Magnetic properties of the Lower Old Red Sandstone lavas in the Midland Valley,Scotland; palaeomagnetic and tectonic considerations

Thermal demagnetization studies of lavas in the Strathmore area of the Midland Valley, Scotland, support overall palaeomagnetic data found in previous studies of these rocks. Reduced directional scatter as compared to some earlier studies, is attributed to more effective demagnetization, resolving some of the directional complexity of previous studies. Combined magnetic fabric and directional analysis suggest that at least some deviating directions may be explained by local tectonism. The existence of almost antiparallel directional groups and field tests give supporting evidence for a “primary” (deuteric) origin of the main magnetization of these rocks. Additionally, a second remanence component having shallow reverse directions of magnetization, is attributed to later remagnetization in Old Red Sandstone time. The Midland Valley results are seen in conjunction with other Palaeozoic palaeomagnetic results and possible geodynamic implications are discussed.     

Biosorption of Rare-Earth Elements and Yttrium by Heterotrophic Bacteria in an Aqueous Environment

This paper reports the results of the experimental determination of the coefficient of sorption of rare-earth elements and yttrium (REY) under conditions of acidic pH using several strains of heterotrophic bacteria (Microbacterium sp., Curtobacterium sp., Bacillus subtilis, Pseudomonas putida, and Bacillus pumilis) that are widespread in natural and technogenic waters of the Far East (Russia). Insignificant fractionation between heavy and light rare-earth elements, negative cerium and dysprosium anomalies, and a positive europium anomaly were revealed. The selectivity of REY biosorption by gram-positive and gram-negative bacteria, as well as inertia of the biosorption process under more acidic conditions of the medium, were shown.     

A study of bernalite,Fe(OH)3, using Mössbauer spectroscopy,optical spectroscopy and transmission electron microscopy

To study the crystal chemistry of bernalite, Fe(OH)₃, and the nature of the octahedral Fe³⁺ environment, Mössbauer spectra were recorded from 80 to 350 K, optical spectra were recorded at room temperature and a sample was studied using transmission electron microscopy. The Mössbauer spectrum of bernalite consists of a single six-line magnetic spectrum at 80 K. A broadened six-line magnetic spectrum with significantly less intensity is observed at higher temperatures, and is attributed to a small fraction of bernalite occurring as small particles. The variation of hyperfine magnetic field data for bulk bernalite with temperature is well described by the Weiss molecular field model with parameters of H ₀ = 55.7±0.3 T and T _N = 427±5K. The centre shift data were fitted to the Debye model with parameters ₀=0.482±0.005 mm/s (relative to -Fe) and _M=492±30 K. The quadrupole shift is near zero at 300 K, and does not vary significantly with temperature. Absorption spectra in the visible and near infrared range show three crystal field bands of Fe³⁺ at 11 300, 16000 and 23 200 cm^-1, giving a crystal field splitting of 14 570 cm^-1 and Racah parameters of B=629 cm^-1 and C=3381 cm^-1. Infrared reflection spectra show two distinct OH-stretching frequencies, which could correspond to two structurally different types of OH groups. A band was also observed at 2250 cm^-1, suggesting the presence of molecular CO₂ in the large cation site. Analytical transmission electron microscopy indicates that Si occurs within the bernalite structure as well as along domain boundaries. Electron diffraction and imaging show that bernalite is polysynthetically twinned along {100} planes with twin domains ranging from 3 to 20 nm in thickness. Results are discussed with respect to the nature of the octahedral Fe³⁺ site, and compared with values for other iron oxides and hydroxides.     

Landslide triggering scenarios in homogeneous geological contexts: The area surrounding Acri (Calabria, Italy)

The paper describes a methodology to detect landslide triggering scenarios in geological homogeneous areas and for some specific landslide categories. In these scenarios, the rainfall–landslide relationship as well as the pluviometric load conditions influencing slope instability have to be investigated.The methodology is applied to an area located in northern Calabria (Italy) and affected by widespread and different slope instability phenomena. Outcropped, fractured, and deeply weathered crystalline rock masses, determining geologic homogeneous conditions, are present. In the same area, suitable and homogeneous climatic features have also been found.According to the methodology adopted, the hydrologic analysis of rainfall time-series is initially carried out notwithstanding historical data concerning landslide mobilization, but using simple models to determine critical pluviometric scenarios for the three landslide categories: shallow, medium-deep, and deep. Landslide-triggering scenarios individualized according to this procedure are less significant as compared to the landslide mobilization detected in the study area by means of historical research and ascribed to the three landslide categories according to geomorphologic analysis.Subsequently, the possible landslide triggering scenarios are outlined by carefully investigating the hydrologic analysis limited to the periods identified according to the historical data.In the study area and approximately for all the areas characterized by the outcrop of fractured and deeply weathered crystalline rocks, significant triggering scenarios can be outlined. In particular, shallow landslide triggers could be activated by rainfall events with intensities exceeding 90 mm/day and/or with amounts exceeding 160 mm. As for medium-deep and deep landslides, triggering mechanisms are more complicated; and effective rainfall contribution must be taken into account compared to groundwater storage. Moreover, a more complex link between deep landslides and precipitation is confirmed.The results obtained to date highlight the potential of this methodology, which enables us to define and progressively improve the knowledge framework by means of a work sequence integrating different disciplinary tools and results.     

On molecules in sunspots

Spectra of umbrae of several sunspots in the wavelength region 4000–8000 Å scanned photoelectrically at the Göttingen Locarno Observatory were used in order to search for absorption lines of molecules. Several thousands of lines of known molecules were reidentifled (see Table II and Table III). Newly identified molecules are CoH, NiH and H₂O (see Table IV and Wöhl (1969a)). The Zeemann effect on molecular lines (of MgH and CaH; see Table V and Wöhl (1969b)) in spectra of umbrae was detected.     

First Byurakan Spectral Sky Survey. Stars of Late Spectral Types. XI. Zone -7° ≤ δ ≤ -3°

The eleventh list of faint late M and carbon type stars detected on the plates of the First Byurakan Spectral Survey in zone -7° -3° and covering about 1000 square degrees is presented. From 126 detected stars, 88 are newly discovered objects: they are 6 carbon stars, 8 carbon star candidates, and 74 M-type stars; among the latter 38 (26 PSC + 12 FSC) are unclassified IRAS sources, and one object is an unclassified ROSAT source. Distances to the 6 newly discovered early-type carbon stars are estimated. Equatorial coordinates, red magnitudes, and spectral classes determined from the Palomar E-charts are provided. The lack of optical counterparts on Palomar O and E maps for two detected late M-type stars indicates a large variability in brightnesses of these objects (amplitude not smaller than 7.0 magnitude).     

Ranking of Placer Gold Prospects in Chile Through Analytic Hierarchy Process

Chile has a rich, but poorly known history of placer gold mining. At present, this sector is almost nonexistent and there are some restrictions for its revival: disperse and partial information on existing resources and limited technical expertise to assess the potential of placer gold mine sites. This paper presents the background, methodology and results of the prioritization process of known prospects of this kind in Chile. This research was part of a publicly funded project aimed to incentivize the development of this industry. The ranking was carried out using the analytic hierarchy process, which allowed to include different quantitative and qualitative variables related to the economic potential, technical aspects, contextual viability and socioeconomic factors in the analysis. The results show that, despite the increasing relevance of environmental and community issues in mining development, the business potential and the economic/technical aspects are the main factors in the early selection of a site to advance in exploration and development activities. Both variables represented around 40% and 37% of weights in the final selection, respectively. In contrast, contextual viability and local socioeconomic impacts only accounted for the remaining 23%. This study also shows that the inclusion of experts with different backgrounds in the process enriches the analysis and does not significantly distort the final outcome of the prioritization. Finally, the relevance of using MCDM tools when assessing the attractiveness of mine sites for their development is highlighted, particularly when public funds for subsequent exploration activities are committed.