崖南凹陷Y1井崖三段煤系烃源岩发育规律

基于Y1井煤系烃源岩样品微量元素分析、煤岩显微组分及热解测试结果,结合小波分析的米氏旋回划分结果,系统研究了崖南凹陷Y1井崖三段煤系烃源岩特征及发育规律。研究表明:①以104和260尺度结合岩芯沉积序列及地球化学测试结果,将崖三段划分为2个中期和5个短期米氏旋回,垂向上表现为旋回厚度及烃源岩比例向上增大的趋势,中期旋回上部为烃源岩优势发育层位,其中ⅠA2、ⅠA3和ⅠB2为煤系烃源岩发育的优势旋回;②煤系烃源岩有机显微组分表现为富镜质组、贫惰质组、贫壳质组+腐泥组,镜质组含量为44%~100%,平均为83%,以基质镜质体及镜屑体为主,烃源岩类型以Ⅲ型（腐殖型）有机质为主,少量为Ⅱ₂型（腐泥-腐殖型）有机质,烃源岩以产气为主,其成熟度较低,R_o值平均为1.12%,处于生烃阶段初期;③煤系烃源岩发育受多种因素控制,其中断陷盆地向坳陷盆地的转化时期是成煤的关键构造时期、强烈进积作用使得煤系烃源岩保存不全、区域海平面上升时期是成煤的关键时期、短期旋回小波曲线右偏拐点处为煤系烃源岩相对发育层位。     

姚家岭锌金多金属矿床围岩蚀变三维空间定量分析研究

姚家岭锌金多金属矿床是近年来在长江中下游成矿带铜陵矿集区新发现的大型多金属矿床。姚家岭锌金多金属矿床的成矿作用具有多阶段性的特点,矿床范围内围岩蚀变强烈,蚀变类型复杂多样。三维地质信息技术及三维空间分析方法为定量化分析围岩蚀变的空间分布以及与矿化之间的相关关系提供了有利工具。本文基于上述方法,有效地对姚家岭锌金多金属矿床的围岩蚀变的分带性及其与不同矿化之间的关联性行了定量分析。较之于传统研究方法,不仅能快速地对蚀变与矿化的分布特征进行分析,还能从定量的角度获取不同信息之间的规律性和相关性。本文采用的相关方法不但有助于更准确的判定蚀变分带及规律,还可为矿床的成矿模式及找矿模型的建立提供定量化的数据支持。     

肥东花岗质岩脉的变形及年代学特征对郯庐断裂带早白垩世构造活动的指示

郯庐断裂带肥东段位于大别造山带与苏鲁造山带之间。在肥东段西韦采石场内发育了大规模的北北东向左行走滑韧性剪切带和一条低角度的韧性滑脱正断层。走滑韧性剪切带为郯庐断裂带走滑活动的产物,低角度滑脱正断层则代表了伸展背景下的构造活动。低角度滑脱正断层上、下盘发育未变形和变形的岩脉,走滑韧性剪切带内外也发育有受剪切带活动而变形的岩脉。对采石场内岩脉的构造和同位素年代学研究表明,低角度韧性滑脱正断层在129~126Ma之间发生过剪切活动,走滑韧性剪切带的活动时间在125Ma之后。综合研究认为,郯庐断裂带的伸展活动可能开始于早白垩世早期(130Ma),但在早白垩世并非一直处于伸展活动之中,125Ma之后的左行走滑活动很可能发生在早白垩世的晚期。     

基于热储法的鲁西平原地热资源评价

鲁西平原地处山东省的西南部,热储层主要有新近系馆陶组、明化镇组,古近系东营组和奥陶系。通过野外勘察和室内分析结果,选取合理的计算参数,利用热储法等对鲁西平原地热资源进行了评价。结果表明鲁西平原地区地热资源量达1.735 5×1021J,折合标准煤5.923 3×1010t;可利用地热资源量达3.252×1020J,折合标准煤1.110×1010t;热储层百年地热水储存量为4.229×1011 m3,地热水允许开发量为4.229×1011 m3。     

底水油层水平井产液剖面均衡性评价

胜利油田开采底水特征高含水油层的水平井数量多,其中油层向水平井非均衡供液现象普遍。为评价此类水平井产液剖面均衡性,量化其生产动态改善潜力,定义了产液剖面基尼系数GN,并结合现场案例介绍其计算方法,随后统计胜利油田60口样本井,分析GN对见水时间tRL和底水突破前累积产油量QRL的影响,最后据此对GN分级。计算和分析结果表明:GN可以整体表征实际非均衡产液剖面偏离理想均衡产液剖面的程度,通常取值0~1之间,数值越大,均衡性越差;划分GN0.1为产液剖面不均衡,其样本井数54口,占比90%,以理想均衡产液状态为基准,tRL和QRL分别至少有100%和69.5%的提升潜力。     

Nuclear field shift effects on stable isotope fractionation: a review

An anomalous isotope effect exists in many heavy element isotope systems (e.g., Sr, Gd, Zn, U). This effect used to be called the “odd–even isotope effect” because the odd mass number isotopes behave differently from the even mass number isotopes. This mass-independent isotope fractionation driving force, which originates from the difference in the ground-state electronic energies caused by differences in nuclear size and shape, is currently denoted as the nuclear field shift effect (NFSE). It is found that the NFSE can drive isotope fractionation of some heavy elements (e.g., Hg, Tl, U) to an astonishing degree, far more than the magnitude caused by the conventional mass-dependent effect (MDE). For light elements, the MDE is the dominant factor in isotope fractionation, while the NFSE is neglectable. Furthermore, the MDE and the NFSE both decrease as temperatures increase, though at different rates. The MDE decreases rapidly with a factor of 1/T², while the NFSE decreases slowly with a factor of 1/T. As a result, even at high temperatures, the NFSE is still significant for many heavy element isotope systems. In this review paper, we begin with an introduction of the basic concept of the NSFE, including its history and recent progress, and follow with the potential implications of the inclusion of the NFSE into the kinetic isotope fractionation effect (KIE) and heavy isotope geochronology.     

Internal Microanatomy and Zoological Affinity of the Early Cambrian Olivooides

The early Cambrian pentamerous microfossil Olivooides/Punctatus in South China, which is characterized by a diagnostic stellate tubular apex, has been well-known for its almost complete development sequence that can be confidently traced from embryos and hatched juveniles, to conical adults. However, its zoological affinity remains highly controversial. Here we describe the internal microanatomic structures of the soft-body inside the peridermal theca of Olivooides multisulcatus Qian, 1977, including interradial pairs of tentacles, adradial and perradial frenula, perradial oral marginal lappets and twins of perradial gastric saccule-like humps as well as a circular velarium with striated coronal muscles. Particularly, one specimen shows bifurcated velarial canals along the bell aperture. Both the components of the soft-body and the external theca (or cyst) are arranged in perfect pentaradial symmetry. These characteristics are more compatible with those of living cubomedusans and co-occurring Cambrian athecate embryonic cubozoans. Concerning the presence of peridermal theca, Olivooides most likely represents an extinct thecate stem-group cubomedusae but devoid of both perradial eyes and specialized pedalia. The well-grown soft body inside the peridermal tube displays a set of mixed features of both polyp and medusa.     

Fractionation characteristics of rare earth elements (REEs) linked with secondary Fe,Mn, and Al minerals in soils

Soil secondary minerals are important scavengers of rare earth elements (REEs) in soils and thus affect geochemical behavior and occurrence of REEs. The fractionation of REEs is a common geochemical phenomenon in soils but has received little attention, especially fractionation induced by secondary minerals. In this study, REEs (La to Lu and Y) associated with soil-abundant secondary minerals Fe-, Al-, and Mn-oxides in 196 soil samples were investigated to explore the fractionation and anomalies of REEs related to the minerals. The results show right-inclined chondrite-normalized REE patterns for La–Lu in soils subjected to total soil digestion and partial soil extraction. Light REEs (LREEs) enrichment features were negatively correlated with a Eu anomaly and positively correlated with a Ce anomaly. The fractionation between LREEs and heavy REEs (HREEs) was attributed to the high adsorption affinity of LREEs to secondary minerals and the preferred activation/leaching of HREEs. The substantial fractions of REEs in soils extracted by oxalate and Dithionite-Citrate-Bicarbonate buffer solutions were labile (10 %–30 %), which were similar to the mass fraction of Fe (10 %–20 %). Furthermore, Eu was found to be more mobile than the other REEs in the soils, whereas Ce was less mobile. These results add to our understanding of the distribution and geochemical behavior of REEs in soils, and also help to deduce the conditions of soil formation from REE fractionation.     

激电测量在苏吉泉东金矿勘查中的应用

对苏吉泉东金矿进行激电测量,获得激电异常数据(电阻率ρ_s和视极化率η_s)。把不同测线上性质相同的电阻率ρ_s和视极化率η_s的反交点按对应关系联接起来,分别作为相应的破碎带和极化体位置,同时结合地质资料多次反馈,逐步逼近真实地质体。圈定了PSD1,PSD2两个破碎带和Jht1,Jht2,Jht3三个极化体,通过ρ_s和η_s的一维反演及二维反演,拟合出破碎带和极化体的形态特征及相对深度,为矿产勘探提供了较为明确的地球物理依据。     

季节性冰封热融浅湖水温原位观测及其分层特征

为探究季节性冰封浅湖热力学特征,于2010年10月至2013年7月对高原腹地一典型热融湖塘冰层生消、水/冰温及气象条件开展原位观测,分析了水温分布时间变化、温跃层以及冰生消对水温结构的影响。结果发现:冰面升华显著,贯穿整个冰期;水温日变化、季节变化和垂直结构受气温、大气辐射、风速、冰生消和湖底沉积层热贡献影响显著;在"无冰期-结冰前-冰生长期-冰融化期-融化后-无冰期"年循环过程中水温垂直结构分别呈现出"分层-翻转-逆温分层-逆温与正温共存-翻转-分层"的循环过程。分层期水温结构仅由上部混合层和温跃层构成,且偶因强风搅动而全湖翻转混合。可见,相比大中型湖泊,季节性冰封浅湖热力学结构差异显著。