Spatial trends in heavy metals and nitrogen deposition in Navarra (Northern Spain) based on moss analysis

A biomonitoring survey using the moss species Hypnum cupressiforme Hedw. was performed in the North of Navarra (Spain) in 2006. The levels of V, Cr, Mn, Ni, Cu, Zn, As, Zr, Cd, Hg and Pb, and the total nitrogen content were determined in the samples by means of ICP-MS, CV-AA, and the Kjeldahl method. PCA analysis showed a differentiation between lithogenic (V, Cr, Mn, Ni, As and Zr) and anthropogenic elements (Mn, Cu, Zn, Cd, Hg and Pb). Spatial distribution maps were drawn using the kriging method, in order to identify the most affected areas and the main pollution sources. A similar spatial distribution was observed for the elements belonging to each group separated by the PCA, showing an important contribution from metal industries located in the Basque Country, as well as influence of long-range transboundary pollution processes. Background levels were also determined for the study area, along with the contamination factor for the different elements analysed. Mosses seemed to be good biomonitors of N deposition in areas of accumulation.     

Re‐establishment of soil water repellency after destruction by intense burning in a Mediterranean heathland (SW Spain)

Soil water repellency has been conventionally considered as a fire‐induced effect, but an increasing number of studies have suggested that natural background repellency occurs in many soil types, and many of them have suggested that water repellency can be re‐established over time after being destroyed. An experimental fire was conducted to study changes of the soil surface during the first 18 months following intense burning. The main objectives of this paper are as follows: (1) to investigate in situ water repellency changes at three soil depths (0, 2 and 4 cm) immediately after burning; (2) to evaluate the medium‐term evolution of water repellency under field conditions; and (3) to outline the main hydrological consequences of these changes. Also, different water repellency tests (water drop penetration time, ethanol percentage test (EPT) and contact angle (CA) between water drops and the soil surface) were carried out for comparison purposes. Field experiments showed that soil water repellency was partly destroyed after intense burning. Changes were relatively strong at the soil surface, but diminished progressively with depth. Levels of water repellency were practically re‐established 18 months after burning. This suggests that water repellency in the studied area is not necessarily a consequence of fire, but can instead be a natural attribute. Finally, although limited in time, destruction of soil water repellency has important consequences for runoff flow generation and soil loss rates, and, indirectly, for water quality. Copyright © 2009 John Wiley & Sons, Ltd.     

Crust and Upper Mantle Structure in the Caribbean Region by Group Velocity Tomography and Regionalization

An overview of the crust and upper mantle structure of Central America and the Caribbean region is presented as a result of the processing of more than 200 seismograms recorded by digital broadband stations from SSSN and GSN seismic networks. Group velocity dispersion curves are obtained in the period range from 10s to 40s by FTAN analysis of the fundamental mode of the Rayleigh waves; the error of these measurements varies from 0.06 and 0.09 km/s. From the dispersion curve, seven tomographic maps at different periods and with average spatial resolution of 500 km are obtained. Using the logical combinatorial classification techniques, eight main groups of dispersion curves are determined from the tomographic maps and eleven main regions, each one characterized by one kind of dispersion curves, are identified. The average dispersion curves obtained for each region are extended to 150s by adding data from a larger-scale tomographic study (Vdovin et al., 1999) and inverted using a nonlinear procedure. A set of models of the S-wave velocity vs. depth in the crust and upper mantle is found as a result of the inversion process. In six regions we identify a typically oceanic crust and upper mantle structure, while in the other two the models are consistent with the presence of a continental structure. Two regions, located over the major geological zones of the accretionary crust of the Caribbean region, are characterized by a peculiar crust and upper mantle structure, indicating the presence of lithospheric roots reaching, at least, about 200 km of depth.     

Probabilistic leak detectability assessment via state estimation in water transport networks

Leak detectability or leakage awareness refers to the capability of sensing losses from a water supply system. Several methods exist in the technical literature to tackle this problem, but only few address it with a state estimation approach. The aim of this paper is to present a new methodology that enables probabilistic assessment of the extent to which water loss could be detected using state estimation by only analysing a single hydraulic state, i.e. one time period. Significant leaks are sensed by identifying unusually high normalised state estimation residuals, which can be identified based on the largest normalised residual test. More specifically, the probability of detecting leaks is computed here by working with the multivariate distribution among measurements and estimates to take into account the noisy nature of measurements with an analytical approach rather than with sampling experiments, which are time-consuming. The methodology set out herein also provides a procedure to systematically assess the minimum leak that could be detected in different parts of the network for a specific measurement setting and operating condition. The method has been applied to a water transport network case study to show its potential and to highlight the usefulness of such a tool for practitioners. The limitations of such a methodology are also discussed, including its possible use for on-line leak detection strategies.     

Coherent structure dynamics and sediment particle motion around a cylindrical pier in developing scour holes

Recent investigations on the dynamics of the turbulent horseshoe vortex system (THV) around cylindrical piers have shown that the rich coherent dynamics of the vortical structures is dominated by low-frequency bimodal fluctuations of the velocity field. In spite of these advances, many questions remain regarding the changes of the flow and sediment transport dynamics as scour progresses. In this investigation we carry out laboratory experiments to register the development of the scour hole around a cylindrical pier in a fine-sand bed (d ₅₀ = 0.36 mm). We use the bathymetry measured in the experiment to simulate the flow field employing the detached-eddy simulation approach (DES), which has shown to resolve most of the turbulent stresses around surface-mounted obstacles. From these simulations we compare the dynamics of the THV to the flat-bed case, and analyze the effects on particle transport and sediment flux using the Lagrangian particle model of Escauriaza and Sotiropoulos (2011b) to study the impact of the changes of the flow on the sediment dynamics.     

Robust Regulation of Alkalinity in Highly Uncertain Continuous Anaerobic Digestion Processes

In this paper, a multiple‐input multiple‐output (MIMO) model‐based robust control scheme is proposed for the indirect control of both total alkalinity and the ratio (intermediate alkalinity)/(total alkalinity) by regulating volatile fatty acid concentrations and strong ions concentration, while guaranteeing the so‐called operational stability in anaerobic digestion (AD) processes. The proposed MIMO regulator is an adaptive controller derived from an AD model which incorporates the physicochemical equilibrium of the system as well as the use of a robust interval observer to estimate key process bounds that are used in the computation of the control efforts. Numerical simulations were carried out for a number of operating conditions under the most uncertain scenarios. Results showed that the proposed multivariable control law is able to recover the system stability around a pre‐determined set point in the face of parameter uncertainty and load disturbances.     

Sequence stratigraphy of Holocene incised-valley fills and coastal evolution in the Gulf of Cádiz (southern Spain)

This first sedimentary interpretation of two incised-valley fills in the Gulf of Cádiz (southern Spain), which accumulated during the last fourth-order eustatic cycle in response to fluvial incision, changes of sea level, and correlative deposition, relates the filling of the estuarine basins and their barriers with four regional progradation phases, H₁ to H₄. The cases studied are the wave-dominated Guadalete, and the mixed, tide and wave-dominated Odiel-Tinto estuaries. The sequence boundary is a type-1 surface produced during the lowstand of the Last Glacial period ca. 18 000 ¹⁴C yr BP. No fluvial lowstand deposits were found in the area. Due to rapid transgression the valley fills consist of transgressive and highstand sediments. The maximum landward advance of the estuarine barriers occurred ca. 6500–6000 ¹⁴C yr BP during the maximum of the Flandrian transgression, but there is no evidence of sea level rising appreciably above the present. A large part of the estuaries was filled during H₁ (ca. 6500–4400 ¹⁴C yr BP) but ravinement by shifting tidal inlets destroyed most of the coeval barriers. During the H₂ phase (ca. 4200–2550 ¹⁴C yr BP) sedimentation was favoured by arid conditions and concentrated in the axial estuarine zones and the barriers. Between H₂ and H₃ prevailing winds changed from W to WSW, increasing spit growth to the east and south-east. Progradation of bay-head deltas and flood-plains during H₃ (ca. 2300–800 ¹⁴C yr BP) and H₄ (500 yr ago to the present) further reduced the accommodation space in the largely-filled valleys, and sediment by-passed the estuaries and accumulated in the estuarine barriers as fast-growing spits. Arid conditions and increasing human activity have caused rapid coastal modifications.