Secondary geochemical dispersion in the Precambrian auriferous Hutti-Maski schist belt, Raichur district, Karnataka, India. Part I: anomalies of As, Sb, Hg and Bi in soil and groundwater

The nature of secondary geochemical dispersion of As, Sb, Hg and Bi in soil and ground water of the semi-arid, tropical, Archaean, auriferous, Hutti-Maski greenstone belt has been investigated for identification of appropriate geochemical techniques for Au exploration in similar terrains.Results indicate that the <180 μm size-fraction of C-horizon soil is an appropriate sampling medium for delineating pedogeochemical anomalies of As, Sb, Hg and Bi related to gold mineralisation. These pedogeochemical anomalies along with anomalous values of alkalinity, chloride, sulphate, As and Sb in groundwater are controlled significantly by primary mineralisation located along shear zones in the greenstone belt. Arsenic anomalies in soil are broad, whereas, those of Sb and Bi are restricted to narrow zones directly over mineralised areas. In contrast, Hg anomalies around known mineralised areas are irregular and do not clearly demarcate the mineralised areas. The study indicates that anomalies of As, Sb and Hg in soil are principally hydromorphic, whereas those of Bi are clastic.The study recommends use of groundwater sampling at 2–3 km spacing with routine analysis of chloride, sulphate and alkalinity along with As and Sb in the first phase. This may be followed up with sampling of C-horizon of soils on a 1 km square grid for As-anomalies. Arsenic-anomalous areas may be sampled for As, Sb, Hg and Bi on a 500 m square grid for detailed exploration.     

中亚与亚洲中部晚白垩世的陆生脊椎动物组合对比

通过对前人建议的26个生物地层标志化石存在与否的简约分析,中亚与亚洲中部晚白垩世的陆生脊椎动物组合的相对层位得到了更清楚的揭示。此区最古老的组合是乌兹别克斯坦克孜勒库姆沙漠的Khodzhakul组合(早塞诺曼期),其次为蒙古戈壁沙漠东部BaynShire组的下部和上部的组合(塞诺曼期至桑顿期)。中国内蒙古二连达布苏动物群与中亚的土伦期—桑顿期动物群属于同一类群,因为它们均具龟鳖类Khunnuchelys,前者时代可能为桑顿期。三个中亚的组合(Bissekty、Yalovach和Bostobe组合)中有两个地方性的鳄形类(Kansajsuchus和Tadzhikosuchus)和一个出现于戈壁沙漠的鳄形类(Shamosuchus)化石。戈壁沙漠的坎潘期至马斯特里赫特期组合与北美同期动物群为同一类群。Djadokhta组与BarunGoyot组的坎潘期脊椎动物组合具有高度的地方性,并反应了半干旱的古环境。产自Nemegt组的组合生存于比较潮湿的环境。在组成上,这一组合与其他河流相沉积环境(Bissekty、二连达布苏以及北美Judithian期和Lancian期的组合)相似。具顶饰的鸭嘴龙Saurolophus的存在,支持了Nemegt组合为马斯特里赫特期时代。戈壁沙漠的这三个组合(Djadokhta、Barun Goyot和Nemegt组合)被归为一类,因为它们共同拥有地方性的龟类Mongolemys和兽脚亚目的小驰龙类。亚洲中部和北美的坎潘期至马斯特里赫特期组合与亚洲更加古老的组合不同在于存有暴龙科、肿头龙亚目和鸭嘴龙科。在中亚,由于地区性的海侵,这一时间段内的陆生脊椎动物组合多不清楚。     

Petrology of Lamproites from Smoky Butte, Montana

Hyalo-armalcolite-phlogopite lamproites and sanidine-phlogopitelamproites occurring at Smoky Butte, Montana are rocks formedfrom rapidly quenched, high temperature, uncontaminated lamproiticmagma. Petrographic variations are attributable to differentcooling histories of several batches of compositionally identicalmagma. Compared with other occurrences of lamproite, the rocksare unusually rich in TiO₂ and are characterized by the presenceof abundant armalcolite and the most TiO₂-rich phlogopites yetfound in this paragenesis. Compositional data are given fortitanian phlogopite, olivine, diopside, titanian potassian richterite,armalcolite, sanidine, analcite, and glass. The mafic mineralsare Al-deficient and exhibit very little compositional variation.Original leucite has been pseudomorphed by sanidine or analcite.The latter mineral was probably formed at the same time thatthe glass lost K, and gained Na, during alteration by groundwater.All of the lamproites are strongly enriched in Ta, Hf, and thelight REE (La /Yb = 162–280), and have high MgO and Crcontents. Mineralogical, geochemical, and previously publishedisotopic data are combined in developing a petrogenetic modelwhich suggests that these lamproites were derived from an ancient(2.5 Ga) doubly metasomatized harzburgitic source, and thatthey represent relatively primitive lamproites which were intrudedat near-liquidus temperatures.     

The tropospheric distribution of formaldehyde during TROPOZ II

A series of 149 measurements of the HCHO mixing ratio were made between 0 and 10 km altitude and 70° N to 60° S latitude during TROPOZ II. The data show a vertical decrease of the HCHO mixing ratio with altitude at all latitudes and a broad latitudinal maximum in the HCHO mixing ratio between 30° N and 30° S at all altitudes. The measured mixing ratios of HCHO are considerably higher than those expected from CH₄ oxidation alone, but agree broadly with the average latitude by altitude distribution of HCHO derived by a 2D model including emissions of C₁–C₇ hydrocarbons. A number of the regional scale deviations of the measured HCHO distribution from the average modelled one can be explained in terms of the local wind field.     

Three－dimensional Global Scale Permanent－wave Solutions of the Nonlinear Quasigeostrophic Potential Vorticity Equation and Energy Dispersion

The three-dimensional nonlinear quasi-geostrophic potential vorticity equation is reduced to a linear form in the stream function in spherical coordinates for the permanent wave solutions consisting of zonal wavenumbers from 0 to n and rn vertical components with a given degree n. This equation is solved by treating the coefficient of the Coriolis parameter square in the equation as the eigenvalue both for sinusoidal and hyperbolic variations in vertical direction. It is found that these solutions can represent the observed long term flow patterns at the surface and aloft over the globe closely. In addition, the sinusoidal vertical solutions with large eigenvalue G are trapped in low latitude, and the scales of these trapped modes are longer than 10 deg. lat. even for the top layer of the ocean and hence they are much larger than that given by the equatorial β-plane solutions. Therefore such baroclinic disturb-ances in the ocean can easily interact with those in the atmosphere.Solutions of the shallow water potential vorticity equation are treated in a similar manner but with the effective depth H = RT / g taken as limited within a small range for the atmosphere.The propagation of the flow energy of the wave packet consisting of more than one degree is found to be along the great circle around the globe both for barotropic and for baroclinic flows in the atmosphere.     

Validation of parameterized convective fluxes with DIAMOD

Summary A diagnostic model (DIAMOD) for the atmosphere over Europe is use at the University of Vienna. Central parameters in each diagnostic column (horizontal resolution 100 km, time resolution 12 hours) are the vertical moisture plus heat flux (the total convective heat fluxh) and the vertical rain flux (r); both are functions of pressure. In this study DIAMOD is applied to validate the output of a forecast model for the simulation of acid deposition (EURAD) which is in use at the University of Cologne. The basic equations of both DIAMOD and EURAD models are summarized with emphasis on the sub-gridscale hydrologic components.First, the nontrivial problem of validating model output versus observations is discussed. Two different validation techniques based upon the budget equations are indentified. The fully prognostic technique compares the forecast of EURAD for the total verification period with the corresponding DIAMOD output. The semiprognostic validation technique involves only one-time-step tendencies. Neither yields an exact correspondence between EURAD and DIAMOD; however, the semiprognostic technique comes somewhat closer to the ideal of an objective validation. The quantities investigated are: The fields, the time tendencies and the fluxesh andr.Second, EURAD is validated versus DIAMOD with both techniques for the EUMAC Joint Wet Case (the Chernobyl episode) in April 1986; the output fields include selected profiles ofh(p) over France (a moist night situation) and over Greece (a dry day situation). The comparison demonstrates for both that the EURAD forecasts are acceptable for ther-fluxes but are relatively poor for theh-fluxes. Reasons for the differences are discussed.With 11 Figures     

Identifying Key Sources of Uncertainty in Climate Change Projections

What sources of uncertainty shouldbe included in climate change projections and whatgains can be made if specific sources of uncertaintyare reduced through improved research?DIALOGUE, anintegrated assessment model, has been used to answerthese questions. Central in the approach of DIALOGUEis the concept of parallel modeling, i.e., for eachstep in the chain from emissions to climate change anumber of equivalent models areimplemented. The followingconclusions are drawn:The key source of uncertainty in global temperatureprojections appears to be the uncertainty inradiative forcing models. Within this group ofmodels uncertainty within aerosol forcing models isabout equal to the total forcing of greenhouse gasmodels. In the latter group CO₂ is dominant.The least important source of uncertainty appears tobe the gas cycle models. Within this group of modelsthe role of carbon cycle models is dominant.Uncertainty in global temperature projections hasnot been treated consistently in the literature.First, uncertainty should be calculated as a productof all uncertainty sources. Second, aparticular choice of a base year for global warmingcalculations influences the ranking of uncertainty.Because of this, a comparison of ranking resultsacross different studies is hampered. We argue that`pre-Industrial' is the best choice for studies onuncertainty.There is a linear relationship between maximumuncertainty in the year 2100 and cumulativeemissions of CO₂ over the period 1990–2100:higher emissions lead to more uncertainty.     

Frequency distributions of transient regional climate change from perturbed physics ensembles of general circulation model simulations

Large ensembles of coupled atmosphere–ocean general circulation model (AOGCM) simulations are required to explore modelling uncertainty and make probabilistic predictions of future transient climate change at regional scales. These are not yet computationally feasible so we have developed a technique to emulate the response of such an ensemble by scaling equilibrium patterns of climate change derived from much cheaper “slab” model ensembles in which the atmospheric component of an AOGCM is coupled to a mixed-layer ocean. Climate feedback parameters are diagnosed for each member of a slab model ensemble and used to drive an energy balance model (EBM) to predict the time-dependent response of global surface temperature expected for different combinations of uncertain AOGCM parameters affecting atmospheric, land and sea-ice processes. The EBM projections are then used to scale normalised patterns of change derived for each slab member, and hence emulate the response of the relevant atmospheric model version when coupled to a dynamic ocean, in response to a 1% per annum increase in CO₂. The emulated responses are validated by comparison with predictions from a 17 member ensemble of AOGCM simulations, constructed from variants of HadCM3 using the same parameter combinations as 17 members of the slab model ensemble. Cross-validation permits estimation of the spatial and temporal dependence of emulation error, and also allows estimation of a correction field to correct discrepancies between the scaled equilibrium patterns and the transient response, reducing the emulation error. Emulated transient responses and their associated errors are obtained from the slab ensemble for 129 pseudo-HadCM3 versions containing multiple atmospheric parameter perturbations. These are combined to produce regional frequency distributions for the transient response of annual surface temperature change and boreal winter precipitation change. The technique can be extended to any surface climate variable demonstrating a scaleable, approximately linear response to forcing.     

Summer temperature variability across four urban neighborhoods in Knoxville,Tennessee, USA

The urban heat island (UHI) is a well-documented effect of urbanization on local climate, identified by higher temperatures compared to surrounding areas, especially at night and during the warm season. The details of a UHI are city-specific, and microclimates may even exist within a given city. Thus, investigating the spatiotemporal variability of a city’s UHI is an ongoing and critical research need. We deploy ten weather stations across Knoxville, Tennessee, to analyze the city’s UHI and its differential impacts across urban neighborhoods: two each in four neighborhoods, one in more dense tree cover and one in less dense tree cover, and one each in downtown Knoxville and Ijams Nature Center that serve as control locations. Three months of temperature data (beginning 2 July 2014) are analyzed using paired-sample t tests and a three-way analysis of variance. Major findings include the following: (1) Within a given neighborhood, tree cover helps negate daytime heat (resulting in up to 1.19 ^°C lower maximum temperature), but does not have as large of an influence on minimum temperature; (2) largest temperature differences between neighborhoods occur during the day (0.38–1.16 ^°C difference), but larger differences between neighborhoods and the downtown control occur at night (1.04–1.88 ^°C difference); (3) presiding weather (i.e., air mass type) has a significant, consistent impact on the temperature in a given city, and lacks the differential impacts found at a larger-scale in previous studies; (4) distance from city center does not impact temperature as much as land use factors. This is a preliminary step towards informing local planning with a scientific understanding of how mitigation strategies may help minimize the UHI and reduce the effects of extreme weather on public health and well-being.     

一堆气候模式的灵敏度分析

在本文中我们设计了一个只有垂直方向的一维气候模式。该模式可以用来研究大气中CO_2气体浓度从330增加到660ppm时地面温度的变化。同时我们将分析几个反馈机制对气候系统灵敏度的贡献,其中包括大气湿度反馈、云反馈和地面反射率反馈等机制。