Klüfte und Talrichtungen im Turon des südöstlichen Münsterlandes

Zusammenfassung Am Südostrand des Münsterländer Kreidebeckens fließen alle größeren Wasserläufe im Bereich der Turonkalke nach NNE oder NE, obwohl das allgemeine Gelände- und Schichtengefälle nach NNW gerichtet ist. Die Ursachen für diese Abweichung sind im Mechanismus der Felserosion zu suchen, der im wesentlichen durch die Eigentümlichkeiten der Karstgerinne und durch die Gesteinszerklüftung bestimmt wird. Bei den Detailuntersuchungen geben sich komplexe Beziehungen zwischen Fließrichtung und Kluftrichtungen zu erkennen.Besonders bedeutend für die Entstehung der NNE gerichteten Täler sind die 170°- und 30°-streichenden Klüfte.

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On the south-east border of the Cretaceous basin of Munster, Westfalia, the current directions of streams in the area of Turon-limestone go to NNE or NE, although the main dipping of land surface as well as bedding planes points towards NNW. This divergence is caused by the mechanism of rock erosion, which is determined by peculiarities of subterranean stream channels and joints in limestone. The investigations show complex relations between flow direction and direction of joints.The 170°- and 30°-striking joints are significant of the origin of the NNE direction of the valleys.

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Résumé Dans le Turonien au bord sud-est du bassin Crétacé de Münster (Westphalie) toutes les rivières coulent en direction nord-nord-est ou nord-est, quoique la surface morphologique générale et les couches soient penchées en direction nord-nord-ouest. Cette divergence est expliquée par le mécanisme de l'érosion qui dépend principalement des fentes et du caractère des ruisseaux karstiques. Pendant ces études on a pu observer des relations complexes entre la direction des courants et la direction des fentes.Les fentes en direction nord-nord-est (30°) et sud-sud-est (170°) ont considérablement influencé l'origine des vallées.

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- - , -. . . , NNE, , 170° 30°.

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Herrn Professor Dr.Roland Brinkmann zum 70. Geburtstag gewidmet.     

OCCURRENCE OF HIGH-ANGLE STRATIFICATION IN LITTORAL AND SHALLOW NERITIC ENVIRONMENTS,CENTRAL GEORGIA COAST,U.S.A.1

High-angle stratification (greater than 20°) is produced in several areas of shallow marine sedimentation along the barrier islands of the central Georgia coast. The maximum angle of inclination is 30° which is the angle of repose for the saturated, fine-grained, angular sand of this area. High-angle stratification forms in the following locations: (1) The depositional margin of tidal channel inlets. Under some wave and current conditions, sand accumulates near low tide level and steepens the depositional interface to the angle of repose. (2) The steep face of asymmetrical megaripples developed by tidal currents. Ripples with amplitudes as much as 3 ft. and wave lengths of 20–40 ft. commonly develop in channel inlets and other areas of sand sediments. (3) The steep face of sand waves formed in channel inlets. These large asymmetrical ripples have amplitudes as great as 12 ft. and wave lengths of ca. 300 ft. Lengths along the crests are over 600 ft. (4) The landward side of low bars developed on the beach. Bars and troughs (ridges and runnels) are common on the beaches of this area. The bars, which are as much as 5 ft. high, shift landward by deposition on the steep landward face. (5) The oceanward side of large sand waves at the mouth of offshore tidal channels. Large sand waves are located 6 miles offshore from Doboy Sound inlet in 20–25 ft. of water. The steep face of these asymmetrical sand waves is orientated toward the ocean. Amplitude of these large ripples is as much as 17 ft. and length along the crests is over 1/2 mile.     

A study of strontium in core 119K,Discovery deep,Red Sea

The isotopic composition of strontium of pore water and of authigenic minerals leached from the sediment of core 119K with hot aqua regia is similar to that of the brine in the Discovery deep and differs from that of normal seawater. The average ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratio of strontium removed by acid leaching is 0.7077 ± 0.0007 (1σ) compared to a value of 0.70904 for the Red Sea. The detrital silicate fraction exhibits an approximate inverse correlation between ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratios and strontium concentrations which provides tentative support for a model in which the detrital silicate fraction of deep-sea sediment is considered to be a mixture of terrigenous dust of sialic composition enriched in radiogenic ⁸⁷Sr and of volcanogenic material of basaltic composition and low ⁸⁷Sr abundance. The ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratios of the shells of foraminifers and pteropods, expressed as δ ⁸⁷Sr‰ relative to 0.70904 for seawater, decrease from $\text{?0.23 ± 0.17‰}$ at 90 cm to $\text{?0.82 ± 0.17‰}$ at 273 cm and remain constant at this value to a depth of 450 cm. The lowering of the δ ⁸⁷Sr values is attributed both to the presence of aragonite overgrowths on pteropod shells and to possible isotope exchange with strontium in the connate fluid.     

湖南省柿竹园矽卡岩矿床中石榴石特征

通过野外与显微镜观察和电子探针分析, 对柿竹园多金属矿床矽卡岩中石榴石的特征进行了研究.根据石榴石的产出状态、矿物的共生组合, 矽卡岩可分为4个带: 磁铁矿-辉石-石榴石带、辉石-石榴石带、符山石-石榴石带、矽卡岩化大理岩带.从成分上的变化, 探讨了石榴石在各矽卡岩带中的特征.柿竹园矿床矽卡岩中的石榴石可分为早、晚两期, 早期形成的石榴石颜色为暗棕色, 并且在垂直和水平方向上有明显的变化规律.从磁铁矿-辉石-石榴石带到矽卡岩化大理石带, 随着石榴石中Fe₂O₃含量的减少, Al₂O₃含量的增加, 由钙铁榴石向钙铝榴石变化; 石榴石晶体具有从核部向边缘由均质性向非均质性变化的规律.早期石榴石形成于较氧化的条件下, 温度为520~620℃, 压力为1000×105Pa, 由富含Si, Al, Fe, Cl, F组分的热液和泥盆纪佘田桥组灰岩反应交代形成.当温度降至450~ 540℃, pH, Eh值降低时, 晚期石榴石形成的同时使白钨矿沉淀.晚期石榴石颜色比早期形成的石榴石浅, 为红色.结晶颗粒较大, 并且, 普遍可以观察到石榴石环带结构.      

The use of slump structures as palaeoslope orientation estimators

The two main methods of estimating palaeoslope direction from slump structure orientation data are reviewed. The mean axis method takes the downslope direction as the perpendicular to the mean slump fold axis. The separation are method estimates the downslope direction by the bisector of a planar separation angle between groups of slump folds with opposite downplunge asymmetry. The advantages and disadvantages of each method are considered in detail, by reference first to idealized slump fold distributions and then to a compilation of sixty natural slump fold axis distributions, mostly from published data. Among the advantages of the mean axis method are the ease of deriving confidence limits for estimates and its applicability where fold asymmetry data are unavailable. The main advantage of the separation are method is its validity for strongly skewed fold axis samples. The statistical robustness of the mean axis method, however, due to its reliance on average properties of data, makes it more generally reliable than the separation arc method which depends on extreme properties of data. A procedure for determining palaeoslope directions is suggested which reflects the respective strengths of the two methods.     

Authigenie gypsum in deep-sea manganese nodules

Gypsum crystals of authigenic origin have been found in manganese nodules of the deep-sea sediment surface (4500-5500 m water depth) from the Central Pacific Ocean.     

Mössbauer spectroscopic studies of iron in organic material from natural sedimentary environments

⁵⁷Fe Mössbauer spectra have been obtained from samples of humic acid, fulvic acid and kerogen and from the organic material extracted from bituminous chalk with benzene-methanol. The spectra indicate that iron occurs in a trivalent form in the silicate residue of the humic acid fraction, as hydrated ferrous ions associated with the fulvic acid fraction, as pyrite in kerogen and in a form not detectable by Mössbauer spectroscopy in the benzene-methanol extract.     

The behaviour of dissolved organic material,iron and manganese in estuarine mixing

Fractionation by ultra-filtration of the dissolved organic material (DOM) in the River Beaulieu, with typical concentrations of dissolved organic carbon (DOC) of 7–8 mg C/l, showed it to be mainly in the nominal molecular weight range of 10³–10⁵, with 16–23% of the total DOC in the fraction > 10⁵. The molecular weight distribution of DOM in the more alkaline River Test (average DOC, 2 mg C/l) was similar. In the River Beaulieu water, containing 136–314 βg Fe/l in ‘dissolved’ forms, 90% or more of this Fe was in the nominal molecular weight fraction > 10⁵. Experiments showed that DOM of nominal molecular weight <10⁵ could stabilize Fe(III) in ‘dissolved’ forms. The concentrations of ‘dissolved’ Fe in the river water probably reflect the presence of colloidal Fe stabilized by organic material and this process may influence the apparent molecular weight of the DOM. Dissolved. Mn (100–136 βg/l) in the River Beaulieu was mainly in true solution, probably as Mn(II), with some 30% in forms of molecular weight greater than ca 10⁴.During mi xing in the Beaulieu Estuary, DOC and dissolved Mn behave essentially conservatively. This contrasts with the removal of a large fraction of the dissolved Fe (Holliday and LISS, 1976, Est. Coastal Mar. Sci. 4, 349–353). Concentrations of lattice-held Fe and Mn in suspended particulate material were essentially uniform in the estuary, at 3.2 and 0.012%, respectively, whereas the non-lattice held fractions decreased markedly with increase in salinity. For Mn the decrease was linear and could be most simply accounted for by the physical mixing of riverborne and marine participates, although the possibility that some desorption occurs is not excluded. The non-linear decrease in the concentration of non-lattice held Fe in particulates reflected the more complex situation in which physical mixing is accompanied by removal of material from the ‘dissolved’ fraction.     

Phase Relations and Crystallization Sequence in a Contact-Metamorphosed Rock from the Gunflint Iron Formation, Minnesota

Portions of the Gunflint Iron Formation, originally a ferruginoussediment, were metamorphosed by the intrusion of the DuluthComplex to assemblages containing: pigeonite (Wo₁₀En₂₄Fs₆₆)+olivine(Fo₁₃Fa₃₇)+Fe-Ti oxide (Mt₆₂Usp₃₄Hc₄)+plagioclase (An₉₄Ab₆)+vapor+augite (Wo₄₀En₂₀Fs₄₀) or cummingtonite Fe/(Fe+Mg) {smalltilde} 0.69; quartz was present but probably was not in equilibriumwith olivine. Comparison with synthetic phase-equilibrium studiesindicate conditions of initial recrystallization of T 800 °C,P_total 2kb, fo₂ slightly below that of the pure fayalite-magnetite-quartzassemblage, and P_H2O < P_total. During the slow cooling process following initial recrystallization,the phases present underwent a complex series of exsolution,inversion, oxidation, and hydration reactions. Pigeonite initiallyexsolved augite along (001), then inverted to orthopyroxene,which then exsolved augite along (100). The augite exsolvedonly pigeonite on (001) during its cooling history. The Fe-Tioxide for the most part oxidized to an intergrowth of magnetiteand ilmenite, although unoxidized portions later exsolved ulvöspinel.Cummingtonite exsolved actinolite, forming irregular patchesof the latter. Olivine, orthopyroxene, and augite reacted withplagioclase to form retrograde amphiboles. Orthopyroxene had difficulty nucleating during this slow coolingprocess, forming only at widely spaced points in mosaics ofprimary pigeonite grains, and never nucleating within primaryaugite grains. The resulting orthopyroxene grains are much largerthan the original pigeonite grains.     

Oxygen isotope fractionation between rutile and water

Synthetic rutile-water fractionations (1000 ln α) at 775, 675, and 575° C were found to be ?2.8, ?3.5, and ?4.8, respectively. Partial exchange experiments with natural rutile at 575° C and with synthetic rutile at 475° C failed to yield reliable fractionations. Isotopic fractionation within the range 575–775° C may be expressed as follows: 1 $$1000\ln \alpha ({\rm T}i{\rm O}_{2 } - H_2 O) = - 4.1 \frac{{10^6 }}{{T_{k^2 } }} + 0.96$$ . Combined with previously determined quartz-water fractionations, the above data permit calibration of the quartz-rutile geothermometer: 1 $$1000\ln \alpha ({\text{S}}i{\rm O}_{2 } - Ti{\rm O}_{2 } ) = 6.6 \frac{{10^6 }}{{T_{k^2 } }} - 2.9$$ . When applied to B-type eclogites from Europe, as an example, the latter equation yields a mean equilibration temperature of 565° C.