggest that close to Canada the Alpha Ridge is oceanic in nature and was built in part by volcanic activity. It is unclear whether this part of the ridge formed in an intraplate or a plate margin environment. Estimates from paleontological, heat flow and magnetic data place the construction of a volcanic ridge within the Cretaceous period between about 120 and 80 Ma ago, the interval in which the Canada Basin seafloor formed but clearly before the creation of the Lomonosov Ridge. The place of the Makarov Basin in this chronology remains unclear.     

Lead(II) complexation by fulvic acid: how it differs from fulvic acid complexation of copper(II) and cadmium(II)

Pb²⁺, like Cu²⁺, forms strong complexes with fulvic acids (Cd²⁺-fulvate complexes are much weaker), but Pb-fulvate precipitates at a much lower mole ratio of metal ion to fulvic acid than either Cu-fulvate or Cd-fulvate does. Physical association of Pb²⁺ with Pb-fulvate solids as well as complexation by sites still available in the precipitates probably causes the increased removal of free Pb²⁺ from solution after precipitation begins.     

The drivers of Chinese CO2 emissions from 1980 to 2030

China's energy consumption doubled within the first 25 years of economic reforms initiated at the end of the 1970s, and doubled again in the past 5 years. It has resulted of a threefold CO₂ emissions increase since early of 1980s. China's heavy reliance on coal will make it the largest emitter of CO₂ in the world. By combining structural decomposition and input–output analysis we seek to assess the driving forces of China's CO₂ emissions from 1980 to 2030. In our reference scenario, production-related CO₂ emissions will increase another three times by 2030. Household consumption, capital investment and growth in exports will largely drive the increase in CO₂ emissions. Efficiency gains will be partially offset the projected increases in consumption, but our scenarios show that this will not be sufficient if China's consumption patterns converge to current US levels. Relying on efficiency improvements alone will not stabilize China's future emissions. Our scenarios show that even extremely optimistic assumptions of widespread installation of carbon dioxide capture and storage will only slow the increase in CO₂ emissions.     

Search for finite dimensional attractors in atmospheric turbulence

The question is investigated whether the dynamics of turbulent wind fields in the atmospheric boundary layer can be satisfactorily described by a low-dimensional deterministic system. Special emphasis is laid on the detection of a possibly existing, underlying strange attractor. Fast response wind measurements of an ultrasonic anemometer with a sampling rate of 21 Hz were carried out over periods of several days in the near surface boundary layer. The correlation dimension of the resulting time series, several million data points long, is estimated by means of the Grassberger-Procaccia algorithm. No sign of a low dimensional attractor can be detected. By comparison with different types of random noise, the existence of an attractor with dimension lower than six can be excluded in the present data sets.