Peak discharge of a Pleistocene lava-dam outburst flood in Grand Canyon, Arizona, USA

The failure of a lava dam 165,000 yr ago produced the largest known flood on the Colorado River in Grand Canyon. The Hyaloclastite Dam was up to 366 m high, and geochemical evidence linked this structure to outburst-flood deposits that occurred for 32 km downstream. Using the Hyaloclastite outburst-flood deposits as paleostage indicators, we used dam-failure and unsteady flow modeling to estimate a peak discharge and flow hydrograph. Failure of the Hyaloclastite Dam released a maximum 11 × 10⁹ m³ of water in 31 h. Peak discharges, estimated from uncertainty in channel geometry, dam height, and hydraulic characteristics, ranged from 2.3 to 5.3 × 10⁵ m³ s⁻¹ for the Hyaloclastite outburst flood. This discharge is an order of magnitude greater than the largest known discharge on the Colorado River (1.4 × 10⁴ m³ s⁻¹) and the largest peak discharge resulting from failure of a constructed dam in the USA (6.5 × 10⁴ m³ s⁻¹). Moreover, the Hyaloclastite outburst flood is the oldest documented Quaternary flood and one of the largest to have occurred in the continental USA. The peak discharge for this flood ranks in the top 30 floods (>10⁵ m³ s⁻¹) known worldwide and in the top ten largest floods in North America.     

Late Pleistocene glacial and lake history of northwestern Russia

Five regionally significant Weichselian glacial events, each separated by terrestrial and marine interstadial conditions, are described from northwestern Russia. The first glacial event took place in the Early Weichselian. An ice sheet centred in the Kara Sea area dammed up a large lake in the Pechora lowland. Water was discharged across a threshold on the Timan Ridge and via an ice-free corridor between the Scandinavian Ice Sheet and the Kara Sea Ice Sheet to the west and north into the Barents Sea. The next glaciation occurred around 75-70 kyr BP after an interstadial episode that lasted c. 15 kyr. A local ice cap developed over the Timan Ridge at the transition to the Middle Weichselian. Shortly after deglaciation of the Timan ice cap, an ice sheet centred in the Barents Sea reached the area. The configuration of this ice sheet suggests that it was confluent with the Scandinavian Ice Sheet. Consequently, around 70-65 kyr BP a huge ice-dammed lake formed in the White Sea basin (the 'White Sea Lake'), only now the outlet across the Timan Ridge discharged water eastward into the Pechora area. The Barents Sea Ice Sheet likely suffered marine down-draw that led to its rapid collapse. The White Sea Lake drained into the Barents Sea, and marine inundation and interstadial conditions followed between 65 and 55 kyr BP. The glaciation that followed was centred in the Kara Sea area around 55-45 kyr BP. Northward directed fluvial runoff in the Arkhangelsk region indicates that the Kara Sea Ice Sheet was independent of the Scandinavian Ice Sheet and that the Barents Sea remained ice free. This glaciation was succeeded by a c. 20-kyr-long ice-free and periglacial period before the Scandinavian Ice Sheet invaded from the west, and joined with the Barents Sea Ice Sheet in the northernmost areas of northwestern Russia. The study area seems to be the only region that was invaded by all three ice sheets during the Weichselian. A general increase in ice-sheet size and the westwards migrating ice-sheet dominance with time was reversed in Middle Weichselian time to an easterly dominated ice-sheet configuration. This sequence of events resulted in a complex lake history with spillways being re-used and ice-dammed lakes appearing at different places along the ice margins at different times.     

Rock fracturing by explosive energy: review of state-of-the-art

A study of the dynamic rock fracture initiation and propagation due to explosive energy is presented through a detailed state-of-the-art review. Explosive energy dissipation in crushing and fracturing is examined and the various means to enhance the explosive energy utilization for dynamic rock fracturing are reviewed. The study highlights the need for a better understanding of the dynamic fracturing process particularly in the presence of in situ stresses in the rock mass.     

The transition from peraluminous to peralkaline granitic melts: Evidence from melt inclusions and accessory minerals

Fractional crystallization of peraluminous F- and H₂O-rich granite magmas progressively enriches the remaining melt with volatiles. We show that, at saturation, the melt may separate into two immiscible conjugate melt fractions, one of the fractions shows increasing peraluminosity and the other increasing peralkalinity. These melt fractions also fractionate the incompatible elements to significantly different degrees. Coexisting melt fractions have differing chemical and physical properties and, due to their high density and viscosity contrasts, they will tend to separate readily from each other. Once separated, each melt fraction evolves independently in response to changing T/P/X conditions and further immiscibility events may occur, each generating its own conjugate pair of melt fractions. The strongly peralkaline melt fractions in particular are very reactive and commonly react until equilibrium is attained. Consequently, the peralkaline melt fraction is commonly preserved only in the isolated melt and mineral inclusions.

We demonstrate that the differences between melt fractions that can be seen most clearly in differing melt inclusion compositions are also visible in the composition of the resulting ore-forming and accessory minerals, and are visible on scales from a few micrometers to hundreds of meters.     

A reassessment of models for hydrocarbon generation in the Khibiny nepheline syenite complex, Kola Peninsula, Russia

Although hydrocarbon-bearing fluids have been known from the alkaline igneous rocks of the Khibiny intrusion for many years, their origin remains enigmatic. A recently proposed model of post-magmatic hydrocarbon (HC) generation through Fischer-Tropsch (FT) type reactions suggests the hydration of Fe-bearing phases and release of H₂ which reacts with magmatically derived CO₂ to form CH₄ and higher HCs. However, new petrographic, microthermometric, laser Raman, bulk gas and isotope data are presented and discussed in the context of previously published work in order to reassess models of HC generation. The gas phase is dominated by CH₄ with only minor proportions of higher hydrocarbons. No remnants of the proposed primary CO₂-rich fluid are found in the complex. The majority of the fluid inclusions are of secondary nature and trapped in healed microfractures. This indicates a high fluid flux after magma crystallisation. Entrapment conditions for fluid inclusions are 450–550 °C at 2.8–4.5 kbar. These temperatures are too high for hydrocarbon gas generation through the FT reaction. Chemical analyses of rims of Fe-rich phases suggest that they are not the result of alteration but instead represent changes in magma composition during crystallisation. Furthermore, there is no clear relationship between the presence of Fe-rich minerals and the abundance of fluid inclusion planes (FIPs) as reported elsewhere. δ¹³C values for methane range from − 22.4‰ to − 5.4‰, confirming a largely abiogenic origin for the gas. The presence of primary CH₄-dominated fluid inclusions and melt inclusions, which contain a methane-rich gas phase, indicates a magmatic origin of the HCs. An increase in methane content, together with a decrease in δ¹³C isotope values towards the intrusion margin suggests that magmatically derived abiogenic hydrocarbons may have mixed with biogenic hydrocarbons derived from the surrounding country rocks.     

Partial melting and P–T evolution of the Kodaikanal Metapelite Belt, southern India

The Kodaikanal region of the Madurai Block in southern India exposes a segment of high-grade metamorphic rocks dominated by an aluminous garnet–cordierite–spinel–sillimanite–quartz migmatite suite, designated herein as the Kodaikanal Metapelite Belt (KMB). These rocks were subjected to extreme crustal metamorphism during the Late Neoproterozoic despite the lack of diagnostic ultrahigh-temperature assemblages. The rocks preserve microstructural evidence demonstrating initial-heating, dehydration melting to generate the peak metamorphic assemblage and later retrogression of the residual assemblages with remaining melt. The peak metamorphic assemblage is interpreted to be garnet + sillimanite + K-feldspar + spinel + Fe–Ti oxide + quartz + melt, which indicates pressure–temperature (P–T) conditions around 950–1000 °C and 7–8 kbar based on calculated phase diagrams. A clockwise P–T path is proposed by integrating microstructural information with pseudosections. We show that evidence for extreme crustal metamorphism at ultrahigh-temperature conditions can be extracted even in the cases where the rocks lack diagnostic ultrahigh-temperature mineral assemblages. Our approach confirms the widespread regional occurrence of UHT metamorphism in the Madurai Block during Gondwana assembly and point out the need for similar studies on adjacent continental fragments.     

A Decision Support System for the Evaluation of Eco-engineering Strategies for Slope Protection

A decision support system (DSS) has been developed to assist expert and non-expert users in the evaluation and selection of eco-engineering strategies for slope protection. This DSS combines a qualitative hazard assessment of erosion and mass movements with a detailed catalogue of eco-engineering strategies for slope protection of which the suitability is evaluated in relation to the data entered. The slope decision support system (SDSS) is a knowledge based DSS in which knowledge is stored in frames containing rules that can evaluate the available information for a project, stored as project specific information (PSI) in a data file. The advantages of such a system are that it accepts incomplete information and that the qualitative nature of the information does not instil the user with a sense of unjustified exactitude. By its multidisciplinary and progressive nature, the DSS will be of value during the initial stages of an eco-engineering project when data collection and the potential of different eco-engineering strategies are considered. The accent of the output of the DSS is on the application of eco-engineering strategies for slope protection as an environmentally-friendly solution aiding sustainable development. For its acceptance within the engineering community, the DSS needs to prove its predictive capacity. Therefore, its performance has been benchmarked against successful and unsuccessful cases of slope stabilisation using eco-engineering. The target audience and the areas of application of this DSS are reviewed and the strategies for further development in this area suggested.     

On the Importance of Geolithological Features for the Estimate of the Site Response: The Case of Catania Metropolitan Area (Italy)

The evaluation of seismic site response in the urban area of Catania was tackled by selecting test areas having peculiar lithological and structural features, potentially favourable to large local amplifications of ground motion. The two selected areas are located in the historical downtown and in the northern part of Catania where the presence of a fault is evident. Site response was evaluated using spectral ratio technique taking the horizontal- to-vertical component ratio of ambient noise. Inferences from microtremor measurements are compared with results from synthetic accelerograms and response spectra computed at all drillings available for this area. Such method is particularly suitable in urban areas where the nature of the outcropping geological units is masked by city growth and anthropic intervention on the surface geology. The microtremor H/V spectral ratios evaluated at soft sites located within the downtown profile tend to be smaller than that usually reported in the literature for such soils. A tendency for amplifications to peaks near 2 Hz is observed only in some sites located on recent alluvial deposits. Evidences for amplifications of site effects (frequency range 4–8 Hz) were observed in the sampling sites located on the fault, with a rapid decrease of spectral amplitude just a few tenths of metres away from the discontinuity. Numerical simulations evidenced the importance of geolithological features at depth levels even greater than 20–30 m. Besides this, the results strongly confirm the importance of the subsurface geological conditions, in the estimate of seismic hazard at urban scale.     

Distribution of cadmium, chromium, copper, lead and zinc in marine sediments in Hong Kong waters

Partitioning of heavy metals (Cd, Cr, Cu, Pb, Zn) in marine sediments collected from various sites in Hong Kong waters were determined using sequential extraction method. Sediments from Kellette Bank, located in Victoria Harbour, had higher metal concentrations especially Cu and Zn than most other sites. Slightly over 20% of total Cu and Cr existed as readily available forms in Peng Chau and Kellette Bank. At most sampling sites, over 15% of the Cu existed as the exchangeable form indicating that Cu could be readily released into the aqueous phase from sediments. A significantly higher percentage of Pb and Zn was associated with the three non-residual fractions. Hence, there is a greater environmental concern for remobilization of Pb and Zn compared with Cr. The high amount of residual Cd (>50%) and the relatively lower Cd content indicate that little environmental concern is warranted for the remobilization of Cd. Distribution of metals in sediments collected from different depth at Kellette Bank shows that metal concentrations decreased with profile depth. The levels of Pb and Zn associated with the two readily available fractions increased sharply in the surface sediment. These metals represented the pollutants, which were introduced into the area in the mid-eighties through early nineties as a result of rapid economic and industrial development in the territory. As significant portions of these metals were bound to the readily available phases in the surface sediments, metal remobilization could be a concern. An erratum to this article can be found at     

The growth, collapse and quiescence of Teno volcano, Tenerife: new constraints from paleomagnetic data

Tenerife basically consists of three Miocene shield volcanoes, the Anaga, the Teno and Central shield, as well as the Pliocene Cañadas volcano. The temporal evolution and structural significance of each volcano with respect to the history of Tenerife is still a matter of debate. We present paleomagnetic results in order to enhance the view of the volcanic history of the Teno volcano by means of magnetostratigraphy. It is found that the initial subaerial phase shows reverse magnetizations throughout. After two major sector collapses, dominantly normally magnetized lavas extruded. Comparisons of observed magnetic polarities with the geomagnetic polarity timescale show that these volcanic activities occurred within 0.4 Myr between 6.3 and 5.9 Ma. Significantly younger flows, ～ 5.3 Myr old according to their radiometric age, revealed again normal polarity throughout. The absence of inversely magnetized lavas in-between the two normal periods indicates a volcanic hiatus or erosional phase. The evolutionary sequence and the estimated high production rates for the initial building phase are similar as would be expected for a hotspot volcano. The average geomagnetic field for 6.0 ± 0.2 Ma is close to an axial dipole field showing a slight far-sided/right-handed effect. The field strength, determined by Thellier-type intensity determinations, corresponds to a virtual axial dipole moment of 4.9 × 10²² A m². This value is approximately half of the present day field strength, but similar to values obtained for the mid-Miocene. It also corresponds to the proposed tertiary low-field level of the geomagnetic dipole moment.