Modelling interactions between fold–thrust belt deformation, foreland flexure and surface mass transport

Interactions between fold and thrust belt deformation, foreland flexure and surface mass transport are investigated using a newly developed mathematical model incorporating fully dynamic coupling between mechanics and surface processes. The mechanical model is two dimensional (plane strain) and includes an elasto‐visco‐plastic rheology. The evolving model is flexurally compensated using an elastic beam formulation. Erosion and deposition at the surface are treated in a simple manner using a linear diffusion equation. The model is solved with the finite element method using a Lagrangian scheme with marker particles. Because the model is particle based, it enables straightforward tracking of stratigraphy and exhumation paths and it can sustain very large strain. It is thus ideally suited to study deformation, erosion and sedimentation in fold–thrust belts and foreland basins. The model is used to investigate how fold–thrust deformation and foreland basin development is influenced by the non‐dimensional parameter , which can be interpreted as the ratio of the deformation time scale to the time scale for surface processes. Large values of imply that the rate of surface mass transport is significantly greater than the rate of deformation. When , the rates of surface processes are so slow that one observes a classic propagating fold–thrust belt with well‐developed wedge top basins and a largely underfilled foreland flexural depression. Increasing causes (1) deposition to shift progressively from the wedge top into the foredeep, which deepens and may eventually become filled, (2) widespread exhumation of the fold–thrust belt, (3) reduced rates of frontal thrust propagation and possible attainment of a steady‐state orogen width and (4) change in the style and dynamics of deformation. Together, these effects indicate that erosion and sedimentation, rather than passively responding to tectonics, play an active and dynamic role in the development of fold–thrust belts and foreland basins. Results demonstrate that regional differences in the relative rates of surface processes (e.g. because of different climatic settings) may lead to fold–thrust belts and foreland basins with markedly different characteristics. Results also imply that variations in the efficiency of surface processes through time (e.g., because of climate change or the emergence of orogens above sea level) may cause major temporal changes in orogen and basin dynamics.     

Multisite surface reaction versus transport control during the hydrolysis of a complex oxide

Dissolution experiments of a tholeiite basalt glass carried out at different pH and T (up to 300°C) using a rotatingdisc apparatus show that, depending on pH and T, dissolution can be controlled by one of the following steps: (1) surface reaction; (2) transport of reactants in solution; and (3) mixed reaction. The activation energies of these different processes were found to be 60, 9 and 15–50 kJ mol⁻¹, respectively. Taking account of these results, it appears likely that surface reactions are not rate limiting for the hydrolysis of most crystalline silicate minerals in hydrothermal and metamorphic processes, and that caution should be exercised when predicting rate of reactions at high temperatures solely on the basis of activation energies measured at low temperatures.

Comparison of experimental and theoretical potentiometric titrations of the basalt glass and its constituent oxides indicates that the adsorption of H⁺ and OH⁻ ions at the basalt surface is metal cation specific and that the net adsorption can be predicted from the sole knowledge of the acidity constants of the network-forming constituent oxides. We found that in the acidic pH region dissolution is promoted by the adsorption of H⁺ on al and Fe surface sites while in the basic region, dissolution is promoted by the adsorption of OH⁻ on Si sites. The combination of the two distinct types of surface sites, Al and Fe on the one hand, and Si on the other hand, results in a dissolution rate minimum at a pH-value between the pH_zpc of the two groups of oxide components. Linear regressions with a slope n=3.8 are observed both in acid and alkaline solutions in logarithmic plots of the rate of dissolution vs. the surface charge. The value of n, which represents the number of protonation or hydroxylation steps prior to metal detachment, has been found equal to the mean valence of the network-forming metals.

Combining concepts of surface coordination chemistry with transition state theory afforded characterisation of the activated complexes involved in basalt dissolution processes. From the values obtained for the thermodynamic properties of activation for basalt dissolution it is assumed that the activated complexes formed during the H₂O-promoted dissolution of the basalt glass are more tightly bonded than those formed during H⁺- or OH⁻-promoted dissolution.     

A data assimilation approach to discharge estimation from space

River discharge is currently monitored by a diminishing network of gauges, which provide a spatially incomplete picture of global discharges. This study assimilated water level information derived from a fused satellite Synthetic Aperture Radar (SAR) image and digital terrain model (DTM) with simulations from a coupled hydrological and hydrodynamic model to estimate discharge in an un‐gauged basin scenario. Assimilating water level measurements led to a 79% reduction in ensemble discharge uncertainty over the coupled hydrological hydrodynamic model alone. Measurement bias was evident, but the method still provided a means of improving estimates of discharge for high flows. The study demonstrates the potential of currently available synthetic aperture radar imagery to reduce discharge uncertainty in un‐gauged basins when combined with model simulations in a data assimilation framework, where sufficient topographic data are available. The work is timely because in the near future the launch of satellite radar missions will lead to a significant increase in the volume of data available for space‐borne discharge estimation. Copyright © 2009 John Wiley & Sons, Ltd.     

Slope-control on the aspect ratio of river basins

Although it is traditionally thought that drainage basins are geometrically similar, we present new results which indicate that the aspect ratio of weakly dissected river basins at large scales (10–10³ km²) depends on the surface slope: steeper surfaces develop narrower and lengthier basins whereas more gently dipping surfaces develop more equant and wider basins. This relationship is interpreted to be related to the nature of water flow over rough surfaces, with steeper slopes causing less flow convergence and lengthier and narrower basins. We derive an empirical relationship that can be used to infer the slope of a surface on which a river basin acquired its geometry based solely on a measure of its basin form. This relation provides a unique means of inferring the relative chronology of river basin development with respect to surface tilting and therefore provides a direct link between river basin morphology and tectonics.     

The lacustrine microbial carbonate factory of the successive Lake Bonneville and Great Salt Lake,Utah, USA

The Bonneville Basin is a continental lacustrine system accommodating extensive microbial carbonate deposits corresponding to two distinct phases: the deep Lake Bonneville (30 000 to 11 500 ¹⁴C bp ) and the shallow Great Salt Lake (since 11 500 ¹⁴C bp ). A characterization of these microbial deposits and their associated sediments provides insights into their spatio‐temporal distribution patterns. The Bonneville phase preferentially displays vertical distribution of the microbial deposits resulting from high‐amplitude lake level variations. Due to the basin physiography, the microbial deposits were restricted to a narrow shoreline belt following Bonneville lake level variations. Carbonate production was more efficient during intervals of relative lake level stability as recorded by the formation of successive terraces. In contrast, the Great Salt Lake microbial deposits showed a great lateral distribution, linked to the modern flat bottom configuration. A low vertical distribution of the microbial deposits was the result of the shallow water depth combined with a low amplitude of lake level fluctuations. These younger microbial deposits display a higher diversity of fabrics and sizes. They are distributed along an extensive ‘shore to lake’ transect on a flat platform in relation to local and progressive accommodation space changes. Microbial deposits are temporally discontinuous throughout the lake history showing longer hiatuses during the Bonneville phase. The main parameters controlling the rate of carbonate production are related to the interaction between physical (kinetics of the mineral precipitation, lake water temperature and runoff), chemical (Ca²⁺, Mg²⁺ and HCO₃^? concentrations, Mg/Ca ratio, dilution and depletion) and/or biological (trophic) factors. The contrast in evolution of Lake Bonneville and Great Salt Lake microbial deposits during their lacustrine history leads to discussions on major chemical and climatic changes during this interval as well as the role of physiography. Furthermore, it provides novel insights into the composition, structure and formation of microbialite‐rich carbonate deposits under freshwater and hypersaline conditions.     

A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.