Environmental Geochemistry and Acid Mine Drainage Evaluation of an Abandoned Coal Waste Pile at the Alborz-Sharghi Coal Washing Plant,NE Iran

In this paper, an abandoned waste coal pile, which is resulted from Alborz-Sharghi coal washing plant, NE of Iran was mineralogically and geochemically characterized to evaluate pyrite oxidation, acid mine drainage (AMD) generation, and trace element mobility. After digging ten trenches and vertical sampling, a quantitative method including the atomic absorption test, and the quality-based methods including optical study were carried out for determination of pyrite fractions in the waste pile. The geochemical results revealed that the fraction of remaining pyrite increased with depth, indicating that pyrite oxidation is limited to the shallower depths of the pile which were confirmed by variations of sulfate, pH, EC, and carbonate with depth of the pile. To evaluate the trend of trace elements and mineralogical constituents of the waste particles, the samples were analyzed by using XRD, ICP-MS, and ICP-OES methods. The results showed the secondary and neutralizing minerals comprising gypsum have been formed below the oxidation zone. Besides, positive values of net neutralization potential indicated that AMD generation has not taken in the waste pile. In addition, variations of trace elements with depth reveal that Pb and Zn exhibited increasing trends from pile surface toward the bottom sampling trenches while another of them such as Cu and Ni had decreasing trends with increasing depth of the waste pile.     

Sedimentological analysis of two drill cores through the crater moat‐filling breccia,Flynn Creek impact structure,Tennessee

Sedimentological (line‐logging) analysis of two drill cores, FC77‐3 and FC67‐3, situated, respectively, in the northwestern and southeastern quadrants of the Flynn Creek impact structure's crater‐moat area reveals that the ~27 m thick crater moat‐filling breccia consists of three subequal parts. These parts, which were deposited during early modification stage of this marine‐target impact structure, are distinguished on the basis of vertical trends in sorting, grain size, and counts of clasts per meter in comparison with other well‐known marine‐target impact structures, namely Lockne, Tvären, and Chesapeake Bay. The lower part is interpreted to represent mainly slump deposits, and the middle part is interpreted to represent a stage intermediate between slump and marine resurge, that is, a traction flow driven by overriding suspension flow. The upper part (size graded, and relatively well sorted and fine grained) is interpreted to represent marine resurge flow only. The upper part is capped by a relatively thin and relatively fine‐grained calcarenite to calcisiltite deposit.     

Calibration of regional pollen data to construct maps of former forest types in southern Sweden

A method was developed to construct maps of former forest types based on regional pollen data in southern Sweden. The considered species were Alnus, Betula, Carpinus, Corylus, Fagus, Fraxinus, Juniperus, Picea, Pinus, Populus, Quercus, Salix, Tilia and Ulmus. A network of 37 regional pollen sites with high data quality from lakes and peat deposits were selected from Sweden south of 60 ° N. Pollen percentage values were calculated and converted into estimates of tree composition. For controlling the reliability of the reconstruction, the estimates from the core-tops were compared with present day forest inventory data, and local pollen diagrams were compared with the regional pollen diagrams. An inverse distance weighted interpolation algorithm was used to generate maps for each tree species distribution at 2000 BP, 1500 BP, 1000 BP, 500 BP and 0 BP. A supervised classification routine was implemented to generate nine different forest types common to the five studied time intervals. The maps show that the amounts and patterns of distribution of the species and the forest types have varied in a significant but systematic manner through time. The changes are due to human activities, migrational patterns and changes in climate. These maps will be of value as a basis for future landscape planning, forestry and conservation of biodiversity.This is the 20th in a series of papers published in this special AMQUA issue. These papers were presented at the 1994 meeting of the American Quaternary Association held 19–22 June, 1994, at the University of Minnesota, Minneapolis, Minnesota, USA. Dr Linda C. K. Shane served as guest editor for these papers.     

Palaeointensity In the Pelagic Realm: Marine Sediment Data Compared With Archaeomagnetic and Lake Sediment Records

Summary. Four box cores collected from the Ontong—Java plateau during the Eurydice expedition have been used to make relative geomagnetic palaeo-intensity measurements. Rock magnetic measurements on the sediments show that they are characterized by a uniform magnetic mineralogy, and that they are suitable for relative intensity estimates. These are obtained by normalizing the NRM by an ARM imparted in a low DC bias field. the palaeoceanographic event known as the preservation spike is used to establish a crude time-scale for the record so that it may be compared with other data from the same region, and also with global palaeointensity estimates. the marine sediment data are quite similar to Australian intensity data from lake sediments and archaeomagnetic sources, but as might be expected exhibit some obvious differences from the global record.     

Comparison of ecophysiological characteristics between introduced and indigenous mangrove species in China

Due to its rapid growth, the introduced mangrove species Sonneratia apetala from Bangladesh has been widely used in mangrove restoration in southeastern China since 1985. As an indigenous mangrove species in Hainan, China, Sonneratia caseolaris was also planted in Guangdong Province for afforestation purposes. Both species have developed well in their new habitats, but their ecophysiological differences with the native mangrove species have not been studied. In this study, leaf gas exchange, water and nitrogen use efficiencies of two Sonneratia species were compared with those of selected native mangrove species (Avicennia marina, Aegiceras corniculatum, Kandelia candel, and Excoecaria agallocha) in Hainan and Shenzhen. The introduced S. apetala maintained lower carbon assimilation rate (A) and photosynthetic nitrogen use efficiency (PNUE) than the indigenous S. caseolaris. In Shenzhen, the two introduced Sonneratia had comparable photosynthetic rates and water use efficiency (WUE) with the native mangrove species, except that PNUE in S. caseolaris was significantly higher than in the native mangrove species. The two Sonneratia species showed significant overlap in PNUE and long-term WUE. Photosynthetic parameters derived from leaf photosynthetic light–response curves and A–C_i curves also suggested lower carbon assimilation capacities for the introduced Sonneratia than for the native mangrove species in both study sites. The lower light compensation point (LCP) of two introduced Sonneratia in both study sites also indicated a better adaptation to a low light regime than the native mangrove species. The results of photosynthetic capacities indicated that the introduced mangrove species have little competitive advantage over local native mangrove species in their respective new habitats.     

Sediment deposition in the flood plain of Stemple Creek Watershed, northern California

Over the past 150 years, major land use changes have occurred in the Stemple Creek Watershed in northern California that have caused erosion to move soils from the upland to the flood plain, stream channels, and the bay. The purpose of this study is to document the recent (1954 to present) sediment deposition patterns in the flood plain area adjacent to Stemple Creek using the ¹³⁷Cesium technique. Sediment deposition ranged from 0.26 to 1.84 cm year⁻¹ for the period from 1964 to 2002 with an average of 0.85±0.41 cm year⁻¹. Sediment deposition rates were higher for the 1954 to 1964 period with a range of 0.31–3.50 cm year⁻¹ and an average of 1.29±1.04 cm year⁻¹. These data indicate that sediment deposition in the flood plain has decreased since the middle 1950s, probably related to reduction in row crop agriculture and an increase in pasturelands. This study shows that the flood plains in the Stemple Creek Watershed are a significant sink for the soils being eroded from the upland area. Given the significance of the flood plain for trapping eroded materials before they reach the stream channels or the bay, efforts need to be made to manage these flood plain areas to insure that they do not change and become a source rather than a sink for eroded materials as improved management practices on the upland areas reduce sediment input to the flood plain.     

Mass-front velocity of dry granular flows influenced by the angle of the slope to the runout plane and particle size gradation

The mass-front velocities of granular flows results from the joint action of particle size gradations and the underlying surfaces.However,because of the complexity of friction during flow movement,details such as the slope-toe impedance effects and momentum-transfer mechanisms have not been completely explained by theoretical analyses,numerical simulations,or field investigations.To study the mass-front velocity of dry granular flows influenced by the angle of the slope to the runout plane and particle size gradations we conducted model experiments that recorded the motion of rapid and long-runout rockslides or avalanches.Flume tests were conducted using slope angles of 25°,35°,45°,and 55° and three particle size gradations.The resulting mass-front motions consisted of three stages:acceleration,velocity maintenance,and deceleration.The existing methods of velocity prediction could not explain the slowing effect of the slope toe or the momentum-transfer steady velocity stage.When the slope angle increased from 25° to 55°,the mass-front velocities dropped significantly to between 44.4% and59.6% of the peak velocities and energy lossesincreased from 69.1% to 83.7% of the initial,respectively.The velocity maintenance stages occurred after the slope-toe and mass-front velocity fluctuations.During this stage,travel distances increased as the angles increased,but the average velocity was greatest at 45°.At a slope angle of 45°,as the median particle size increased,energy loss around the slope toe decreased,the efficiency of momentum transfer increased,and the distance of the velocity maintenance stage increased.We presented an improved average velocity formula for granular flow and a geometrical model of the energy along the flow line.     

Practical Incorporation of Multivariate Parameter Uncertainty in Geostatistical Resource Modeling

There is a need to bridge theory and practice for incorporating parameter uncertainty in geostatistical simulation modeling workflows. Simulation workflows are a standard practice in natural resource and recovery modeling, but the incorporation of multivariate parameter uncertainty into those workflows is challenging. However, the objectives can be met without considerable extra effort and programming. The sampling distributions of statistics comprise the core theoretical notion with the addition of the spatial degrees of freedom to account for the redundancy in the spatially correlated data. Prior parameter uncertainty is estimated from multivariate spatial resampling. Simulation-based transfer of prior parameter uncertainty results in posterior distributions which are updated by data conditioning and the model domain extents and configuration. The results are theoretically tractable and practical to achieve, providing realistic assessments of uncertainty by accounting for large-scale parameter uncertainty, which is often the most important component impacting a project. A simulation-based multivariate workflow demonstrates joint modeling of intrinsic shale properties and uncertainty in estimated ultimate recovery in a shale gas project. The multivariate workflow accounts for joint prior parameter uncertainty given the current well locations and results in posterior estimates on global distributions of all modeled properties. This is achieved by transferring the joint prior parameter uncertainty through conditional simulations.     

Chemical composition of waters and the phytoplankton of the lakes within the delta of the Selenga river

Field observations showed that the characteristics of chemical composition of waters and the development of plankton algae in the lakes within the delta of the Selenga river are determined by their flowage. The most open Lake Nekipelovskoe communicates with the Selenga outlets throughout a year, and Lake Zavernyaikha only at the period of an open channel. Lake Semenovskoe and Lake Khlystov Zaton are located in the islands and are isolated from the outlets. According to composition of main ions, the lakes under investigation refer to the hydrocarbonate class, the calcium group. The sum of ions in the water of Lake Nekipelovskoe approaches the one in the Selenga (86?221 mg/dm³), and the highest sums of ions were recorded in the wintertime in the lakes isolated from the outlets (446?743 mg/dm³). The lakes of the delta are characterized by a high trophicity. The maximum concentrations of total phosphorus in Lake Nekipelovskoe and Lake Zavernyaikha were 68 and 122 μg mg/dm³, and in Lake Semenovskoe and Lake Khlystov Zaton ?0.8 and ?0.63 μg mg/dm³, respectively. The most intense development of algae is observed in Lake Zavernyaikha, which is due to the high population of Baikal endemics. Lake Zavernyaikha showed a close negative correlation between the concentration of NO ₃ ^? , mineral phosphorus and phytoplankton biomass; the correlation coefficient was ?0.8 and ?0.63, respectively. The lakes exhibited increased contents readily hydrolysable organic matter, and a decrease in dissolved oxygen concentration in winter; hydrogen sulfide was repeatedly recorded in Lake Khlystov Zaton. The water quality in the lakes during the springtime varies from “quite clean” to “weakly polluted”; at low-water periods, especially in winters, it can drop to the category of “exceedingly dirty”. The water quality of the Selenga can be influenced by the lakes during spring floods when material accumulated during the wintertime is transported to the river outlets and further to Lake Baikal.