Occurrence Forms of Carbon,Sulfur, and Noble Metals in Deposits of the Black-Shale Formation by the Example of the Degdekan Gold-Ore Deposit (Northeastern Russia)

Pyrite crystals and ore-bearing shales of the Degdekan deposit were studied by means of XPS, SEM–EDX, EPMA, and AAS. Five peaks of carbon organic forms were identified, conforming to polymer compounds containing either double bonds of carbon or alkyne groups and compounds containing C–OH and C=O bonds, as well as, probably, small amounts of S-containing compounds and those with functional groups of carboxylic acids. Sulfate prevails over sulfite in pyrites; among the surface sulfide forms, disulfide prevails over monosulfide; the presence of polysulfide is registered. The occurrence of various chemical forms of sulfur on the surface might provide for concentrating of microelements including the noble metals (NMs) in their surface-bound forms. The regular behavior of NMs (Au, Pt, Pd, and Ru) depending on the grain sizes (specific surfaces) of pyrite crystals along with the narrow range of the ratios of structural and surface components of the concentrations of different NMs points to NM coprecipitation with pyrite during the same productive stage. No capture of NM-containing carbonaceous phases took place, which should violate the regularity of Au distribution in pyrites of the Sukhoi Log deposit.     

<Superscript>230</Superscript>Th/U Chronology and Geochemistry of Irinovskoe Hydrothermal Field (Mid-Atlantic Ridge)

The results of ²³⁰Th/U dating and mineralogical–geochemical studies of sulfide ores from the Irinovskoe hydrothermal field and the Severo-Zapadnoe ore occurrence (Mid-Atlantic Ridge) are presented. Sulfides are represented primarily by copper–sulfide ores with 12–30% Cu content; sulfur- and zinc-sulfide ores are distributed less frequently. The analysis of a change in the composition of sulfides over time has made it possible to identify three stages of formation. Each stage assumes that mineral associations are changed from high-temperature (sulfur and copper sulfide) to medium temperature (Zn–Cu and Zn-sulfide) sulfide ores. The whole age range of formation of the hydrothermal deposits falls within the time interval of about 58000–8000 for the Irinovskoe field and 69000–11000 years ago for the Severo-Zapadnoe ore occurrence.     

Arcanite from Fumarole Exhalations of the Tolbachik Volcano (Kamchatka,Russia) and Its Crystal Structure

The crystal structure (R = 0.0194) of arcanite β-K₂SO₄ was studied on a single crystal from exhalations of the Arsenatnaya fumarole, Tolbachik Volcano (Kamchatka, Russia). The mineral crystallizes at a temperature of ≥350–430°C and associates with langbeinite, aphthitalite, hematite, tenorite, johillerite, and others. Arcanite is orthorhombic, Pnma, a = 7.4763(2) Å, b = 5.77262(16) Å, c = 10.0630(3) Å, V = 434.30(2) ų, Z = 4. Its structure contains isolated SO₄ tetrahedra, whereas K cations center ten- and nine-fold polyhedra.     

First Results of U–Pb LA–ICP–MS Isotope Dating of Detrital Zircons from Arkose Sandstone of the Biryan Subformation of Zilmerdak Formation (Upper Riphean,South Urals)

Detrital zircons (DZs) from arkose sandstones of the Upper Riphean Zilmerdak Formation (Southern Urals) yielded ages in the range of 3039–964 Ma. Grains with Late Karelian and Early and Middle Riphean ages compose 35, 34, and 26% of the total number of the analyzed zircons, respectively. This is similar to the age spectra of the Vendian sandstones (Asha Group), but it differs significantly from the age distribution typical of the Riphean stratotype sandstones.     

Cambrian Magmatism in the Northern Urals: New Data on the Age and Formation Conditions

Cambrian igneous formations in the Northern Urals were identified and described for the first time. It was established that the Timanide orogeny terminated in the Early Cambrian and was followed by continental rifting above a mantle plume in the Late Cambrian.     

Formation of Water-Bearing Defects in Olivine in the Presence of Water–Hydrocarbon Fluid at 6.3 GPa and 1200°C

The main trends of water dissolution in Fe-bearing olivine have been investigated in the olivine–H₂O–hydrocarbon fluid system in experiments at a pressure of 6.3 GPa, a temperature of 1200°C, and hydrogen fugacity ( fH₂) buffered by the Mo–MoO₂ equilibrium. The content and contribution of ОH defects of different types in Fe-bearing olivines depend on the composition of reduced fluids in the system. As the fraction of hydrocarbons in the fluid increases, the H₂O content in olivine crystals decreases from 900 to 160–180 ppm, while the ОН absorption peaks become lower at high frequencies and occupy a larger part of the infrared spectrum in the low-frequency region. According to the experimental results, even the deepest seated mantle olivines with OH defects were not equilibrated with a fluid rich in light alkanes or oxygenated hydrocarbons.     

Foidite and Meimechite Lavas of Polar Siberia (Some Questions of Petrogenesis)

Doklady Earth Sciences - For the Permian–Triassic foidite and meimechite lavas of Polar Siberia, both the whole-rock petrochemistry and geochemistry and that of melt inclusions in olivine...     

The Deep Geoelectrical Section of the Avacha–Koryak Zone of Contemporary Volcanism,Kamchatka

The methods and results of magnetotelluric sounding in the range of 0.0001–1000 s and more with the use small portable magnetotelluric stations are considered. Data on the distribution of electrical conductivity at depths beneath the Avacha–Koryak zone of contemporary volcanism are obtained. The obtained data are interpreted using the modern techniques and methods.