Quantifying hydrogen‐deuterium exchange of meteoritic dicarboxylic acids during aqueous extraction

Abstract— Hydrogen isotope ratios of organic compounds in carbonaceous chondrites provide critical information about their origins and evolutionary history. However, because many of these compounds are obtained by aqueous extraction, the degree of hydrogen‐deuterium (H/D) exchange that occurs during the process needs to be quantitatively evaluated. This study uses compound‐specific hydrogen isotopic analysis to quantify the H/D exchange during aqueous extraction. Three common meteoritic dicarboxylic acids (succinic, glutaric, and 2‐methyl glutaric acids) were refluxed under conditions simulating the extraction process. Changes in δD values of the dicarboxylic acids were measured following the reflux experiments. A pseudo‐first order rate law was used to model the H/D exchange rates which were then used to calculate the isotope exchange resulting from aqueous extraction. The degree of H/D exchange varies as a result of differences in molecular structure, the alkalinity of the extraction solution and presence/absence of meteorite powder. However, our model indicates that succinic, glutaric, and 2‐methyl glutaric acids with a δD of 1800%***_o would experience isotope changes of 38_o, 10_o, and 6_o, respectively during the extraction process. Therefore, the overall change in δD values of the dicarboxylic acids during the aqueous extraction process is negligible. We also demonstrate that H/D exchange occurs on the chiral α‐carbon in 2‐methyl glutaric acid. The results suggest that the racemic mixture of 2‐methyl glutaric acid in the Tagish Lake meteorite could result from post‐synthesis aqueous alteration. The approach employed in this study can also be used to quantify H/D exchange for other important meteoritic compounds such as amino acids.     

Geological environment conflicts of Kunming Basin and its urban sustainable development

Kunming Basin locates middle of Yunnan altiplano and has a particularity in geography,topographic and geological environment.With the urban dilation quickly,add the reason of the unreasonable city layout,conflicts between environment and urban resources consumption become shrill increasingly.It is human being activities that lead to vulnerability and depravation of geological environment in local.Take a few examples on geological environment to expatiate relationship between urban construction and geological environment carrying capacity,and find a way how to make a better plan for urban sustainable development to achieve new balance between man and nature in local.     

超基性岩中含铜、钴块状硫化物矿床——德尔尼铜矿成因新认识

长期以来对德尔尼铜矿的成因存在着不同认识。从矿石组成和结构、构造来看,应属典型的块状硫化物矿石,矿床亦应属于含铜黄铁矿型矿床。但从其地质产状来看又与一般的黄铁矿型矿床大不相同,与一般的岩浆熔离铜镍硫化物矿床也有较多差异。这就是本矿床类型独特之处。近年来通过工作又取得一些新资料,特别是超基性岩和矿石的同位素年龄数据。本文在综合新老资料基础上,提出新看法,认为该矿床形成于上地幔,再就位于地壳浅部。其成因类型暂定为:“深部熔离—构造侵位矿床”。鉴于本矿床与一般块状硫化物矿床相比有其独特性,建议命名为“德尔尼型”。     

柴达木盆地东北缘古元古代变质镁铁—超镁铁质岩的地质特征及成因探讨

1:5万区域地质调查工作中,在柴达木陆块北缘首次发现古元古代变质镁铁—超镁铁质岩,获得成岩年龄为1952±15Ma,其岩石化学、地球化学特征反映出岩浆来源于亏损地幔,反映出该地区克拉通在古元古代(19亿年)发生了一次强烈的裂解(洋)事件,对于研究柴达木盆地北缘元古代结晶基底地质构造演化及进一步探讨柴达木盆地的起源及构造演化过程提供了重要地质线索。     

富氏谱分析法模拟地壳垂直运动的地学依据及其策应力模型

应用地壳波浪与镶嵌构造学说对富氏谱分析法提取地壳垂直形变信息的科学性做了地质学意义上的阐释 ,并提出了根据多期形变资料提取特定波段上构造策应力的数学模型     

贵州织金煤矿区龙潭组岩石特征及其意义

织金矿区含煤地层为上二叠统龙潭组,含主要可采煤6层.煤系地层以含玄武岩屑、海绿石为特征的5类碎屑岩夹碳酸盐岩,水平、沙纹、波状层理发育,煤系中稳定的灰岩、硅铁质灰岩标志层较多,有利于煤层的划分与对比,并产丰富的动植物化石及碎块.属海、陆交替环境下的标型海陆交互相沉积.     

NORTHERN AND SOUTHERN HEMISPHERIC POLAR LOWS——A COMPARATIVE STUDY

Northern Hemispheric“polar lows”,i.e.maritime,small,but fairly intense cyclonic systems have been studied formore than two decades.Recently researchers have turned their attention towards the occurrence of polar lows and othersmall-scale cyclonic disturbances on the Southern Hemisphere.In this paper a short account of our present knowledgeof Northern Hemispheric polar lows will be given,followed by some preliminary results of an investigation of the natureand occurrence of polar lows on the Southern Hemisphere.     

广西森林旅游资源的特色及其开发意义

广西森林旅游资源多达 816 .7万hm2 ,景点 2 80个 ,内容丰富 ,前景广阔 ,加强广西森林旅游资源特色的开发 ,有利于促进广西旅游业可持续发展 ,有利于经济、社会、环境效益的提高及人们的文化素质和生活质量的提高。     

K-H Instability of Dust Plasma

Areview about K-H instability related to comet tail is presented.The effect of dust graing on KHI is theoretically analysed and relations of critical shear to excit KHI with the properties of dust grains both for sheared ion flow and for sheared dust flow re put out.Their possible application in comet tail is suggested.