Potency of constructed wetlands for deportation of pathogens index from rural,urban and industrial wastewater

Pathogen removal is essential for wastewater treatment and its potential reuse in agriculture. Three field-scale wastewater treatment systems consisting of free surface flow were operated around 1.5 years receiving water from urban domestic, rural domestic and industrial sources. The study was conducted to evaluate seasonal performance of constructed wetland systems in removing Escherichia coli, Enterococci and total coliforms under continuous hydraulic flow. Results displayed that all three wetlands gain recognition in removing pathogen load with high removal efficacy till water reaches output ports. Removal efficiencies were even higher, 66–93, 78–92 and 80–94% for E. coli, Enterococci and total coliforms, respectively, within constructed wetlands. Remarkably at shorter temporal scales in CW-A, greater homogeneity of pathogen concentrations was assessed at wetland outlet sites. In outlet ports, results displayed a highly effective removal of E. coli concentration 80–90% (June 2015), 86–92% (October 2015) and 79–92% (February 2016), Enterococci 80–94% (June 2015), 83–94% (October 2015) and 80–94% (February 2016) and total coliforms 85–93% (June 2015), 87–95% (October 2015) and 88–96% (February 2016). Positive correlation was observed between bacterial indicators (E. coli–Enterococci, r = 0.038; p < 0.01 and E. coli–total coliforms, r = 0.142; p < 0.01). Removal of bacterial indicators in constructed wetland was also displayed by PCA in which three-component analysis of variance was 98.39% and showed a clear decrease in measured parameter gradients toward samples from outlet ports. Constructed wetlands provide cost-effective treatment systems for reducing the pathogen load in wastewater in variable agro-climatic conditions and thus improve water quality.     

Management of shock loads wastewater produced from water heaters industry

Water heater manufacturing represents one sector of household electrical appliance industry. It includes several batch processes which resulted in a highly polluted wastewater as shock loads. The objective of this study was to manage the shock loads wastewater with a simple and cost-effective approach prior to final discharge into municipality. To achieve this objective, two approaches were studied. The first approach was the chemical treatment of the accumulated shock loads wastewater using alum and an anionic polymer. Although this approach produced a very high-quality effluent, it was economically and technically infeasible. The second approach was a controlled release of the shock loads to the normal daily discharge in a way that guarantees the compliance of the end-off-pipe with the National Regulatory Standards. This solution required establishment of an equalization tank for normal daily flow and a holding tank for controlled release of the shock loads. Mathematical calculations were carried out to determine the most violating parameters in order to calculate the mixing ratio the of shock loads with the normal daily flow. Full engineering design of the proposed solution was carried out. This approach was implemented and proved to be simple, easy to operate, cost-effective and can be replicated in similar batch processing manufacturing plants.     

Water stress index and its implication for agricultural land-use policy in Thailand

Land-use change and expansion for agriculture significantly affect freshwater resource availability which in turn results in different levels of water scarcity and competition among users in different areas and time. The study uses the water stress index as an indicator for determining the potential impact of water use considering water deprivation potential. Considering the case of Thailand, the temporal aspects of water withdrawal and availability have been analyzed and characterized as the monthly water stress index for the 25 watersheds in the country. Wide variations of monthly water stress index are obtained; extreme water stress is observed in the areas of the Chao Phraya and Tha Chin watersheds (the central region) during the dry season because of the large areas cultivating second rice (rice planted in dry season). The target of the Thai government on agricultural land-use change and zoning toward the conversion of about 0.37 M·ha of the upland paddy fields with low productivity to sugarcane was evaluated showing serious implications on the monthly water stress index of the relevant watersheds and the water scarcity footprint potentials of rice and sugarcane production. The results reveal that proper policy can help reduce the amount of water requirement for agriculture in June, July, August and September by about 60–220 M·m³, which in turn results in the decrease in monthly water stress index values. Nevertheless, appropriate measures of water resource management for agriculture still need to be designed to avoid water competition as well as protect the ecosystem.     

Determining ammonia nitrogen decay rate of Malaysian river water in a laboratory flume

There is lack of information regarding ammonia nitrogen (AN), (i.e. NH₃-N) decay rate of river water in tropical regions like Malaysia. AN decay rate is a very important kinetic parameter to estimate NH₃-N, nitrate nitrogen (NO₃-N) and dissolved oxygen concentrations of river water by using computer models. This study presents determination of ammonia nitrogen decay rate of river water in the tropical environment of Malaysia. A laboratory flume was used to conduct twelve experiments. The flume was used to represent the turbulent condition of a typical river. Ammonia nitrogen decay rate for the tropical environment of Malaysia was observed to be between 0.194 and 0.554 per day. Median value of AN decay rate was 0.26 per day, which is slightly lower than the global median value of 0.295 per day. To check the accuracy of flume experiments, the AN decay rate of Pusu River obtained from the flume experiment was used to calibrate and validate ammonia nitrogen concentration of the river by using water quality analysis and simulation program (WASP). Very good calibration and validation results were achieved, which substantiated the accuracy of the flume experiments.     

Effect of confining stress and loading frequency on dynamic behavior of municipal solid waste in Kahrizak landfill

In order to analyze the stability of a landfill site, it should analyze some properties of waste introducing the main structural elements. Up to now, it has not been done much research on the properties of municipal solid waste. In addition, due to the differences in waste properties from one country to another and even from one to another landfill site, it is impossible to generalize the results. These conditions caused local research on the evaluation of static and dynamic parameters of municipal solid waste to be done. Because Iran is a seismic country, the short-term behavior of waste controls landfill sites stability during seismic loads; so it is necessary to know the dynamic behavior of these materials. In this paper, about 18 cyclic tests were performed, and in addition to determining the dynamic parameters of municipal solid waste of Tehran Kahrizak Disposal Site using cyclic triaxial test, the effect of confining stress and loading frequency on dynamic properties of these materials was evaluated. The results have shown that with increasing the confining stress and loading frequency, shear modulus and damping ratio was increased and decreased, respectively, and it is related to the composition of the municipal solid waste materials.     

Application of magnetic adsorbent with silicate and phenyl polymers to adsorb Rhodamine B

The extensive use of Rhodamine B (RhB) for textile, paper, pigment, food, cosmetic, and drug manufacturing and its indiscriminate disposal leads to serious human, biological, and environmental hazards. A magnetic adsorbent with silicate and phenyl polymers (Ph/SiO₂/Fe₃O₄) has been prepared to absorb RhB. The morphology and structure of the adsorbents have been characterized by TGA, XRD, FTIR, and adsorption–desorption measurement. The results revealed that Ph/SiO₂/Fe₃O₄ exhibited a paramagnetic behavior and could easily and quickly be separated from a suspension. The RhB adsorption behavior was almost pH independent due to the adsorption between the phenyl ring of Ph/SiO₂/Fe₃O₄ and RhB by π–π electron-donor–acceptor interactions. The adsorption behavior of RhB adsorption was in good agreement with the Langmuir adsorption isotherm, and the maximum adsorption capacity was 142.186 mg g^?1. Good desorption performance of Ph/SiO₂/Fe₃O₄ showed that this novel magnetic adsorbent cannot only be activated by ethanol extraction process but also reuse by the recovery of magnetic force.     

Hydrogeochemical Features of Thermal Waters of South Trungbo (Central Vietnam)

The results of studying the features of the hydrogeological structure and chemical and isotope composition of thermal waters from the central part of Vietnam that are characterized by intense manifestations of intrusive magmatism are presented. It is established that low–and high–thermal waters with temperature varying within 30–85°C are developed in the area under study. The value of total mineralization of the hydrotherms ranges from 0.05 to 10.05 g/dm³. It is assumed that the circulation of thermal waters that are different in temperature and chemical composition occurs at two levels. The regular change of the hydrotherm composition in the direction from mineralized chloride sodium, including with increased Ca content, to fresh sodium bicarbonate is revealed. The ratio of δ¹⁸O–δ²H isotopes indicates that the water component is based on meteoric water. In the coastal areas, there is an isotope shift towards the ocean waters, which is also confirmed by the hydrogeochemical data. The key factors for forming the chemical composition of the thermal waters in South Trungbo are their genetic type, the interaction processes in the “water–rock–gas–organic substance” system, and their equilibrium–nonequilibrium state.     

Paleogene–Neogene Boundary of Primorye,Russian Far East

Complex geological and paleobotanic analysis of sections of the boundary Oligocene–Miocene sediments of southern Primorye is conducted. The presence of a stratigraphic hiatus is identified in the transitional complexes of the Pushkino and Pavlovka depressions but not in the sections of the Rakovka depression; thus, it is suggested to use one of them (borehole no. 15) to choose the stratotype of the Paleogene–Neogene boundary. The previous conclusion on the presence of economic coal deposits of Primorye within the Paleogene part of the Tertiary complex is supported. It is suggested to use the section which is exposed by the Rakovka brown coal open pit (point 9209) as a stratotype of the upper subformation of the Pavlovka Formation.     

An orthotropic interface damage model for simulating drying processes in soils

The study of drying process in soils has received an increased attention in the last few years. This is very complex phenomenon that generally leads to the formation and propagation of desiccation cracks in the soil mass. In recent engineering applications, high aspect ratio elements have proved to be well suited to tackle this type of problem using finite elements. However, the modeling of interfaces between materials with orthotropic properties that generally exist in this type of problem using standard (isotropic) constitutive model is very complex and challenging in terms of the mesh generation, leading to very fine meshes that are intensive CPU demanding. A novel orthotropic interface mechanical model based on damage mechanics and capable of dealing with interfaces between materials in which the strength depends on the direction of analysis is proposed in this paper. The complete mathematical formulation is presented together with the algorithm suggested for its numerical implementation. Some simple yet challenging synthetic benchmarks are analyzed to explore the model capabilities. Laboratory tests using different textures at the contact surface between materials were conducted to evaluate the strengths of the interface in different directions. These experiments were then used to validate the proposed model. Finally, the approach is applied to simulate an actual desiccation test involving an orthotropic contact surface. In all the application cases the performance of the model was very satisfactory.