Provenance and diagenesis of organic matter in Late Cretaceous and Tertiary sediments from the southern Black Sea margin

The organic matter in the Late Cretaceous and Tertiary sediments from the southern Black Sea margin is assigned to the terrestrial-marine/terrestrial range of organic facies. Within this range, the stratigraphic section yields different organic facies types in response to different accumulation and preservation controlling processes. During the Late Companian-Maastrichtian, organic material from the shelf and slope was re-deposited in the deeper oxic parts of the basin. Rapid transport and sedimentation resulted in a higher degree of preservation of lipid-rich, terrestrial components (sporinite, cutinite, resinite) in comparison to the autochthonous sediments. The increase in organic carbon with increasing silt/clay content together with low carbon concentrations in the allochthonous sediments suggest that the accumulation of organic matter in the source areas was controlled by terrigenous influx and that the accumulation conditions were not favorable.In the Eocene (fore-arc basin), the higher content of marine organic matter can be explained by progressive shallowing of the environment and by reduced oxygen content in the bottom waters (reduced bioturbation).In the Miocene and Pliocene (back-arc basin), the organic fraction of the sediments from the basin margin is purely terrestrial and consists mostly of inertinite and reworked terrigenous liptinite indicating oxidative conditions. The dominance of inertodetrinite in the Miocene and of semifusinite in the Pliocene point to a change in the source area or to a higher energy transport or deposition conditions for the Miocene marginal sediments. In the basin interior, the higher content of marine organic matter is due to an oxygen deficiency or anoxic conditions in the bottom waters. Mineral associations indicate complete sulfate reduction and consequent methanogenesis. This is also implied in the hydrocarbon distributions. Periodic oxic conditions lead to a decrease in the marine liptinitic component. In the basin interior, however, the terrigenous fraction is still dominant, implying a continuous influx from the basin margins.The Late Cretaceous to Pliocene sediments are thermally immature (Rm<0.5%, T_max<435 °C).

---

Zusammenfassung Die organische Substanz in den Sedimenten der Oberkreide und des Tertiärs der südlichen Schwarzmeerregion ist dem terrestrischen bis marin-terrestrischen Bereich organischer Fazies zuzuordnen. Innerhalb dieses Bereiches weisen die stratigraphischen Abschnitte unterschiedliche organische Faziestypen auf, die auf unterschiedliche, die Akkumulation und den Erhaltungsgrad der organischen Substanz kontrollierende Prozesse zurückzuführen sind.Während des Obercampan-Maastrichtiums und des Paläozäns (fore-arc Becken) wurde organisches Material des Schelf/-hanges in den tieferen oxischen Beckenbereichen resedimentiert. Die rasche Zufuhr und Ablagerung führte zu einem gegenüber den autochthonen Sedimenten höheren Erhaltungsgrad an lipidreichen, terrestrischen Komponenten (Sporinit, Cutinit, Resinit). Die Zunahme an organischem Kohlenstoff mit steigendem Silt-/Tonanteil bei insgesamt niedrigen Kohlenstoffkonzentrationen in den Resedimenten läßt vermuten, daß die Akkumulation organischer Substanz in den Liefergebieten durch terrigene Zufuhr bestimmt wurde und die Akkumulationsbedingungen ungünstig waren.Für das Eozän ist ein erhöhter Eintrag an marinem organischem Material zu verzeichnen, der mit der zunehmenden Verflachung des Ablagerungsraumes (fore-arc Becken) und einer Reduzierung im Sauerstoffgehalt des Bodenwassers (abnehmende Bioturbation) erklärt wird.Für das Miozän und Pliozän (back-arc Becken) ist die organische Fraktion der Ablagerungen des Beckenrandes rein terrestrisch und besteht zum größten Teil aus Inertinit und wieder aufgearbeitetem terrigenem Liptinit, die oxidative Verhältnisse anzeigen. Die Dominanz von Inertodetrinit im Miozän und Semifusinit im Pliozän indiziert eine Änderung im Liefergebiet oder ein höheres Energieniveau beim Transport bzw. im Ablagerungsraum der miozänen Randsedimente. Im Beckeninneren ist ein erhöhter Anteil an mariner organischer Substanz festzustellen, der auf Sauerstoffverarmung oder anoxische Verhältnisse im Bodenwasser zurückgeführt wird. Die Mineralassoziationen in den Sedimenten weisen auf vollständige Sulfatreduktion und nachfolgende Methanogenese hin, die sich auch mit den Kohlenwasserstoffverteilungen nachvollziehen läßt. Periodisch oxische Bedingungen führen zu einer Reduzierung der marin-liptinitischen Komponente. Im Beckeninneren dominiert jedoch auch die terrigene Fraktion (Huminit/Vitrinit, Inertinit), was auf kontinuierliche Zufuhr vom Beckenrand schließen läßt.Die Sedimente der Oberkreide bis Pliozän sind thermisch unreif (Rm<0.5%, T_max<435 °C).

---

Résumé La matière organique contenue dans les sédiments du Crétacé supérieur et du Tertiaire de la partie sud de la Mer Noire est à rapporter au domaine de facies organique terrestre à marin-terrestre. La série stratigraphique présente, dans les limites de ce domaine, divers types de facies organiques qui traduisent les divers processus qui régissent l'accumulation et la préservation.Au cours du Campanian supérieur-Maastrichtien, des matériaux organiques provenant du shelf et du talus continental ont été redéposés dans les parties oxygénées plus profondes du bassin. La rapidité du transport et de la sédimentation a entraîné la préservation de composants terrestres riches en lipides (sporonite, cutinite, résinite), dans une mesure plus élevée que dans les sédiments autochtones. L'augmentation de la teneur en carbone organique corrélative à celle de la fraction fine (boue et silt), de même que la faible concentration en carbone des sédiments allochtones indique que, dans la région-source, l'accumulation de matières organiques était régie par un afflux terrigène et que les conditions d'accumulation n'étaient pas favorables.A l'Eocène (bassin d'avant-arc) le contenu en matière organique marine est plus élevé, ce qui s'explique par la diminution progressive de la profondeur et par la réduction de la teneur en oxygène des eaux du fond (bioturbation réduite).Au Miocène et au Pliocène (bassin d'arrière-arc), la fraction organique des sédiments de la bordure du bassin est purement terrestre et consiste principalement en inertinite et en liptinite terrigène remaniée, ce qui indique des conditions oxydantes. La prédominance d'inertodétrinite au Miocène et de semifusinite au Pliocène indique soit une source différente, soit un transport ou un dépôt dans les conditions de plus haute énergie des sédiments miocènes marginaux. Vers l'intérieur du bassin, le contenu plus élevé en matière organique marine est dû à une déficience en oxygène ou à des conditions anoxiques dans les eaux de fond. Les associations minérales indiquent une réduction complète des sulfates et en conséquence une méthanogenèse, ce qui ressort également de la distribution des hydrocarbures. Des conditions oxydantes périodiques provoquent une diminution du composant liptinitique marin. Dans l'intérieur du bassin, toutefois, la fraction terrigène reste dominante, ce qui implique un afflux continu depuis les marges du bassin.Les sédiments d'âge crétacé supérieur à pliocène sont thermiquement immatures (Rm<0,5%; Tmax<435 °C).

---

, , - . , , . - , . , ( , , ), . , , . , (force-arc Basin) ( ). (back-arc Basin) , . , , . , , . , . . ( , ), . : (Rm<0,5 %; T_max<435° ).

     

Steady state rocking response of rigid blocks part 2: Experiment

The results of an experimental investigation on the rocking response of rigid blocks subjected to sinusoidal base motion is presented. It is shown that two common types of steady state response are harmonic and 1/3 subharmonic response. The measured steady state response amplitudes correlate well with theoretical predictions for both harmonic and 1/3 subharmonic responses. Within each type of steady state response, theoretical studies show that the system may respond in either a symmetric or an unsymmetric mode. A symmetric mode denotes that the block oscillates about a mean zero position while an unsymmetric mode implies the mean position of oscillation is at an inclined position. One form of unsymmetric response was observed in the experiment. In addition, almost periodic responses were also observed in the experiment, although their existence has not been reported in theoretical studies.     

Prediction of the spatial distribution of the modified mercalli intensity using neural networks

This paper presents the development of an adaptive, non-parametric forecast model for the direct prediction of the spatial distribution of the Modified Mercalli Intensity (MMI) corresponding to an earthquake scenario. The model is based on recent advances in neural networks computation, and is constructed through supervised learning using historical earthquake and regional geological data as training sets. A MMI forecast model for moderate earthquakes with magnitudes between 6 and 7 was developed based on data from the Loma Prieta, Coalinga and Morgan Hill earthquakes. For these data sets, the neural networks forecast model is shown to have excellent data synthesis capability; multiple sets of data can be encapsulated by a relatively simple network architecture. Limited comparison of forecasts made by the neural networks model and conventional models demonstrates that improved accuracy can be achieved. Implementation and operational advantages of the neural networks approach such as general input features, minimum preconceived knowledge of the data sets, the ability to learn and to adapt incrementally and the autonomous and automatic synthesis of the structure underlying the data sets, have been illustrated.     

粤北凡口铅锌矿床的成因、成矿时代、成矿模式与找矿

作者运用构造与成矿结合，矿化与蚀变统一的观点，并以矿物学理论方法为主要手段，对凡口铅锌矿床进行综合研究，认为该矿床属同构造热液充填交代成因．它在国内外铅锌矿床中，是一种新的矿床成因类型，与燕山早期的构造－岩浆活动有着密切联系．     

Pattern analysis on mixed-mode hydrometric data

This paper presents a pattern analysis technique that has been successfully applied to a set of hydrometric network data collected in British Columbia, Canada. This technique can extract information from a set of observed heterogeneous multivariate data. The data are represented as n-tuples of mixed discrete and continuous values. The technique is capable of screening out statistically irrelevant information. It is also able to detect inherent subgroups in the data through adopting an event-covering approach. The subgroup characteristics represent important empirical understanding even though there may be considerable probabilistic variation within each individual subgroup.     

Seismic response of foundations embedded in a layered half-space

An integral equation technique to determine the response of foundations embedded in a layered viscoelastic half-space when subjected to various types of seismic waves is presented. The technique is validated by comparison with previous results for rigid hemispherical and cylindrical foundations embedded in a uniform half-space. Illustrative results for rigid cylindrical foundations embedded in layered media are also presented.     

Hierarchical aggregation in percolation model

There is a growing belief that the complex dynamics of seismicity can be better understood by studying the collective behavior of numerous lithosphere instability sources rather than focusing on the details of each of them. Classical site-percolation is a simple and tractable model which exhibits such important general features of complex systems as criticality and phase transitions of second kind. It also illustrates the mechanism of hierarchical aggregation, which is very important for explaining collective phenomena in material fracture and earthquake nucleation processes. We study the dynamics of a 2D site percolation model on a square lattice using the hierarchical approach introduced by Gabrielov et al., Phys. Rev. E., 5293–5300, 1999. The key elements of the approach are the tree representation of clusters and the Horton–Strahler scheme for cluster ranking. Accordingly, the evolution of percolation model is considered as a hierarchical inverse cascade of cluster aggregation. We analyzed the growth of the percolation cluster and established the time-dependent rank distribution of its subclusters, as well as corresponding laws for its mass, rank, and their relationship. We report several phenomena premonitory to the onset of percolation that complement the traditional power-law increase of the model's observables. In addition, we have shown that the Tokunaga side-branching constraint uniquely determines the mass–rank relationship for a general aggregation process (not necessarily originated from the percolation model). The results can be used for development and improvement of earthquake prediction techniques.