Influence of injection conditions on field tracer experiments

Calibration of ground water transport models is often performed using results of field tracer experiments. However, little attention is usually paid to the influence, on resulting breakthrough curves, of injection conditions and well-aquifer interactions, more particularly of the influence of the possible trapping of the tracer in the injection wellbore. Recently, a new mathematical and numerical approach has been developed to model injection conditions and well-aquifer interactions in a very accurate way. Using an analytical solution derived from this model, a detailed analysis is made of the evolution of the tracer input function in the aquifer. By varying injection conditions from one simulation to another, synthetic breakthrough curves are generated with the SUFT3D ground water flow and transport finite-element simulator. These tests show clearly that the shape of the breakthrough curves can be dramatically affected by injection conditions. Using generated breakthrough curves as "actual" field results, a calibration of hydrodispersive parameters is performed, neglecting the influence of injection conditions. This shows that neglecting the influence of actual injection conditions can lead to (1) errors on fitted parameters and (2) misleading identification of the active transport processes. Conclusions and guidelines are drawn in terms of proposed methodologies for better controlling the tracer injection in the field, in order to minimize risk of misinterpretation of results.     

Energetics of water dissolution in trachyte glasses and liquids

Enthalpies of dissolution in HF solutions have been measured at 323 K for a series of hydrous trachyte glasses. Enthalpies of mixing between water and molten trachyte have then been calculated from heat capacity data for the same set of samples and available enthalpy for pure water. The moderately negative enthalpies of mixing suggested at 1 bar by the measurements made on glasses almost disappear when trachyte liquids and water are referred to the same temperature, and particularly so when enthalpies of mixing are calculated for a few kbars pressure. As found for albite and phonolite liquids, trachyte melts thus appear to mix nearly ideally as far as enthalpy is concerned. These results imply that the enthalpy of exsolution of water from magmas is very small or negligible under the P-T-X conditions relevant to trachytic volcanism, even for complete degassing of up to 5 wt% H₂O. Furthermore, the viscosity increase associated with exsolution-driven cooling is negligible compared to the decrease caused directly by water exsolution.     

Reconstructing 4000 years of mass movement and tsunami history in a deep peri‐Alpine lake (Lake Geneva,France‐Switzerland)

The study of mass movements in lake sediments provides insights into past natural hazards at historic and prehistoric timescales. Sediments from the deep basin of Lake Geneva reveal a succession of six large‐scale (volumes of 22 × 10⁶ to 250 × 10⁶ m³) mass‐transport deposits, associated with five mass‐movement events within 2600 years (4000 cal bp to 563 ad ). The mass‐transport deposits result from: (i) lateral slope failures (mass‐transport deposit B at 3895 ± 225 cal bp and mass‐transport deposits A and C at 3683 ± 128 cal bp ); and (ii) Rhône delta collapses (mass‐transport deposits D to G dated at 2650 ± 150 cal bp , 2185 ± 85 cal bp , 1920 ± 120 cal bp and 563 ad , respectively). Mass‐transport deposits A and C were most probably triggered by an earthquake, whereas the Rhône delta collapses were likely to be due to sediment overload with a rockfall as the external trigger (mass‐transport deposit G, the Tauredunum event in 563 ad known from historical records), an earthquake (mass‐transport deposit E) or unknown external triggers (mass‐transport deposits D and F). Independent of their origin and trigger mechanisms, numerical simulations show that all of these recorded mass‐transport deposits are large enough to have generated at least metre‐scale tsunamis during mass movement initiation. Since the Tauredunum event in 563 ad , two small‐scale (volumes of 1 to 2 × 10⁶ m³) mass‐transport deposits (H and I) are present in the seismic record, both of which are associated with small lateral slope failures. Mass‐transport deposits H and I might be related to earthquakes in Lausanne/Geneva (possibly) 1322 ad and Aigle 1584 ad , respectively. The sedimentary record of the deep basin of Lake Geneva, in combination with the historical record, show that during the past 3695 years, at least six tsunamis were generated by mass movements, indicating that the tsunami hazard in the Lake Geneva region should not be neglected, although such events are not frequent with a recurrence time of 0·0016 yr^?1.     

A New Interlaboratory Characterisation of Silicon,Rare Earth Elements and Twenty‐Two Other Trace Element Concentrations in the Natural River Water Certified Reference Material SLRS‐6 (NRC‐CNRC)

The natural river water reference material SLRS‐6 (NRC‐CNRC) is the newest batch of a quality control material routinely used in many international environmental laboratories. This work presents a nine‐laboratory compilation of measurements of major and trace element concentrations and their related uncertainties, unavailable in the NRC‐CNRC certificate (B, Cs, Li, Ga, Ge, Hf, Nb, P, Rb, Rh, Re, S, Sc, Se, Si, Sn, Th, Ti, Tl, W, Y, Y, Zr and REEs). Measurements were mostly made using inductively coupled plasma‐mass spectrometry. The results are compared with equivalent data for the last batch of the material, SLRS‐5, measured simultaneously with SLRS‐6 in this study. In general, very low concentrations, close to the quantification limits, were found in the new batch. The Sr isotopic ratio is also reported.     

THE DETERMINATION OF FLUORINE BY PROTON INDUCED GAMMA RAY EMISSION SPECTROMETRY (PIGE) IN EIGHTEEN CHINESE STANDARD REFERENCE SAMPLES OF STREAM SEDIMENTS, SOILS AND ROCKS: GSD 9-12, GSS 1-8 AND GSR 1-6

Eighteen new Chinese standard reference samples (including stream sediments, soils and rocks) have been analysed by an automated proton induced gamma ray emission (PIGE) method for fluorine. Results of determinations are reported and are generally in good agreement with the "usable values" previously published.     

Potential evidence for slab detachment from the flexural backstripping of a foredeep: Insight on the evolution of the Pescara basin (Italy)

The discrepancy between the size of the Apenninic chain and the depth of the Adriatic foredeep is investigated using 2D flexural backstripping on well‐constrained depth‐converted cross‐sections in the Pescara basin (Central Italy). The procedure consisted of removal, uplift, unfolding and unfaulting of the Pliocene–Pleistocene foreland deposits to produce a palaeogeographic map of the basin at the end of the Messinian and to constrain sedimentary rates since the Miocene. Results are found to support the contribution of an external load to the foreland evolution together with the Apenninic chain load. The interplay of the two types of loads resulted in spatial and temporal variations of the foredeep evolution that are quantified by palaeogeographic maps and sedimentation rates obtained through backstripping. Results are interpreted as representing the effects of a southward‐migrating wave linked to slab detachment beneath the Adriatic foredeep. This procedure can be useful to investigate similar problems on other chains worldwide.     

A hydrofluoric acid solution calorimetric investigation of glasses in the systems NaAlSi3O8-KAlSi3O8 and NaAlSi3O8-Si4O8

Glasses in the systems NaAlSi₃O₈-KAlSi₃O₈ and NaAlSi₃O₈-Si₄O₈ have been studied by means of hydrofluoric acid solution calorimetry at 50°C. Results indicate small negative enthalpies of mixing in the former system and small positive departures from ideality in the latter.     

Spatial variability of palaeosols across Cretaceous interfluves in the Dunvegan Formation, NE British Columbia, Canada: palaeohydrological, palaeogeomorphological and stratigraphic implications

A basic sedimentological and palaeopedological framework is now in place for non-marine sequence models. The variability of interfluve palaeosols has not, however, been systematically documented, nor have the stratigraphic implications of that variability been incorporated into sequence models. Interfluve palaeosol variability in the deltaic Dunvegan Formation, NE British Columbia, Canada, is investigated, for which a detailed allostratigraphic and palaeogeographic framework has been developed, based on abundant well (> 2300 logs) and outcrop (> 60 sections) control. Regionally extensive valley fills and interfluves have been mapped in coastal plain deposits over an area of about 50 000 km². This palaeogeographic framework permits interfluve surfaces exposed in outcrop to be located in terms of distance from the margins of coeval valleys. The micromorphological, geochemical and mineralogical characteristics of five representative sequence-bounding palaeosols located from 250 m to more than 15 km from coeval valley margins are described. These interfluve palaeosols are similar to modern Alfisols and all record (i) aggradation on an alluvial/coastal plain; (ii) a subsequent static and/or degradational phase related to valley incision, non-deposition and soil thickening; and (iii) a final aggradational phase related to valley filling and renewed sedimentation across the coastal plain. Within this overall template, however, variations in palaeosol thickness, redoximorphic features, illuvial clay content and geochemistry suggest developmental control by hydrological characteristics that were influenced by both the nature of the underlying alluvial sediments and distance from the valley margin. The presence of mature interfluve palaeosols with complex developmental histories suggests that landscape dissection may have been related to terrace development associated with valley incision. Palaeosols closer to valley margins are thicker, contain more illuvial clay and display characteristics suggesting better drained conditions relative to those palaeosols that developed further from valley margins. Subsequent deposition on interfluves also reflects distance from valleys, with those sites close to valleys accumulating cumulic soils with evidence of brackish groundwater, whereas far from valleys (> 10–15 km), groundwater was fresh and clastic supply minimal, encouraging peat formation. Variations in drainage and palaeotopography during landscape dissection resulted in different palaeosol development styles on interfluve surfaces that can be shown, on the basis of physical correlation, to have the same geomorphic age. These observations support the concept of the soil-forming interval as a basis for pedostratigraphic correlation in ancient terrestrial deposits. Palaeosol variability on interfluves is to be expected, and recognition and documentation of this variability is an important prerequisite to palaeogeomorphological, palaeoclimatic and sequence stratigraphic interpretations.     

Classifications of retail stores and shopping centres: some methodological issues

This paper reviews current methods used in classifying retail outlets and areas devoted to retailing, in the geographical and town planning literature. For retail outlets, classifications based upon types of goods sold, and types of shopping trip, are discussed. This is followed by an analysis of modern large store development which reflects property developers' and retailers' concerns. Areas devoted to retail uses are subdivided into unplanned ‘retail areas’ and planned ‘shopping centres’. Traditional classifications based upon central place theory are reviewed for both of these types, and found wanting in the light of recent changes in retail development practice and consumer behaviour. Classifications based upon physical development characteristics and type of shopping trip are recommended. Finally, classifications of urban retail location are examined. This revised version was published online in July 2006 with corrections to the Cover Date.