The influence of salinity on the solubility of Zn and Cd sulphides in the Scheldt estuary

In the estuary of the river Scheldt, where an oxygen gradient exists in addition to the salinity gradient, redox processes will be of major importance for trace metal mobilisation. In this study, the influence of salinity and pH on the redox processes of dissolved Zn and Cd sulphides is investigated together with the effects on the ratio of the dissolved Zn and Cd concentrations. The speciation of these metals is calculated with the chemical equilibrium programme +. Zn sulphides are oxidised at lower oxygen concentrations than Cd sulphides, due to lower stability constants, causing a sudden increase or peak in the dissolved Zn/Cd ratio. The formation of dissolved Cd chloride complexes when oxidation occurs at high salinities (S=15) increases the mobility of Cd, causing a decrease in the Zn/Cd peak of the total dissolved concentrations. The peak is three to four times smaller at S=15 than when oxidation occurs at S=2. The simple model calculations compare very well with field data. The Scheldt estuary is suitable to illustrate these calculations. In the 1970s, the anoxic part of the estuary reached S=15–20, but since the early 1980s it has dropped to S=2–10. Historic data on metals in the estuary from 1978, 1987 and the 1990s were used to compare with the equilibrium calculations. The increase of the dissolved Zn/Cd peak at low salinity as a consequence, of the decreasing anoxic region is confirmed well by the data. The good agreement between model calculations and field data is a proof of the extreme importance of redox processes for the solubility of Zn and Cd sulphides in the estuary.     

A unique Galactic planetary nebula with a [WN] central star

We report the discovery of the first probable Galactic [WN] central star of a planetary nebula (CSPN). The planetary nebula candidate was found during our systematic scans of the AAO/UKST Hα Survey of the Milky Way. Subsequent confirmatory spectroscopy of the nebula and central star reveals the remarkable nature of this object. The nebular spectrum shows emission lines with large expansion velocities exceeding 150 km s⁻¹, suggesting that perhaps the object is not a conventional planetary nebula. The central star itself is very red and is identified as being of the [WN] class, which makes it unique in the Galaxy. A large body of supplementary observational data supports the hypothesis that this object is indeed a planetary nebula and not a Population I Wolf–Rayet star with a ring nebula.     

Application of Air Decks in Production Blasting to Improve Fragmentation and Economics of an Open Pit Mine

In blasting with air decks, repeated oscillation of shock waves within the air gap increases the time over which it acts on the surrounding rock mass by a factor at between 2 and 5. The ultimate effect lies in increasing the crack network in the surrounding rock and reducing the burden movement. Trials of air deck blasting in the structurally unfavourable footwall side of an open pit manganese mine has resulted in substantial improvements in fragmentation and blast economics. Better fragmentation resulted in improved shovel loading efficiency by 50–60%. Secondary blasting was almost eliminated. Use of ANFO explosive with this technique reduced explosive cost by 31.6%. Other benefits included reductions in overbreak, throw and ground vibration of the order of 60–70, 65–85 and 44% respectively. This paper reviews the theory of air deck blasting and describes in detail the air deck blast trials conducted in a manganese open pit mine in India. The blast performance data have been analysed to evaluate the benefits of air decking over conventional blasting.     

Regional GHG reduction targets based on effort sharing: a comparison of studies

Over 40 studies that analyse future GHG emissions allowances or reduction targets for different regions based on a wide range of effort-sharing approaches and long-term concentration stabilization levels are compared. This updates previous work undertaken for the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. Regional reduction targets differ significantly for each effort-sharing approach. For example, in the Organisation for Economic Co-operation and Development (OECD) 1990 region, new proposals that emphasize the equity principles of responsibility, capability, and need, and those based on equal cumulative per capita emissions (carbon budgets), lead to relatively stringent emissions reduction targets. In order to reach a low concentration stabilization level of 450?ppm CO₂e, the allowances under all effort sharing approaches in OECD1990 for 2030 would be approximately half of the emissions of 2010 with a large range, roughly two-thirds in the Economies in Transition (EIT), roughly at the 2010 emissions level or slightly below in Asia, slightly above the 2010 level in the Middle East and Africa and well below the 2010 level in Latin America. For 2050, allowances in OECD1990 and EIT would be a fraction of today's emissions, approximately half of 2010 emission levels in Asia, and possibly less than half of the 2010 level in Latin America.

Policy relevance

The concept of equity and the stringency of future national GHG reduction targets are at the heart of the current debate on the new international climate change agreement to be adopted in 2015. Policy insights gained from an analysis of over 40 studies, which have quantitatively analysed the proposed GHG reduction targets, are presented. It is found that the outcome of effort-sharing approaches is often largely determined by the way the equity principle is implemented and that the distributional impacts of such approaches can be significantly different depending on the criteria used, the stabilization level and shape of the global emissions pathway. However, the current literature only covers a small proportion of the possible allocation approaches. There should thus be an in-depth modelling comparison to ensure consistency and comparability of results and inform decision making regarding the reduction of GHG emissions.     

Richtmyer-Meshkov Experiments on the Omega Laser

Observations of the interstellar medium reveal a dynamic realm permeated by shocks. These shocks are generated on a large range of scales by galactic rotation, supernovae, stellar winds, and other processes. Whenever a shock encounters a density interface, Richtmyer-Meshkov instabilities may develop. Perturbations along the interface grow, leading to structure formation and material mixing. An understanding of the evolution of Richtmyer-Meshkov instabilities is essential for understanding galactic structure, molecular cloud morphology, and the early stages of star formation. An ongoing experimental campaign studies Richtmyer-Meshkov mixing in a convergent, compressible, miscible plasma at the Omega laser facility. Cylindrical targets, consisting of a low density foam core and an aluminum shell covered by an epoxy ablator, are directly driven by fifty laser beams. The aluminum shell is machined to produce different perturbation spectra. Surface types include unperturbed (smooth), single-mode sinusoids, multi-mode (rough), and multi-mode with particular modes accentuated (specified-rough). Experimental results are compared to theory and numerical simulations.     

ON THE CHARACTERISTICS OF NON-LINEAR SOIL RESPONSE AND DYNAMIC SOIL PROPERTIES USING VERTICAL ARRAY DATA IN JAPAN

Non-linear response of the soil is investigated by comparing the spectral ratios (uphole/downhole) using weak and strong motions. Data from seven vertical arrays in Japan are analysed in this study. The frequency-dependent transfer function of soil is calculated as a ratio of the spectrum at uphole to the spectrum at downhole, considering the horizontal component of shear wave. In spectral ratio analysis auto- and cross-spectra are employed. The reduction in the predominant frequency of the transfer function with increases in excitation level reflects the non-linear response of the soil. Results of analysis demonstrate a significant non-linear ground response at six sites with surface PGA exceeding 90 gal. However, the results of one site show the linear response up to 130 gal surface PGA. Furthermore, the in situ strain-dependent soil behaviour is examined through the shear modulus – shear strain relationship. When compared, the actual and laboratory results of the shear strain – shear modulus relationship are in agreement. Additionally, a good consistency between the tendency of reduction in shear modulus ratio with shear strain increases, and reduction of predominant frequency with ground motion increases, confirms the significance of non-linearity in site effects study.     

Radiation Products in Processed Ices Relevant to Edgeworth-Kuiper-Belt Objects

Near the inner edge of the Edgeworth-Kuiper Belt (EKB) are Pluto and Charon, which are known to have N₂- and H₂O-dominated surface ices, respectively. Such non-polar and polar ices, and perhaps mixtures of them, also may be present on other trans-Neptunian objects. Pluto, Charon, and all EKB objects reside in a weak, but constant UV-photon and energetic ion radiation environment that drives chemical reactions in their surface ices. Effects of photon and ion processing include changes in ice composition, volatility, spectra, and albedo, and these have been studied in a number of laboratories. This paper focuses on ice processing by ion irradiation and is aimed at understanding the volatiles, ions, and residues that may exist on outer solar system objects. We summarize radiation chemical products of N₂-rich and H₂O-rich ices containing CO or CH₄, including possible volatiles such as alcohols, acids, and bases. Less-volatile products that could accumulate on EKB objects are observed to form in the laboratory from acid-base reactions, reactions promoted by warming, or reactions due to radiation processing of a relatively pure ice (e.g., CO → C₃O₂). New IR spectra are reported for the 1–5 mu;m region, along with band strengths for the stronger features of carbon suboxide, carbonic acid, the ammonium and cyanate ions, polyoxymethylene, and ethylene glycol. These six materials are possible contributors to EKB surfaces, and will be of interest to observers and future missions.     

Carbon isotopes and iodine concentrations in a Mississippi River delta core recording land use, sediment transport, and dam building in the river's drainage basin

Sedimentary material from coastal and nearshore areas in the Mississippi Delta region are comprised of different organic carbon sources with diverse ages that require isotopic and elemental records for resolving the various sources of plant residues. Carbon isotopic ((13)C, (14)C) values were used to differentiate contributions from plants using the C3, C4, and/or CAM (crassulacean acid metabolism) carbon fixation pathways., and iodine concentrations indicated that wetland plant residues are a significant source of organic carbon in a sediment core from the Mississippi River delta region collected at a 60 m water depth. This sediment core had been extensively described in Oktay et al. [Oktay, S.D., Santschi, P.H., Moran, J.E., Sharma, P., 2000. The (129)Iodine Bomb Pulse Recorded in Mississippi River delta Sediments: Results from Isotopes of I, Pu, Cs, Pb, and C. Geochim. Cosmochim. Acta 64 (6), 989-996.] and significantly, includes unique features that had not previously been seen in the marine environment. These special features include a plutonium isotopic close-in fallout record that indicates a purely terrestrial source for these sediment particles and the elements associated with it, and a distinct iodine isotopic peak (as well as peaks for plutonium and cesium isotopes) that indicate little bioturbation in this core. Our carbon isotopic and iodine data can thus be compared to published records of changes in drainage basin land use, river hydrology, and hydrodynamic sorting of suspended particles to elucidate if these changes are reflected in nearshore sediments. This comparison suggests a significant contribution for organic carbon (OC) from C4 plants to these sediments during the 1950's to early 1960's. Relative older carbon isotopes, and episodically high iodine concentrations (up to 34 ppm) were observed during this time period that (1) indicate sediment deposition that is coincident with the times of major hydrological changes induced from dam and levee building in both the upper and lower reaches of the Mississippi River drainage basin, and (2) suggest episodic organic carbon deposition from wetland plant residues.     

Mineralogical,geochemical and microfabric evidences of gypsum crusts: a case study from Budapest

High levels of SO₂ and particulate pollution enable the rapid development of gypsum-rich weathering crusts in Budapest. Two types of white crusts, thin and thick ones, and two forms of black crusts, laminar and framboidal ones, were studied in limestone buildings of the parliament and Citadella. The percentage of crust cover and damage categories were documented on selected walls. Petrographic, XRD, XRF and sulphur isotope analyses were performed under laboratory conditions to understand the mechanism of crust formation. White crusts found both on exposed and sheltered walls display a calcite-rich layer with gypsum, while black crusts are enriched with gypsum. The sulphur isotopic composition of white and black crusts overlaps, but the crusts are slightly enriched in heavy isotopes compared to rainwater. S content, Si/Al ratios and particulates in black crusts suggest that air pollution (SO₂, dust) contributes to black crust formation. The accumulation of sulphur and Zn enrichment of white crusts were also documented indicating that under high pollution levels, even these compound can accumulate on exposed facades.