Detection of PAHs in seawater using surface-enhanced Raman scattering (SERS)

The laboratory characterization of a field-operable surface-enhanced Raman scattering sensor (SERS optode) is presented for the detection of aromatic hydrocarbons in seawater. The sensor has been developed for deployment with a robust underwater spectrograph. To meet the demands of the harsh seawater application, sol-gel derived SERS substrates were used. The calibration curves of six PAHs were determined to be of Langmuir adsorption isotherm type with limits of detection ranging from the microg l(-1) to ng l(-1) level. The experimentally determined adsorption constants varied strongly with the molecular weight of the analytes and correlated with their solubility. A mixture of five PAHs dissolved in seawater was investigated to demonstrate the utility of this method for screening. Emphasis was put on the interference from suspended particulate matter (SPM). The Raman measurement with backscattering configuration was shown to be immune against turbidities up to 1000 NTU. The physico-chemical interference arising from adsorption by the sediment was measured on-line by adding sediment to a PAH-spiked solution. According to the calibration curve, the PAH concentration decrease corresponded to more than 98% of the analyte being scavenged by the sediment.     

Variation in tree mortality and regeneration affect forest carbon recovery following fuel treatments and wildfire in the Lake Tahoe Basin, California, USA

Background

Forest fuel treatments have been proposed as tools to stabilize carbon stocks in fire-prone forests in the Western U.S.A. Although fuel treatments such as thinning and burning are known to immediately reduce forest carbon stocks, there are suggestions that these losses may be paid back over the long-term if treatments sufficiently reduce future wildfire severity, or prevent deforestation. Although fire severity and post-fire tree regeneration have been indicated as important influences on long-term carbon dynamics, it remains unclear how natural variability in these processes might affect the ability of fuel treatments to protect forest carbon resources. We surveyed a wildfire where fuel treatments were put in place before fire and estimated the short-term impact of treatment and wildfire on aboveground carbon stocks at our study site. We then used a common vegetation growth simulator in conjunction with sensitivity analysis techniques to assess how predicted timescales of carbon recovery after fire are sensitive to variation in rates of fire-related tree mortality, and post-fire tree regeneration.

Results

We found that fuel reduction treatments were successful at ameliorating fire severity at our study site by removing an estimated 36% of aboveground biomass. Treated and untreated stands stored similar amounts of carbon three years after wildfire, but differences in fire severity were such that untreated stands maintained only 7% of aboveground carbon as live trees, versus 51% in treated stands. Over the long-term, our simulations suggest that treated stands in our study area will recover baseline carbon storage 10?C35?years more quickly than untreated stands. Our sensitivity analysis found that rates of fire-related tree mortality strongly influence estimates of post-fire carbon recovery. Rates of regeneration were less influential on recovery timing, except when fire severity was high.

Conclusions

Our ability to predict the response of forest carbon resources to anthropogenic and natural disturbances requires models that incorporate uncertainty in processes important to long-term forest carbon dynamics. To the extent that fuel treatments are able to ameliorate tree mortality rates or prevent deforestation resulting from wildfire, our results suggest that treatments may be a viable strategy to stabilize existing forest carbon stocks.     

岩溶地区电磁波场的特性研析

通过从理论上对岩溶地区电磁波传播的特有现象进行研究和分析,得出形成岩溶的高阻碳酸盐岩对电磁波的吸收较弱;碳酸盐岩因其成层沉积的特定环境,使岩溶地区岩石的各向异性现象较明显;以及由于地空界面的存在和岩溶洞壁两侧介质电性差异明显,致使电磁波出现强烈的反射及散射现象,形成很强的二次波,以致溶洞异常背景出现干涉条纹,甚至使异常严重畸变等结论      

油气系统动力学模拟方法评价

介绍了油气系统研究中最新发展起来的油气系统动力学方法;在与常规油气盆地模拟方法进行比较研究的基础上,对系统动力学模拟方法进行了评价,指出系统动力学模拟可较好地解决目前油气盆地模拟中存在的许多关键问题,是研究油气系统的有效途径。     

Iron in Precambrian rocks: implications for the global oxygen budget of the ancient Earth

Banded iron formations (BIF) are prominent in sediments older than 2 Ga. However, little is known about the absolute abundance of BIF in Archean and Early Proterozoic sediments, and the source of the Fe is still somewhat uncertain. Also unknown is the role that Fe may have played in the maintenance of low oxygen pressures in the Archean and Early Proterozoic atmosphere. An analysis of the chemical composition of Precambrian rocks provides some insight into the role of Fe in Precambrian geochemical cycles. The Fe content of igneous rocks is well correlated with their Ti content. Plots of Fe vs. Ti in Precambrian sandstones and graywackes fall very close to the igneous rock trend. Plots of Fe vs. Ti in Precambrian shales also follow this trend but show a definite scatter toward an excess of Fe. Phanerozoic shales and sandstones lie essentially on the igneous rock trend and show surprisingly little scatter. Mn/Ti relations show a stronger indication of Precambrian Mn loss, perhaps due to weathering under a less oxidizing early atmosphere. These data show that Fe was neither substantially added to nor significantly redistributed in Archean and early Proterozoic sediments. Enough hydrothermal Fe was added to these sediments to increase the average Fe content of shales by at most a factor of 2. This enrichment would probably not have greatly affected the near-surface redox cycle or atmospheric oxygen levels. Continued redistribution of Fe and mixing with weathered igneous rocks during the recycling of Precambrian sediments account for the excellent correlation of Fe with Ti in Phanerozoic shales and for the similarity between their Fe/Ti ratio and that of igneous rocks.     

用于多频电磁波测井的圆锥螺旋式有源接收天线

对用负阻抗变换电路同圆锥螺旋天线相结合，构成的有源接收天线进行了理论分析。并给出了该有源天线稳定工作的条件和设计原理。结果表明，用该方法设计的有源接收天线具有很宽的频带、较高的灵敏度和很小的尺寸，是多频电磁波测井较为理想的接收天线。     

Prior exposure to Cu contamination influences the outcome of toxicological testing of Fucus serratus embryos

Brown seaweeds are often employed in single species toxicity testing to study the association between the pollutant and the biota in contaminated marine habitats. We have used Fucus serratus (Phaeophyta) from one Cu resistant and one non-resistant population to evaluate the effect of prior exposure to metal pollution on toxicological endpoints. Analysis of comparative toxicity was conducted for embryo rhizoid elongation and adult relative growth rate (RGR). Algae that had previously been exposed to Cu expressed consistently lower levels of sensitivity to Cu than those that had no history of exposure to the pollutant. For both non-resistant and resistant populations rhizoid length was a more sensitive endpoint than adult RGR. While early life history stages of brown algae are generally regarded as being pollution-sensitive and inhibition of spore and embryo rhizoid elongation is frequently used as endpoints in bioassays, the test results may be affected by prior exposure of the parent algae to the pollutant. We conclude that the effect of prior exposure should be considered when comparing endpoints between studies and when selecting material for future testing.