江西铜坑嶂钼矿和红山铜矿含矿斑岩锆石U-Pb定年及其地质意义

江西铜坑嶂钼矿和红山铜矿是在武夷山成矿带中最近发现的两个斑岩型矿床。本文利用LA-ICP-MS锆石U-Pb定年方法对铜坑嶂花岗斑岩和红山含矿花岗斑岩分别进行了年代学研究,获得铜坑嶂岩体中花岗斑岩的锆石年龄为138±1Ma,代表斑岩体侵位的年龄;红山矿区含矿斑岩的锆石年龄,分作两期,分别为99Ma和49Ma,两期不同的年龄可能代表了两期热事件。研究表明,铜坑嶂钼矿的成岩成矿时代均发生在白垩纪,其岩浆作用与成矿作用基本吻合。综合前人资料,认为铜坑嶂钼矿区的斑岩和红山铜矿区的斑岩可能分别形成于大陆弧后伸展带和岩石圈伸展环境。     

Late tortonian—lower messinian (miocene) palaeogeography of SE Sicily: information from two new formations of the sorting group

A thick volcanoclastic, biohermal and lagoonal sequence of strata succeeds the Siracusa Limestone Member (Monti Climiti Formation) of SE Sicily. This overlying sequence may be divided into two new formations on the basis of lithostratigraphy, petrology and palaeontology. The older formation, here named the Carlentini Formation, is predominantly a thick volcanoclastic sequence but with two intervening carbonate horizons. Faunas are rare within the volcanic strata but may be abundant and associated with corals and patch-reefs within the two carbonate levels.The younger formation, here named the Monte Carrubba Formation, is almost exclusively composed of oolitic grainstones and lagoonal wackestones. Peritidal carbonates are developed in the northeast of the area. Faunas are frequently of low diversity. Euryhaline mollusc associations are dominant, although Pecten vigolenesis occurs in the lower beds.Collectively the new formations span the late Tortonian—lower Messinian time interval and may be correlated with the Calcare di Base of the main sicilian basin to the west.The palaeoenvironmental reconstruction suggests that both formations were deposited around the SW margins to a low island or landmass lying to the north of the Hyblean region.     

Suitability of monosaccharides as markers for particle identification in carbonate sediments*†

The identification of the remains of organisms contributing to carbonate sediments by means of scanning electron-microscopy is limited to particles of the 2–20 μm size class. Mineralogy and the content of Mg, Sr and trace elements alone are usually insufficient to solve the problem of identification, especially in the differentiation between algal and coral aragonite. The organic matrix of calcareous organisms consists of stable biopolymers such as polysaccharides and glycoproteins which are intimately associated with the carbonate skeleton. Analysis of these hydrolysed compounds gives rise to characteristic arrays of monosaccharides which provide independent criteria for producer identification. The calcareous green algae Halimeda, Penicillus and Udotea show high xylose and low fucose levels. Xylose and fucose levels are elevated in the red algae Amphiroa but only fucose is prominent in the brown algae Padina. The corals Oculina, Porites, Millipora and Montastrea are relatively rich in fucose and show little or no xylose. In the bivalves Arca, Codakia and in Argopecten mannose may be characteristic. Analysis of artificial and natural sediments demonstrates that coral and algal aragonite can be distinguished on the basis of the total sugar concentration and respective xylose and fucose levels. The applicability of the technique in comparison to geochemical and mineralogical methods has been demonstrated for surface sediments from varying water depths of Harrington Sound, Bermuda.     

Lithofacies modelling and sequence stratigraphy in microtidal cool-water carbonates: a case study from the Pleistocene of Sicily, Italy

ABSTRACT Quaternary carbonates in SE Sicily were deposited in seamount and short ramp settings during glacio‐eustatically driven highstand conditions. They provide an excellent opportunity to investigate the depositional and erosional aspects of cool‐water carbonate sedimentation in a microtidal marine water body. The derived ramp facies model differs significantly from modern‐day, open‐ocean ramp scenarios in projected facies depth ranges and in the preservation of inshore facies. A sequence stratigraphic study of the carbonates has confirmed many established aspects of carbonate sedimentation (e.g. production usually only occurred during highstands). It has also revealed several new features peculiar to water bodies with little tidal influence, including ‘catch‐up’ surfaces taking the place of transgressive facies, second‐order sequence boundary events being most important as triggers for initiating resedimentation and a virtual absence of sediment shedding to the basin during the terminal lowstand. Production in the carbonate factory lasted for about 0·5 Myr. Despite this, carbonate production was considerable and included both bioconstructional and bioclastic‐dominated facies and the production of abundant lime muds. A model for eustatically controlled cool‐water carbonate production and resedimentation in microtidal marine water bodies is presented. This is considered to be more applicable to Neogene and Quaternary strata in the Mediterranean region than are current open‐ocean models.     

Stable hydrogen isotopes in iron oxides—II. DH variations among natural goethites

Goethite samples analyzed for this study have a δD range from ?202 to ?98 per mil with a corresponding δD range of associated waters from about ?110 to +7 per mil. Goethites with the most positive δD values are from marine environments. Goethite-water equilibrium $\text{D}\text{H}$ fractionation factors measured in this laboratory at 100°C and 145°C and estimated for sedimentary temperatures from data on natural samples have values of about 0.900 at all three temperatures. These data suggest that goethite δD values may be a direct, temperature-independent measure of the δD values of the waters with which the goethite last equilibrated. Most of the goethite δD values in this study reflect the δD values of the modern waters in the locales of origin.Substitution of Mn and/or Al for Fe in the goethite structure may affect the mineral-water fractionation factor. Manganese appears to decrease the value of α. The effect of Al substitution on α has not yet been measured, but preliminary arguments suggest that increasing Al content could increase α values.     

Sedimentology of Quaternary perched springline and paludal tufas: criteria for recognition, with examples from Guadalajara Province, Spain

Outcrop‐scale geometries and bed relationships of ambient temperature freshwater carbonates are poorly understood because many described tufas have been dismantled by erosion and present only part of a particular depositional model. At the field scale, four end‐member models encompass the tufa continuum: (1) perched springline; (2) paludal; (3) fluvial; and (4) lacustrine tufas. Individual bed types can occur with variable dominance within several of these models, but one or more beds are characteristically dominant only within a single tufa model, so it can be differentiated from relatively isolated outcrop fragments. Two models (perched springline tufas and paludal tufas) are known in outline only in the literature despite being present within the Quaternary deposits of most karstic regions. Perched springline tufas generally form lobate, fan‐shaped mound morphologies on hillslopes and develop from single or multiple spring resurgences. Mature deposits show a subhorizontal top and a steep face on the downflow side. The steep outer zones of tufa mounds may be developed into cascades with moss curtains or can be dominated by shallow rimstone pools according to face angle. Tufa deposits lying downslope of the mounds are usually detrital in nature, especially if some dismantling of the mound has occurred. The relatively thin subhorizontal lobe‐top deposits commonly contain organic‐rich deposits. Paludal tufas develop predominantly in waterlogged valley bottom situations, where line‐sourced waters emerge from valley side and bottom aquifers. Lime mud precipitation predominates in these sites. Mud is deposited as subhorizontal laminites that thin towards the valley axis and downstream of resurgences. Tufa spring‐mounds may form where lesser volumes of water are involved. Individual tussocks (phytoherm cushions) of grasses and rushes are the most diagnostic feature of the model, but sapropels and peats may be intercalated. Diagenesis in both models is rapid. Lithification of individual beds is virtually instantaneous and always occurs before the decay of the associated living vegetation. The resulting highly porous and permeable fabrics remain fresh in Holocene tufas, but aggrading neomorphism and partial spar infill of vegetation moulds is common in older deposits. Dissolution in many perched springline tufas is small scale. Many large cavities are primary, but with later coatings of speleothems. Early removal of organics from paludal tufas is responsible for autobrecciation and differential compaction.