Magnetic susceptibility and electrical conductivity as a proxy for evaluating soil contaminated with arsenic,cadmium and lead in a metallurgical area in the San Luis Potosi State,Mexico

A total of 113 samples of waste and soil were collected from a site in the state of San Luis Potosi, Mexico, that was occupied for several years by the metallurgical industry. Specific magnetic susceptibility (MS), electrical conductivity (EC) and pH were determined, as well as the total and available concentrations of potentially toxic elements (PTEs) such as As, Cd, Cu, Fe, Pb and Zn, which may cause a health risk for humans, animals and ecosystems, and the concentrations of major ions in aqueous extracts of soils and wastes. The solid phases of the samples were also characterized. The results revealed that the soils and wastes exhibited elevated values of PTEs, MS and EC. For soils these values decreased with increasing distance from the waste storage sites. The MS values were elevated primarily due to the presence of Fe-oxyhydroxides, such as magnetite, hematite and goethite, which contain PTEs in their structure leading to a high correlation between the value of MS and the As, Cd, Fe and Pb contents (r = 0.57–0.91) as well as between the PTEs values (r = 0.68–0.92). The elevated EC values measured in the metallurgical wastes were the result of presence of the sulfate minerals of Ca, Mg and Fe. The pollution index, which indicates the levels of simultaneous toxicity from elements such as As, Cd and Pb, was determined, with extreme hazard zones corresponding to areas that exhibit high MS values (0.91 correlation). In conclusion, MS measurements can be used as an indirect indicator to evaluate the PTE contamination in metallurgical areas, and EC measurements can aid in the identification of pollution sources.     

A software solution for point counting. Petrographic thin section analysis as a case study

In the field of geology, as in many other fields, a common problem is the analysis of 2D sections. An example of this is the petrographic study of rock samples, i.e., the quantification of its mineral components and the percentages of each phase present in it. Conventionally, this quantification has been determined by point counting performed on thin sections. Although point counting is very time consuming, it is of common use in several domains including geology, biology, medicine, and materials sciences, among others. Point counting in thin sections is normally conducted through mechanical or electromechanical devices attached to a microscope; such devices are very expensive, offer limited functionality, and are very time consuming. In this contribution, we introduce an interactive visualization application called Rock.AR that reduces the amount of time required to apply this technique and simplify its work flow. It provides visual tools like distortion techniques, overview + detail, and statistics to assist the technique. A comparison between this application and similar tools through users' experiences is provided. We compare the time it takes to complete a session of point counting and the tools' usability.     

Molecular gas in young planetary nebulae

We review our recent results concerning the molecular gas content of young planetary nebulae NGC 2346, M 2–9, and NGC 6720 (the Ring Nebula in Lyra).Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.     

The challenge of dating early pleistocene fossil teeth by the combined uranium series–electron spin resonance method: the Venta Micena palaeontological site (Orce,Spain)

The palaeontological site of Venta Micena (Orce, Andalusia, Spain) lies in the eastern sector of the Guadix–Baza basin, one of the best documented areas in Europe for Plio‐Pleistocene biostratigraphy. The combination of biochronological and palaeomagnetic results, combined with the radiometric data obtained for Atapuerca Sima del Elefante, indicated that the Venta Micena stratum was formed between the Jaramillo and Olduvai palaeomagnetic events, most likely between 1.22 and 1.77 Ma. Five fossil teeth from two outcrops (sites A and B) were selected to assess the potential of combined uranium series–electron spin resonance (US‐ESR) dating of Early Pleistocene sites. Although the US‐ESR results of the first outcrop showed a large scatter between the three teeth, the mean age of 1.37 ± 0.24 Ma can be considered a reasonable age estimate for Venta Micena. The mean ESR age of 0.62 ± 0.03 Ma obtained for site B seems to be a severe underestimation when compared with the independent age control. This underestimation is attributed to a relative recent U‐mobilization event that led to some U‐leaching. The results show that any ESR age calculations of old samples are extremely sensitive to variations in the measured ²³⁰Th/²³⁴U ratios in dental tissues. Although the results demonstrate that ESR can in principle be applied to Early Pleistocene sites, they also reveal the complexity of dating such old teeth. It is necessary to continue research in several directions, such as study of the behaviour of ESR signals in old teeth and understanding recent U‐mobilization processes, to improve the reliability of the combined US‐ESR dating method applied to Early Pleistocene times, a period for which the number of available numerical dating techniques is very limited. Copyright © 2011 John Wiley & Sons, Ltd.     

High-resolution seismic stratigraphy of the late Neogene of the central sector of the Colombian Pacific continental shelf: A seismic expression of an active continental margin

The sedimentary prism of the central Pacific continental shelf of Colombia was affected by regional folding and faulting, and probably later mud diapirism, from the Late Miocene to the Holocene. Interpretation of high-resolution seismic lines (2 s/dt) revealed that the prism consists of 13 high-resolution seismic units, that can be separated into 5 seismic groups.Deposition of the prism and the associated stacking pattern, are probably the response to variable uplift and subsidence in a fore-arc basin that underwent important tectonic events by the end of the Miocene. Throughout the Pliocene, the continental shelf sedimentation was affected by the growing of a dome structure probable due to mud diapirism. This fact caused peripheral faults both normal and reverse that controlled the distribution of some of the seismic units. During the Late Pleistocene (Wisconsin stage?) a eustatic sea level fall caused the shoreline to advance about 50 km westward of its present position. Because of this eustatic sea level change, a strong fluvial dissection took place and is interpreted as the probable extension of the San Juan River to the south of the present day river mouth. Within this framework it is believed that the Malaga and Buenaventura Bays were the passageways of branches of the old drainage system of the San Juan River. The inner branch circulated through the present Buenaventura Bay and runs southward leaving the mark of an apparent valley identified in the seismic information in the eastern sector of the study area. This old fluvial valley and its filling material located in the present day inner continental shelf front of Buenaventura are postulated as important targets to find placer minerals such as gold and platinum.     

Energy balance and evaporation loss of an irrigation reservoir equipped with a suspended cover in a semiarid climate (south‐eastern Spain)

The main objective of this study was to assess the impact of a suspended cover on the evaporation loss of an agricultural water reservoir (AWR). To this aim, a detailed data collection was carried out in a typical AWR located in south‐eastern Spain during 2 consecutive years. During the first year, the reservoir remained uncovered, while during the second year it was covered with a double black polyethylene (PE) shade cloth. On an annual scale, it was observed that the cover can provide a reduction of evaporation loss of 85%. Two approaches, energy balance and mass transfer, were used to analyse the effect of the cover on the evaporation process. Important modifications were observed on the magnitude, sign, annual trend and relative weight of the components of the energy balance. The changes were ascribed to the strong reduction of net radiation and to the substantial weight of the heat storage and sensible heat flux in the energy balance. A relevant finding was the contrast between the patterns of the annual evaporation curve for open‐water and covered conditions. The mass transfer approach allowed discriminating between the wind‐ and radiation‐shelter effects on the evaporation term. The reduction in water‐to‐air vapour deficit was the main factor explaining the high efficiency of the cover, whereas the reduction of the mass transfer coefficient was a modulating factor that accounted for the wind‐shelter effect. Overall, both approaches provided a sound basis to describe and explain the physical mechanisms underlying the high performance of the tested cover. Copyright © 2010 John Wiley & Sons, Ltd.     

Towards a comprehensive approach to parameter estimation in land surface parameterization schemes

In climate models, the land–atmosphere interactions are described numerically by land surface parameterization (LSP) schemes. The continuing improvement in realism in these schemes comes at the expense of the need to specify a large number of parameters that are either directly measured or estimated. Also, an emerging problem is whether the relationships used in LSPs are universal and globally applicable. One plausible approach to evaluate this is to first minimize uncertainty in model parameters by calibration. In this paper, we conduct a comprehensive analysis of some model diagnostics using a slightly modified version of the Simple Biosphere 3 model for a variety of biomes located mainly in the Amazon. First, the degree of influence of each individual parameter in simulating surface fluxes is identified. Next, we estimate parameters using a multi‐operator genetic algorithm applied in a multi‐objective context and evaluate simulations of energy and carbon fluxes against observations. Compared with the default parameter sets, these parameter estimates improve the partitioning of energy fluxes in forest and cropland sites and provide better simulations of daytime increases in assimilation of net carbon during the dry season at forest sites. Finally, a detailed assessment of the parameter estimation problem was performed by accounting for the decomposition of the mean squared error to the total model uncertainty. Analysis of the total prediction uncertainty reveals that the parameter adjustments significantly improve reproduction of the mean and variability of the flux time series at all sites and generally remove seasonality of the errors but do not improve dynamical properties. Our results demonstrate that error decomposition provides a meaningful and intuitive way to understand differences in model performance. To make further advancements in the knowledge of these models, we encourage the LSP community to adopt similar approaches in the future. Copyright © 2012 John Wiley & Sons, Ltd.     

On the Nature of the Variable Gamma-Ray Sources at Low Galactic Latitudes

Population studies of EGRET gamma-ray sources indicate that there is a distinctive population of bright sources at low galactic latitudes. The sources have a distribution consistent with that of young galactic objects, with a concentration toward the inner spiral arms. There is a subgroup that displays strong variability with timescales from days to months. Following an earlier suggestion by Kaufman Bernadó et al. (2002), we explore the possibility that these sources could be high-mass microquasars. Detailed models for the gamma-ray emission that include inverse Compton interactions of electrons in the relativistic jets and photons from all local fields (stellar UV photons, synchrotron photons, soft X-ray photons from the accretion disk, and hard X-ray photons from a corona) are presented. We conclude that microquasars are excellent candidates for the parent population of the subgroup of variable low-latitude EGRET sources.