Fracture induced emission of alkali atoms from feldspar

Emission of neutral atoms (K and Na) and molecules (H₂O and KOH) observed during fracture of K-feldspar have been accounted for by two independent mechanisms. H₂O and KOH emissions are attributed to the venting of fluid-filled inclusions, while emission of atomic K is due to surface effects accompanying cleavage of crystalline feldspar. The intensity of emitted potassium, at least 6 × 10¹⁴ atoms/cm² of surface area, is sufficient to affect K activities in solution during microbrecciation in the presence of rock-dominated fluids.     

THE TROPICS: ENVIRONMENTS AND HUMAN IMPACTS UNDERSTOOD AND REINTERPRETED

In the 1950s, few people had travelled widely through different parts of the tropics and interpretations on tropical landforms, soils, vegetation and climate largely rested on impressions gained from residence or long sojourns in particular tropical countries. Most academic geography on the tropics was then written by expatriates and lacked the perspective gained from long experience of tropical regions. Particular problems of understanding arose as people attempted to extrapolate from one part of the tropics to another. Since then, understanding has advanced enormously, largely through the efforts of tropical scientists working in their own institutions and through the greater technological ability to study tropical lands both remotely and through easier field access. The establishment of a number of field stations, aimed primarily at the biological sciences, but also facilitating the work of geographers, has been a major stimulus to this effort. Concerns over practical issues, particularly local development and global climatic change have prompted new avenues of research, many of which have been assisted by the great increase in data collection in tropical countries. For the future, South-South dialogue between tropical physical geographers is needed to improve their ability to ask meaningful questions so that they can contribute to teach the rest of their discipline more about serious applied and applicable geography.     

Rain rates based on SSM/I,OLR and raingauge data sets

Summary In this paper we present a methodology for evaluating rain rates from a mix of satellite and surface based observations. The component data sets include the outgoing longwave radiation (OLR), microwave radiometric data from the special sensor microwave imager (SSM/I) and surface raingauge data from the World Weather Watch. We have noted some deficiencies in the SSM/I algorithm-based rain rate over land areas; the OLR-based rain rates exhibit a larger lateral spread and lower intensities than the observed rainfall structures. The proposed combined method assimilates these three data sets to provide improved fields of global tropical rainfall.With 3 Figures     

Mössbauer studies of iron silicate spinel at high pressure

We have measured in situ Mössbauer transmission spectra of iron silicate spinel (γ-Fe₂SiO₄) in a diamond anvil cell at room temperature and pressures up to 16 GPa. The observed spectra show a doublet characteristic of the paramagnetic state. The isomer shift and quadrupole splitting at atmospheric pressure are 1.10 and 2.63 mm/s, respectively, which are smaller than those of fayalite (α-Fe₂SiO₄). Both the isomer shift and quadrupole splitting decrease linearly with pressure with slope of ?0.003(1) and ?0.020(1) mm/sec · GPa, respectively. This simple linear trend suggests that no electronic or polymorphic transitions occur under 16 GPa except for those due to the small and continuous changes of volume and local symmetry under pressure. On the basis of a crystalline field calculation, the negative pressure derivative of the quadrupole splitting is associated with a trend towards an ideal cubic symmetry of the oxygen sublattice.     

Cation ordering of orthopyroxenes from the Skaergaard Intrusion: implications for the subsolidus cooling rates and permeabilities

 We have determined the quenched cation ordering states of five orthopyroxene crystals collected from the marginal border group and the lower zone a and b of the Skaergaard intrusion, and modeled these data to retrieve their closure temperatures (T _c) of Fe–Mg ordering and cooling rates. According to existing thermal models for the Skaergaard pluton, conductive cooling dominated the high and low temperature regimes, which were separated by an intermediate temperature regime in which the cooling was controlled primarily by convective fluid circulation. The cooling rates retrieved from the quenched cation ordering states of the orthopyroxene crystals strictly apply to temperatures around the closure temperatures of the ordering states, ∼340–400^° C, which fall at the transition from convective to the lower temperature conductive cooling. The cooling rates obtained from the cation ordering states of orthopyroxene vary from ∼1 to 270 K/ka. These results agree well with a thermal model calculated using an assumed average permeability of 10^-12 cm² for the pluton, but not completely with a model calculated on the basis of an average permeability of 10^-13 cm², although both values produced shifts of δ¹⁸O that are comparable to those observed in the pluton. Received: 27 February 1995/Accepted: 20 July 1995