Adsorption of copper, nickel and lead ions from synthetic semiconductor industrial wastewater by palm shell activated carbon

Granular activated carbon produced from palm kernel shell was used as adsorbent to remove copper, nickel and lead ions from a synthesized industrial wastewater.Laboratory experimental investigation was carried out to identify the effect of pH and contact time on adsorption of lead, copper and nickel from the mixed metals solution. Equilibrium adsorption experiments at ambient room temperature were carried out and fitted to Langmuir and Freundlich models. Results showed that pH 5 was the most suitable, while the maximum adsorbent capacity was at a dosage of 1 g/L, recording a sorption capacity of 1.337 mg/g for lead, 1.581 mg/g for copper and 0.130 mg/g for nickel. The percentage metal removal approached equilibrium within 30 min for lead, 75 min for copper and nickel, with lead recording 100 %, copper 97 % and nickel 55 % removal, having a trend of Pb²⁺ > Cu²⁺ > Ni²⁺. Langmuir model had higher R² values of 0.977, 0.817 and 0.978 for copper, nickel and lead respectively, which fitted the equilibrium adsorption process more than Freundlich model for the three metals.     

Investigation of ammonia removal from polluted waters by Clinoptilolite zeolite

Ammonia nitrogen compounds in the wastewaters and effluents have harmful effects on water resources. Ion exchange with zeolites is a separation process for ammonia removal from effluents. The objective of this research was to study the efficiency of an ammonia removal and the factor affecting to this process. The Clinoptilolite was obtained from Semnan mines at the north part of Iran. The samples were grounded and sieved based on the U.S. standard mesh number 20, 30, 40 and conditioned by ammonia sulfate and sodium chloride solutions. The characteristics of samples for ammonia removal and the selectivity sequence for adsorbing interfering cations were then determined. Results shown that the average ion exchange capacity of zeolite in batch and continuous systems were 6.65–16 and 16.31–19.5 mg NH₄ ⁺ /g zeolite weight, respectively. In study on the zeolite for selective cations showed the ranking of K⁺, NH₄ ⁺, Na⁺, Ca²⁺ and Mg²⁺ respectively. Results indicated that high level of regeneration (95–98%) might be achieved with NaCl solution. Based on the results, Clinoptilolite may be effective applied in wastewater treatment, both from technical and economical aspects.     

Se and Te mineralization in albitites and prospects of the metasomatites for Au,Salla-Kuolajarvi belt,Northern Karelia

On the basis of the complex of geological features, the eastern flank of the Salla-Pana-Kuolajarvi belt is a prospect structure for gold mineralization in the U-bearing albitites and related acid and mafic metasomatites. Visible tellurides and selenides, which are typical of gold deposits of the Fe-Co-Au-U group in the adjacent territory of Finland within the Salla-Pana-Kuolajarvi belt, were found in the Ozerny occurrence as a result of studies. Native gold is found in association with tellurides. Molybdenite from the occurrence has a high Re content up to 0.3%.     

Elimination of Carbamazepine,Diclofenac and Naproxen from Treated Wastewater by Nanofiltration

Most conventional wastewater treatment plants remove very small amounts of micropollutants, such as pharmaceuticals. Here, the ability of two different types of submerged nanofiltration flat sheet modules to remove pharmaceuticals from wastewater is analyzed. The two nanofiltration membranes were used at relatively low pressures of only 0.3 and 0.7 bar. At such low pressures, the membranes did not retain salts to a great extent. This is advantageous in wastewater treatment because no salt concentrate is produced. Carbamazepine was retained only slightly by the nanofiltration membranes, whereas approximately 60% of diclofenac and naproxen were retained by both membranes. This level of effectiveness might not be enough to justify the use of such a system as an additional treatment step in wastewater treatment plants.     

Little Ice Age advance and retreat sediment budgets for an outlet glacier in western Norway

Burki, V., Hansen, L., Fredin, O., Andersen, T. A., Beylich, A. A., Jaboyedoff, M., Larsen, E. & Tønnesen, J.‐ F. 2009: Little Ice Age advance and retreat sediment budgets for an outlet glacier in western Norway. Boreas, Vol. 39, pp. 551–566. 10.1111/j.1502‐3885.2009.00133.x. ISSN 0300‐9483 Bødalsbreen is an outlet glacier of the Jostedalsbreen Ice Field in western Norway. Nine moraine ridges formed during and after the maximum extent of the Little Ice Age (LIA). The stratigraphy of proglacial sediments in the Bødalen basin inside the LIA moraines is examined, and corresponding sediment volumes are calculated based on georadar surveys and seismic profiling. The total erosion rates (e_tot) by the glacier are determined for the periods AD 1650–1930 and AD 1930–2005 as 0.8 ± 0.4 mm/yr and 0.7 ± 0.3 mm/yr, respectively. These rates are based on the total amount of sediment delivered to the glacier margin. The values are almost one order of magnitude higher than total erosion rates previously calculated for Norwegian glaciers. This is explained by the large amount of pre‐existing sediment that was recycled by Bødalsbreen. Thus, the total erosion rate must be considered as a composite of eroded bedrock and of removed pre‐existing sediments. The total erosion rate is likely to vary with time owing to a decreasing volume of easily erodible, unconsolidated sediment and till under the glacier. A slight increase in the subglacial bedrock erosion is expected owing to the gradually increasing bedrock surface area exposed to subglacial erosion.     

Seismic and well logging interpretation for evaluation of the lower Bahariya reservoir,southwest Qarun (SWQ) Field,Gindi Basin,Egypt

This paper focuses on seismic and well log interpretations for evaluating the sandstones of the Cenomanian Bahariya Formation in the southwest Qarun Field, Gindi Basin, northern Western Desert of Egypt. The seismic profiles display a clear anticlinal structure intersected by reverse faults in the study area. This faulted anticline has been interpreted to be one of the Syrian arc system folds formed by Upper Cretaceous tectonic inversion, which resulted from the NW movement of the African Plate relative to Laurasia. This anticline has been recommended as a target for exploration by the present work as it may represent a structural trap for hydrocarbon accumulation. The sandstones of the Lower Bahariya Formation in the southwest Qarun Field display good reservoir characteristics. The interpretation of the available well log data for the SWQ-21 and SWQ-25 wells for the Lower Bahariya Formation reflects a good reservoir quality for oil production in its topmost part. This reservoir possesses low S_W (<50%), high porosity (16%), low S_W/S_XO and low BVW (<0.09) which all reflect a high potential for oil production.     

Subpollen Particles as Atmospheric Cloud Condensation Nuclei

Izvestiya, Atmospheric and Oceanic Physics - Bioparticles constitute a significant fraction of atmospheric aerosol. Their size range varies from nanometers (macromolecules) to hundreds of...     

A Ka-band backscatter model function and an algorithm for measurement of the wind vector over the sea surface

A Ka-band backscatter model and an algorithm for measurement of the wind speed and direction over the sea surface by a frequency-modulated continous-wave radar demonstrator system operated in scatterometer mode have been developed. To evaluate the proposed algorithm, a simulation of the wind vector retrieval has been performed.     

Radiative association in Li+H revisited: the role of quasi-bound states

The role in radiative association of narrow resonances arising from quasi-bound levels is examined. For the rate coefficient the contribution from such levels is readily calculated in terms of the Einstein A -coefficient from bound rovibrational levels generated using a suitable alternative boundary condition. By locating systematically all the quasi-bound levels, an enhancement by more than an order of magnitude of the rate coefficient for Li(2s) + H(1s) association above about 600 K is obtained. The effect on the LiH abundance in the early Universe is no more than an increase of a factor of 3 for limited ranges of values of the redshift. For the Li(2p) state the effect of narrow resonances appears to have been taken into account in previous calculations.     

Flow behind an attached shock wave in a radiating gas

A simple method is used to determine the curvature of an attached shock wave and the flow variable gradients behind the shock curve at the tip of a straight-edged wedge placed symmetrically in a supersonic flow of a radiating gas near the optically thin limit. The shock curvature and the flow variable gradients along the wedge at the tip are computed for a wide range of upstream flow Mach numbers and wedge angles. Several interesting results are noted; in particular, it is found that the effect of an increase in the upstream flow Mach number or the radiative flux is to enhance the shock wave curvature which, however, decreases with an increase in the specific heat ratio or the wedge angle.