Investigation of Failure Mechanisms and Migration of Organic Chemicals at Wilsonville, Illinois

Ground water contamination was discovered in 1981 in a monitoring well at the Earthline disposal facility near Wilsonville, Illinois. Organic chemicals had migrated at a rate 100 to 1000 times greater than predicted when the site received its permit to operate in 1978. Postulated failure mechanisms included migration through previously unmapped permeable zones, subsidence of an underground mine, organic-chemical and clay-mineral interactions, acid-mine drainage and clay interactions, trench-cover settlement, and erosion.
In this investigation, the Illinois State Geological Survey found the primary reason for the rapid migration: the presence of previously undetermined fractures and joints in glacial till. The inaccurate predictions of hydraulic conductivity were based on laboratory-determined values that did not adequately measure the effects of fractures and joints on the transit time calculations. Field-measured hydraulic conductivity values were generally 10 to 1000 times greater than their laboratory-measured counterparts, thus largely accounting for the discrepancy between predicted and actual migration rates in the transit time calculations. The problem was compounded, however, by the burial of liquid wastes and by trench covers that allowed excess surface runoff to enter the trenches. Organic-chemical and clay-mineral interactions may also have exacerbated the problem in areas where liquid organic wastes were buried.     

Results from several persistent train spectra intercompared

Some results following from two contemporary photographical programs (Slovakia and Japan) for persistent meteor train spectra are compared. It shows that even though both programs are not too different according to their lenses and films used, the spectral interval detected is very different. In this respect prism as a dispersion element is more favourable than the grating with blaze wavelength near 610 nm. However, some results previously assumed as typicai for presented persistent trains-e.g. the forbidden Herzberg O₂ emission, the NO₂ continuum and OH red emissions-seem to be substanciated especially due to higher and linear dispersion of those grating spectra.     

The significance of Messinian occurrences of Globorotalia margaritae and Globorotalia puncticulata in Sicily

Globorotalia puncticulata and Globorotalia margaritae are critical species that define internationally recognized planktonic foraminiferal biozones in the Pliocene. These biozones are defined from stratotype sections on Sicily and their fauna are commonly considered to have been introduced to the Mediterranean after an influx of Atlantic water that terminated the late Miocene desiccation of the basin. Herein new discoveries of these species in rocks that predate the late Miocene desiccation are described. These data are supported by magneto- and lithostratigraphy that have been integrated at a single continuous section. Not only do these discoveries question the existing foraminiferal biozone stratigraphy, they also suggest new models for the dispersal of planktonic species. It is proposed that Globorotalia puncticulata and perhaps even Globorotalia margaritae evolved in the Mediterranean during earliest Messinian times (during or before chron C3Bn1n) and dispersed into the Atlantic. This suggests that a marine connection remained between the two sea areas until at least chron C3An.1n. Using the existing geomagnetic polarity time scale, these occurrences are some 2 Myr earlier than previously recorded in the Mediterranean. The distribution of G. margaritae and G. puncticulata in Mediterranean sections is likely to reflect palaeoenvironment or the preservation of deposits rather than the absolute age of the sediments.     

Nutrient (P, N) dynamics in the southwestern Kattegat, Scandinavia: sedimentation and resuspension effects

 The yearly nutrient supply from land and atmosphere to the study area in SW Kattegat is 10 900 tons of N and 365 tons of P. This is only few percent of the supply from adjacent marine areas, as the yearly transport through the study area is 218 000 tons of N and 18 250 tons of P. Yearly net deposition makes up 1340 tons of N (on average 2.5 g m^–2 yr^–1) and 477 ton of P (on average 0.9 g m^–2 yr^–1). Shallow-water parts of the study area have no net deposition because of frequent (>35% of the year) resuspension. Resuspension frequency in deep water is <1% of the year. Resuspension rates, as averages for the study area, are 10–17 times higher than net deposition rates. Because of resuspension, shallow-water sediments are coarse lag deposits with small amounts of organic matter (1.1%) and nutrients (0.04% N and 0.02% P). Deep-water sediments, in contrast, are fine grained with high levels of organic matter (11.7%) and nutrients (0.43% N and 0.15% P). Laboratory studies showed that resuspension changes the diffusive sediment water fluxes of nutrients, oxygen consumption, and penetration into the sediment. Fluxes of dissolved reactive phosphate from sediment to water after resuspension were negative in organic-rich sediments (13.2% organic matter) with low porosity (56) and close to zero in coarse sediments with a low organic matter content (2.3%) and high porosity (73). Fluxes of inorganic N after resuspension were reduced to 70% and 0–20% in relation to the rates before resuspension, respectively. Received: 10 July 1995 · Accepted: 19 January 1996     

A new method of initial orbit determination

Up to now we have been dealing with the construction of entirely analytical planetary theories such as VSOP82 (Bretagnon, 1982) and TOP82 (Simon, 1983). These theories take into account the whole of the Newtonian perturbations of nine point masses: the Sun, the Earth-Moon barycentre, the planets Mercury, Venus, Mars, Jupiter, Saturn, Uranus and Neptune. They also take into account perturbations due to some minor planets, to the action of the Moon and the relativistic effects. The perturbations of these last three types are in a very simple way under analytical form but they considerably increase the computations when introduced in the numerical integration programs.In the present paper we thus study a solution in which the Newtonian perturbations for the ten point masses are treated through numerical integration, the other perturbations being analytically added.     

Error estimates with L1 solutions

A method is given, based on the pseudoinverse of the equations of condition, to obtain error estimates for the solution in the normL ₁ of an over-determined linear system. The computational labor to obtain the errors, while not trivial, is less than that for various competing methods, particularly if there are many more equations of condition than unknowns. The error estimates for anL ₁ solution are substantially larger than those for a least squares solution of the some data. It is suggested that a complete discussion of a linear system include at least bothL ₁ and least squares solutions with their respective errors and the condition number of the linear system.     

Theoretical properties of radio-galaxies

We present optical photometric observations of the cataclysmic variables AO Psc and V 1223 Sgr, both of which are believed to contain slowly-rotating white-dwarf pulsars. These objectes belong to the new class of intermediate polars in which the magnetized-white-dwarf rotation period lies in between synchrous and extremely fast rotation periods. The observations reported here were carried out from the Kavalur Observatory using a 1 m reflector. High-time resolution light curves depicting a rich variety of flicker phenomena are presented. Results of a periodic analysis to search for coherent periodic modulations in the light curves are also presented. We have also derived the optical pulse profile of AO Psc and point out its similarities to the X-ray pulse profile.     

Initial phase of chromospheric evaporation in a solar flare

In this paper we discuss the initial phase of chromospheric evaporation during a solar flare observed with instruments on the Solar Maximum Mission on May 21, 1980 at 20:53 UT. Images of the flaring region taken with the Hard X-Ray Imaging Spectrometer in the energy bands from 3.5 to 8 keV and from 16 to 30 keV show that early in the event both the soft and hard X-ray emissions are localized near the footpoints, while they are weaker from the rest of the flaring loop system. This implies that there is no evidence for heating taking place at the top of the loops, but energy is deposited mainly at their base. The spectral analysis of the soft X-ray emission detected with the Bent Crystal Spectrometer evidences an initial phase of the flare, before the impulsive increase in hard X-ray emission, during which most of the thermal plasma at 10⁷ K was moving toward the observer with a mean velocity of about 80 km s^-1. At this time the plasma was highly turbulent. In a second phase, in coincidence with the impulsive rise in hard X-ray emission during the major burst, high-velocity (370 km s^-1) upward motions were observed. At this time, soft X-rays were still predominantly emitted near the loop footpoints. The energy deposition in the chromosphere by electrons accelerated in the flare region to energies above 25 keV, at the onset of the high-velocity upflows, was of the order of 4 × 10¹⁰ erg s^-1 cm^-2. These observations provide further support for interpreting the plasma upflows as the mechanism responsible for the formation of the soft X-ray flare, identified with chromospheric evaporation. Early in the flare soft X-rays are mainly from evaporating material close to the footpoints, while the magnetically confined coronal region is at lower density. The site where upflows originate is identified with the base of the loop system. Moreover, we can conclude that evaporation occurred in two regimes: an initial slow evaporation, observed as a motion of most of the thermal plasma, followed by a high-speed evaporation lasting as long as the soft X-ray emission of the flare was increasing, that is as long as plasma accumulation was observed in corona.