Geochronology and Landscape Development Along the Middle Río Quequén Grande at the Paso Otero Locality,Pampa Interserrana,Argentina

The Paso Otero Locality is a cluster of archaeological sites within the middle Río Quequén Grande basin located in the northern coastal plain of Argentina. The valley fill is Holocene alluvial, eolian, and palustrine sediment, including the top of the Guerrero Member (∼10,000 ¹⁴C yr B.P.), upper Río Salado Member (∼3000 ¹⁴C yr B.P.), and lower La Postrera Formation (∼2400 ¹⁴C yr B.P.). Regional soils include the Puesto Callejón Viejo (10,000 to 9400 ¹⁴C yr B.P.) and the Puesto Berrondo (∼4800 ¹⁴C yr B.P.). Radiocarbon sampling of buried A‐horizons on both sides of the river produced 17 dates considered reliable. The geoarchaeological information allows exploration of the implications for the formation of the archaeological record. Similar geological processes of differential intensity have resulted in contexts of different archaeological resolution and integrity. The Paso Otero Locality provides both a local and regional view of late Quaternary events and processes for the middle basin of the Río Quequén Grande.     

Simulation of Geological Contacts from Interpreted Geological Model Using Multiple-Point Statistics

Applications of multiple-point statistics (mps) algorithms to large non-repetitive geological objects such as those found in mining deposits are difficult because most mps algorithms rely on pattern repetition for simulation. In many cases, an interpreted geological model built from a computer-aided design system is readily available but suffers as a training image due to the lack of patterns repetitiveness. Porphyry copper deposits and iron ore formations are good examples of such mining deposits with non-repetitive patterns. This paper presents an algorithm called contactsim that focuses on reproducing the patterns of the contacts between geological types. The algorithm learns the shapes of the lithotype contacts as interpreted by the geologist, and simulates their patterns at a later stage. Defining a zone of uncertainty around the lithological contact is a critical step in contactsim, because it defines both the zones where the simulation is performed and where the algorithm should focus to learn the transitional patterns between lithotypes. A larger zone of uncertainty results in greater variation between realizations. The definition of the uncertainty zone must take into consideration the geological understanding of the deposit, and the reliability of the contact zones. The contactsim algorithm is demonstrated on an iron ore formation.     

Arsenic and metal mobility from Au mine tailings in Rodalquilar (Almería,SE Spain)

In the old mining area of Rodalquilar, mine wastes, soil and sediments were characterized and the results revealed high concentration of Au, Ag, As, Bi, Cu, Fe, Mn, Pb, Se, Sb and Zn in tailings and sediments. The contaminant of greatest environmental concern is As. The mean concentration in the tailings was 679.9, and 345 mg/kg in the sediments of Playazo creek. The groundwater samples from the alluvial aquifer showed high concentration of Al, As, Cd, Fe, Hg, Mn, Ni, Pb, Se, Sb and Zn and very high concentration of chloride and sulfate, which were above the concentration defined in the European standards for drinking water. The presence of As in groundwater may be caused by the oxidation of arsenian pyrite, the possible As desorption from goethite and ferrihydrite and the jarosite dissolution. Groundwater concentrations of Cd, Fe, Mn, and possibly Cu, were associated with low values of Eh, indicating the possible dissolution of oxy-hydroxides of Fe and Mn. The mobility of metals in the column experiments show the release of Al, Fe, Mn, Cr, Cu, Ni, V and Zn in significant concentrations but below the detected values in groundwater. However, As, Cd, Sb, Se Pb and Au, are generally mobilized in concentrations above the detected values in groundwater. The possible mass transfer processes that could explain the presence of the contaminants in the aquifer and the leachates was simulated with the PHREEQC numerical code and revealed the possible dissolution of the following mineral phases: jarosite, natrojarosite, arsenian pyrite, alunite, chlorite, kaolinite and calcite.     

Climate changes and human activities recorded in the sediments of Lake Estanya (NE Spain) during the Medieval Warm Period and Little Ice Age

A multi-proxy study of short sediment cores recovered in small, karstic Lake Estanya (42°02?? N, 0°32?? E, 670 m.a.s.l.) in the Pre-Pyrenean Ranges (NE Spain) provides a detailed record of the complex environmental, hydrological and anthropogenic interactions occurring in the area since medieval times. The integration of sedimentary facies, elemental and isotopic geochemistry, and biological proxies (diatoms, chironomids and pollen), together with a robust chronological control, provided by AMS radiocarbon dating and ²¹⁰Pb and ¹³⁷Cs radiometric techniques, enabled precise reconstruction of the main phases of environmental change, associated with the Medieval Warm Period (MWP), the Little Ice Age (LIA) and the industrial era. Shallow lake levels and saline conditions with poor development of littoral environments prevailed during medieval times (1150?C1300 AD). Generally higher water levels and more dilute waters occurred during the LIA (1300?C1850 AD), although this period shows a complex internal paleohydrological structure and is contemporaneous with a gradual increase of farming activity. Maximum lake levels and flooding of the current littoral shelf occurred during the nineteenth century, coinciding with the maximum expansion of agriculture in the area and prior to the last cold phase of the LIA. Finally, declining lake levels during the twentieth century, coinciding with a decrease in human pressure, are associated with warmer climate conditions. A strong link with solar irradiance is suggested by the coherence between periods of more positive water balance and phases of reduced solar activity. Changes in winter precipitation and dominance of NAO negative phases would be responsible for wet LIA conditions in western Mediterranean regions. The main environmental stages recorded in Lake Estanya are consistent with Western Mediterranean continental records, and show similarities with both Central and NE Iberian reconstructions, reflecting a strong climatic control of the hydrological and anthropogenic changes during the last 800 years.     

Separation of Different Contributions to the Total X-ray Luminosity in Gamma-ray Loud Blazars

The relativistic beaming model has been successfully used to explain many of the observational properties of active galactic nuclei. In this model the total emission is formed by two components, one beamed, one unbeamed. However, the exact contribution from each component in unresolved sources is still not clear. In the radio band, the core and extended emissions are clearly separated. We adopt the method proposed by Kembhavi to separate the two contributions in the X-ray emissions in a sample of 19 gamma-ray loud blazars. It is clearly shown that the beamed emission dominates the X-ray flux and the unbeamed X-ray emission is correlated with the extended radio emission of the considered objects. We also find that the ratio of the beamed to the unbeamed X-ray luminosity is correlated with the X-ray spectral index, an effect that should be a consequence of the underlying X-ray emission mechanism.