Interpreting tracer breakthrough tailing in a conduit-dominated karstic aquifer

Breakthrough tailing has been observed during dye-tracing recovery tests in the Norville aquifer system (chalk), France. Karst-conduit flow and transport parameters were assessed using two different interpretative methods: the linear graphical method and the Chatwin method (implemented in the Qtracer2 program). The linear graphical method was used to model the observed tailing effects, which was explained by a second smaller delayed breakthrough curve. By comparing the results of tracer-test interpretation for the two methods, it was possible to relate the area of this second curve to the importance of turbulent flow in spring discharge. The more turbulent the flow, the less important the contribution of the second breakthrough curve and the tailing effect. The observed tailing could possibly be controlled by hydrodynamics to a greater extent than usually expected, the tailing effects being mostly attributed to diffusion phenomena. Tailing effects were expected to increase with discharge and the piezometric level, which would have resulted in overpressure in conduits, fissure flooding, etc. Instead, breakthrough tailing tended to disappear with increasing aquifer discharge, which would support the hypothesis of there being mostly hydrodynamic-controlled tailing effects instead of matrix- or fissure-diffusion.An erratum to this article can be found at     

Dissolved Trace Metal–Organic Complexes in the Lot–Garonne River System Determined Using the C18 Sep-Pak System

An 11-month observation of dissolved and particulate organic matter, chlorophyll a(Chl a), C18 Sep-Pak extractable hydrophobic dissolved organic matter (hDOM) fraction and associated dissolved trace metals (Cd, Cu, V, Co, Ni, Mo, U) was performed in the Lot–Garonne River system. This system includes the Riou Mort, the Lot River and the downstream reaches of the Garonne River and represents the fluvial transport path of trace metals between the major point source of polymetallic pollution, located in the Riou Mort watershed and the Gironde estuary. Spatial and temporal variations of dissolved and particulate organic carbon and Chl areflect the presence of different types of organic matter and their relation with the hDOM fraction. Maximum Chl a/POC ratios (up to 0.03), indicate intense phytoplankton production from March to May. In the Lot River (Temple), DOC and POC concentrations were clearly higher and mean Chl a concentration (2.8 mg g⁻¹) was about three times higher than those of the other sites. High Chl a/POC ratios suggest high phytoplankton activity with maxima in spring and late summer. In the Riou Mort River, very high POC concentrations of up to 40 (mean: 20) occurred, whereas Chl a concentrations were relatively low indicating low phytoplankton activity. High, strongly variable DOC and POC concentrations suggest important natural (Carboniferous soils, forests) or anthropogenic (e.g., former coal mines, waste areas, agriculture, sewage) carbon sources within the small Riou Mort watershed. Despite high DOC concentrations in the Riou Mort River, hDOM metal fractions were generally lower than those at the other sites. The general order of decreasing binding strength between metals and the organic hydrophobic phase (Cu, U > Co, Ni > V, Mo > Cd) at all four sites was in good agreement with the Irving–William series of transition element affinity towards organic ligands. Accordingly, the role of the hydrophobic phase in dissolved Cd transport appeared to be negligible, whereas the hDOM–Cu fraction strongly contributed to dissolved Cu transport.     

Mercury speciation and mobilization in contaminated soils of the Valle del Azogue Hg mine (SE,Spain)

Hg mobilization from contaminated soils and mine wastes was the source of environmental contamination in the Valle del Azogue mining area. We researched solid-phase speciation and aqueous mobility of Hg through Scanning electron microscopy-energy dispersive X-ray spectroscopy and electron probe microanalysis analysis, solid-phase-Hg-thermo-desorption (SPTD) and laboratory column experiments. We found that in contaminated soils and mine wastes, the predominant Hg species was cinnabar (HgS), mainly formed from the weathering of Hg-rich pyrite, and metallic Hg (0) in the matrix, whereas in calcines and tailings the dominant species was metallic Hg (0). The mobilization of Hg in the aqueous phase seems to have originated from the dissolution of elemental Hg (0) present in soils and wastes, reaching concentrations of up to 67 μg l⁻¹, and showing a higher long-term environmental potential risk, in addition to atmospheric emissions.     

环境样品中痕量元素的化学形态分析Ⅱ．砷汞镉锡铅硒铬的形态分析

环境中元素的生物有效性和毒性依赖于其存在的化学形态。文章依据文献的有关报道介绍砷、汞、镉、锡、铅、硒和铬在环境中的分布、毒性及它们在环境样品如水、土壤、沉积物和生物体中的形态分析方法,包括分析物的保存、提取、分离和检测。引用文献120篇。     

Single frequency processing of Ørsted GPS radio occultation measurements

The Global Positioning System (GPS) radio occultation measurements obtained using the TurboRogue GPS receiver on the Danish satellite Ørsted have been processed using the single frequency method. Atmospheric profiles of refractivity and temperature are derived and validated against numerical weather prediction data from the European Centre for Medium-Range Weather Forecast (ECMWF). Results from the Ørsted GPS measurement campaign in February 2000 indicate that the single frequency method can provide retrievals with accuracy comparable to that of using two frequencies. From comparisons between measured dry temperature profiles and corresponding dry temperature profiles derived from ECMWF analysis fields, we find a mean difference of less than 0.5 K and a standard deviation of 2–4 K between 500 and 30 hPa in height. Above 30 hPa the impact of the ionosphere becomes more dominant and more difficult to eliminate using the single frequency method, and the results show degraded accuracy when compared to previous analysis results of occultation data from other missions using the dual frequency method. At latitudes less than 40° (denoted low latitudes), the standard deviation is generally smaller than at latitudes higher than 40° (denoted high latitudes). A small temperature bias is observed centered at 200 hPa for low latitudes and at 300 hPa for high latitudes. This indicates that the ECMWF analyses do not adequately resolve the tropopause temperature minimum. In the lowest part of the troposphere an observed warm bias is thought to be due to erroneous tracking of the GPS signal in cases of atmospheric multipath propagation.     

World-wide synthetic tide parameters for gravity and vertical and horizontal displacements

The response of the Earth’s crust to the direct effect of lunisolar gravitational forcing is known as the body tide. The body tide is superimposed by surface-loading forces due to the pressure of the periodically varying ocean tide acting on the Earth, called ocean tide loading (OTL). Both body tide and OTL can be decomposed into components of the same frequency known as tidal parameters. However, OTL is more complicated than body tides because of the dynamic effects of the ocean. Estimating OTL requires a model of the ocean tides and knowledge of the elastic properties of the solid Earth. Thus, synthetic tide parameters (amplitude factors and phase leads) have been developed here on a world-wide grid for gravity and positional displacements. The body tide contributions were added to the oceanic contribution to provide the Earth tide response. The accuracy and reliability of the synthetic tidal parameters have been estimated by comparing observed gravity and vertical-displacement tide parameters with those interpolated from our synthetic model, which shows good agreement. Tests also indicate that the synthetic tide parameters provide realistic gravimetric and displacements for practical use in tidal prediction.     

Land use/land cover identification in an alpine and arid region (Nubra Valley, Ladakh) using satellite remote sensing

The remote sensing technology has been widely used for mapping the vegetation types in the tropical landscapes. However, in the temperate and alpine arid regions of India very few studies have been conducted using this technique. In the mountainous temperate arid conditions the vegetation is largely confined to marsh meadows, streams courses, river valleys and moist pockets close to snowfields. The ground truth collection in these zones are physically challenging due to tough terrain and restricted mobility. The detailed mapping of vegetation and other land use classes in these areas is therefore, extremely difficult. This paper describes the use of IRS-ID LISS III sensor for deciphering land cover details Nubra Valley, northern portion of Ladakh Autonomous Hill Council, Jammu & Kashmir (India). This analysis essentially emphasizes in bringing out various vegetation classes (speciallyHippophae rhamnoides and other medicinal plant communities) along the narrow river valleys.     

Wind and Wave Data Analysis for the Aegean Sea - Preliminary Results

In this paper, a statistical analysis on wind and wave buoy measurements and wind and wave model forecasts obtained during a two-year period (1999-2001) is presented with reference to four characteristic near-shore sites of the Aegean Sea. The measurements are a main product of the "POSEIDON" system aiming at the monitoring and forecasting of the state of the Greek seas, operated by the National Centre for Marine Research (NCMR). Although the two-year period is rather short for a thorough analysis of the local wind and wave climate, yet the obtained results, presented herein for the first time, reveal some interesting features of the corresponding wave and wind characteristics. Comparisons between the measurements and the forecast results are also performed at the locations under consideration. It is found that (i) wind speeds obtained from the POSEIDON weather forecasting system are, in general, in agreement with the measurements, except for high wind speeds which are systematically underestimated, (ii) the WAM model can successfully follow the monthly and over year trend of the evolution of wind and wave characteristics, but face significant problems for efficient sea-state forecasting. Finally, the overall pattern of the wind/wave climate for the entire Aegean Sea as obtained from the models is presented by means of the spatial distribution of the mean annual wind and sea-state intensity.