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921.
922.
I. Brandariz P. Castro M. Montes F. Penedo M.E. Sastre de Vicente 《Marine Chemistry》2006,102(3-4):291-299
Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl2 or CaCl2), with binary mixtures of MgCl2 and CaCl2, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl2, while it is increased by the other electrolytes used in this work. 相似文献
923.
924.
D. Evans M.S. Stoker P.M. Shannon STRATAGEM Partners 《Marine and Petroleum Geology》2005,22(9-10):969
The EC-funded STRATAGEM project ran from 2000 to 2003 and was a study of the Neogene evolution of the glaciated northeast Atlantic margin from Lofoten to Porcupine, an area extending over nearly 20 degrees of latitude. An extensive seismic, borehole and sample database has been used, much of it supplied by the oil industry. The main products of STRATAGEM have been an integrated, unified stratigraphic framework in the form of an atlas documenting and illustrating the detailed stratigraphy of the entire margin, and a detailed evolution model for this margin. A brief summary of the background to, and organisation of, the project is presented, together with an outline of the main objectives, the physiographic setting of the area and the database. 相似文献
925.
926.
Miller KA Assunção MG Dangerfield NJ Bandiera SM Ross PS 《Marine environmental research》2005,60(2):153-169
Biomarkers of organochlorine exposure, such as the induction of cytochrome P450 1A (CYP1A), can be used to assess the impact of environmental contaminants on the health of free-ranging marine mammal populations. The objective of the present study was to measure CYP1A in skin and liver biopsies obtained from live harbour seals (Phoca vitulina). Twelve harbour seal pups, aged three to five weeks, were captured from the Fraser River estuary, British Columbia, Canada, and temporarily held in captivity. Skin ( approximately 60 mg) and liver ( approximately 40 mg) biopsies, obtained while seals were under general anaesthesia, yielded sufficient tissue for the measurement of CYP1A by immunoblot analysis and ethoxyresorufin O-deethylase activity. A short-term exposure experiment, in which harbour seals (n=3) were treated orally with beta-naphthoflavone (BNF), resulted in increased hepatic and cutaneous CYP1A protein levels, consistent with observations in other mammals. This study is the first to measure CYP1A in skin and liver biopsies from live harbour seals and to report in vivo BNF-associated CYP1A induction in a marine mammal. The results demonstrate that microsamples collected using minimally-invasive techniques can provide toxicologically-relevant information form marine mammals. 相似文献
927.
Jonathan M. Bull Martin Gutowski Justin K. Dix Timothy J. Henstock Peter Hogarth Timothy G. Leighton Paul R. White 《Marine Geophysical Researches》2005,26(2-4):157-169
Chirp sub-bottom profilers are marine acoustic devices that use a known and repeatable source signature (1–24 kHz) to produce
decimetre vertical resolution cross-sections of the sub-seabed. Here the design and development of the first true 3D Chirp
system is described. When developing the design, critical factors that had to be considered included spatial aliasing, and
precise positioning of sources and receivers. Full 3D numerical modelling of the combined source and receiver directivity
was completed to determine optimal source and receiver geometries. The design incorporates four source transducers (1.5–13 kHz)
that can be arranged into different configurations, including Maltese Cross, a square and two separated pairs. The receive
array comprises 240 hydrophones in 60 groups whose group-centres are separated by 25 cm in both horizontal directions, with
each hydrophone group containing four individual elements and a pre-amplifier.
After careful consideration, it was concluded that the only way to determine with sufficient accuracy the source–receiver
geometry, was to fix the sources and receivers within a rigid array. Positional information for the array is given by a Real
Time Kinematic GPS and attitude system incorporating four antennas to give position, heading, pitch and roll. It is shown
that this system offers vertical positioning accuracy with a root-mean-square (rms) error less than 2.6 cm, while the horizontal
positioning rms error was less than 2.0 cm. The system is configured so that the Chirp source signature can be chosen by software
aboard the acquisition vessel.
The complete system is described and initial navigational and seismic data results are presented. These data demonstrate that
the approach of using fixed source-receiver geometry combined with RTK navigation can provide complete 3D imaging of the sub-surface. 相似文献
928.
We have sampled particles of native aluminium (Al°) in two sediment cores from the Central Indian Basin (CIB). The cores are geographically separated but are located at the base of two seamounts. The native Al° particles occurring as grains and spherules, have an average Al content of 95% and are associated with volcanogenic–hydrothermal material. Morphologically and compositionally, the specimens are similar to those reported from the East Pacific Rise. After ruling out several processes for the presence of the native Al°, we hypothesize that during progressive melting of magma, a basaltic magma is produced which has high contents of reductants such as methane and hydrogen, and a low oxygen fugacity. During the upward migration of such magma, reduction to metallic aluminium and the formation of native Al° particles takes place. 相似文献
929.
930.
Jeffrey M. Napp Christine T. Baier Richard D. Brodeur Kenneth O. Coyle Naonobu Shiga Kathy Mier 《Deep Sea Research Part II: Topical Studies in Oceanography》2002,49(26)
The southeastern Bering Sea shelf ecosystem is an important fishing ground for fin- and shellfish, and is the summer foraging grounds for many planktivorous seabirds and marine mammals. In 1997 and 1998, Northern Hemisphere climate anomalies affected the physical and biological environment of the southeastern Bering Sea shelf. The resulting anomalous conditions provided a valuable opportunity to examine how longer-term climate change might affect this productive ecosystem. We compared historical and recent zooplankton biomass and species composition data for the southeastern Bering Sea shelf to examine whether or not there was a response to the atmosphere–ocean–ice anomalies of 1997 and 1998. Summer zooplankton biomass (1954–1994) over the southeastern shelf did not exhibit a decline as previously reported for oceanic stations. In addition, zooplankton biomass in 1997 and 1998 was not appreciably different from other years in the time series. Spring concentrations of numerically abundant copepods (Acartia spp., Calanus marshallae, and Pseudocalanus spp.), however, were significantly higher during 1994–1998 than 1980–1981; spring concentrations of Metridia pacifica and Neocalanus spp. were not consistently different between the two time periods. Neocalanus spp. was the only taxon to have consistent differences in stage composition between the two time periods—CV copepodites were much more prevalent in May of the 1990s than early 1980s. Since relatively high zooplankton concentrations were observed prior to 1997, we do not attribute the high concentrations observed in the summers of 1997 and 1998 directly to the acute climate anomalies. With the present data it is not possible to distinguish between increased production (control from below) and decreased predation (control from above) to explain the recent increase in concentrations of the species examined. 相似文献