Field Evaluation of the Effectiveness of Surfactant Modified Zeolite and Iron-Oxide-Coated Sand for Removing Viruses and Bacteria from Ground Water

Field experiments were conducted to evaluate the efficiency of iron-oxide-coated sand (ICS) and surfactant modified zeolite (SMZ) to remove viruses and bacteria from ground water. The reactive media were employed as filter packs of a pumping well that withdrew sewage effluent from a constructed wetland at a rate of 0.72 L/min. The contact time of the pumped water with the filter pack (10 cm thick) was about two minutes. Upgradient of the pumping well, the sewage effluent was spiked with MS-2 bacteriophage and E. coli. While the employed ICS filter pack failed to remove viruses and bacteria to a significant degree, the SMZ filter pack removed more than 99% of the viruses and 100% of E. coli from the ground water while fresh. In an additional field experiment using the same configuration but leaving the filter pack in place for more than five months, the SMZ filter pack was still removing 100% of E. coli , but failed to reduce virus numbers to a significant degree.     

Mechanisms of oxygen isotopic exchange and isotopic evolution of <Superscript>18</Superscript>O/<Superscript>16</Superscript>O-depleted periclase zone marbles in the Alta aureole,Utah: insights from ion microprobe analysis of calcite

Oxygen isotope ratios have been measured by ion microprobe and millimeter-scale dental drill along detailed sampling traverses across the boundary between periclase-bearing (δ¹⁸O = 11.8‰) and periclase-free (δ¹⁸O = 17.2‰) marble layers in the periclase (Per) zone of the Alta Stock aureole, Utah. These data define a steep, coherent gradient in δ¹⁸O that is displaced a short distance (~4 cm) into the periclase-free (Cal + Fo) layer. SEM and ion microprobe analyses show two isotopically and texturally distinct types of calcite at the grain scale. Clear (well polished) calcite grains are isotopically homogeneous (within analytical uncertainty; ±0.27‰, 2SD). More poorly polished (pitted), texturally retrograde ‘turbid’-looking calcite has lower and more variable δ¹⁸O values, and replaces clear calcite along fractures, cleavage traces or grain boundaries. Despite significant lowering of the δ¹⁸O values in calcite throughout both layers during prograde metamorphism, ion microprobe analyses indicate that individual clear calcite grains are now isotopically homogeneous across the entire gradient in δ¹⁸O. Diffusion calculations indicate that conservative time scales required for isotopic homogenization of calcite grains by volume diffusion, 30,000–62,000 years at 575–600°C, exceed significantly the timescale (~1,250 years) estimated for the prograde development of the δ¹⁸O gradient at the boundary between these two marble layers. The ion microprobe data and these diffusion calculations suggest instead that surface reaction mechanisms accompanying recrystallization are responsible for the observed oxygen isotope homogeneity of these calcite grains. Thus, the ion microprobe data are consistent with the formation of calcite in oxygen isotope exchange equilibrium with infiltrating fluid during prograde reaction and recrystallization. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Resilience through interlinkage: the green climate fund and climate finance governance

The Green Climate Fund (GCF) is a significant and potentially innovative addition to UNFCCC frameworks for mobilizing increased finance for climate change mitigation and adaptation. Yet the GCF faces challenges of operationalization not only as a relatively new international fund but also as a result of US President Trump’s announcement that the United States would withdraw from the Paris Agreement. Consequently the GCF faces a major reduction in actual funding contributions and also governance challenges at the levels of its Board and the UNFCCC Conference of the Parties (COP), to which it is ultimately accountable. This article analyzes these challenges with reference to the GCF’s internal regulations and its agreements with third parties to demonstrate how exploiting design features of the GCF could strengthen its resilience in the face of such challenges. These features include linkages with UNFCCC constituted bodies, particularly the Technology Mechanism, and enhanced engagement with non-Party stakeholders, especially through its Private Sector Facility. The article posits that deepening GCF interlinkages would increase both the coherence of climate finance governance and the GCF’s ability to contribute to ambitious climate action in uncertain times.

Key policy insights

• The Trump Administration’s purported withdrawal from the Paris Agreement creates challenges for the GCF operating model in three key domains: capitalization, governance and guidance.

• Two emerging innovations could prove crucial in GCF resilience to fulfil its role in Paris Agreement implementation: (1) interlinkages with other UNFCCC bodies, especially the Technology Mechanism; and (2) engagement with non-Party stakeholders, especially private sector actors such as large US investors and financiers.

• There is also an emerging soft role for the GCF as interlocutor between policy-makers and non-Party actors to help bridge the communication divide that often plagues cross-sectoral interactions.

• This role could develop through: (a) the GCF tripartite interface between the Private Sector Facility, Accredited Entities and National Designated Authorities; and (b) strengthened collaborations between the UNFCCC Technical and Financial Mechanisms.