Interaction of copper with fatty acids in Soxhlet extraction and its influence

Treatment with metallic copper for the removal of elemental sulfur from bitumen extracted from sedimentary rocks or petroleum is the most widely used method. Little attention has been paid, however, to its disadvantages. It was observed that copper can interact with some polar organic substances during conventional sulfur removal, which can strongly influence the quantitative and qualitative determination of bitumen, as has been confirmed by interaction of long-chain fatty acids with copper. The copper soap generated was analyzed by element analysis, inductively coupled plasma optical emission spectrometry （ICP-OES）, thermal analysis （TG-DSC） and Fourier Transform Infrared spectroscopy （FFIR）. Mechanism of the interaction was investigated and elucidated. Our experimental results would necessitate improvement of the present method for sulfur removal and/or a search for a new one.     

钻孔灌注桩施工对邻近运营隧道变形影响研究

桩基施工将引起周边地层位移和邻近隧道结构变形,以南京龙津桥改建项目桩基工程为背景,通过现场实测,分析研究钻孔灌注桩施工全过程各工况条件对地层位移场和邻近既有隧道结构变形的影响规律。结果表明:由于钢套管的护壁作用,钻孔灌注桩施工过程中产生的最大地层位移和隧道结构变形较小,说明采用“钢套管边旋压边取土”、“群桩间跳施工”等工艺,对周围土体扰动影响程度较小,建议近隧桩基工程采用全套管灌注桩的施工方法,监测分析结果可为类似工程提供技术参考。     

北京云蒙山地区花岗岩穹隆及伸展构造的探讨

北京云蒙山花岗岩为一中生代侵入的花岗岩穹隆,花岗岩穹隆的叶理普遍发育,叶理轨迹基本平行于穹隆的外部边界,并显示出从核部到边部逐渐增强,东南侧明显强于西北侧的特点。变形构造研究显示,花岗岩穹隆的边部及围岩中普遍存在不同层次及不同运动方向的伸展构造。东南侧以具河防口－水峪伸展型韧性剪切带为特征,剪切运动标志显示为从ＮＷ－ＳＥ的正剪切运动,有限应变分析估算其剪切位移量在１０ｋｍ以上,剪切带上部被河防口正     

Physical and chemical properties of the waters of saline lakes and their importance for deep-water renewal: Lake Issyk-Kul, Kyrgyzstan

The relationships between electrical conductivity, temperature, salinity, and density are studied for brackish Lake Issyk-Kul. These studies are based on a newly determined major ion composition, which for the open lake shows a mean absolute salinity of 6.06 g kg⁻¹. The conductivity-temperature relationship of the lake water was determined experimentally showing that the lake water is about 1.25 times less conductive than seawater diluted to the same absolute salinity as that of the lake water. Based on these results, an algorithm is presented to calculate salinity from in-situ conductivity measurements. Applied to the field data, this shows small but important vertical salinity variations in the lake with a salinity maximum at 200 m and a freshening of the surface water with increasing proximity to the shores. The algorithm we adopt to calculate density agrees well with earlier measurements and shows that at 20°C and 1 atm Lake Issyk-Kul water is about 530 g m⁻³ denser than seawater at the same salinity. The temperature of maximum density at 1 atm is about 0.15°C lower than that for seawater diluted to the same salinity. Despite its small variations, salinity plays an important role, together with temperature changes, in the static stability and in the production of deep-water in this lake. Changes in salinity may have had important consequences on the mixing regime and the fate of inflowing river water over geological time. Uncharged silicic acid is negligible for the stability of the water column except near an ∼15 m thick nepheloid layer observed at the bottom of the deep basin.     

Chemical equilibria of thermal waters for the application of geothermometers from the Guanzhong basin, China

In this study, representative samples from thermal wells and springs were chemically analyzed and geothermometers were used to calculate the deep temperatures of geothermal reservoirs on the basis of water–mineral equilibrium. In some cases, however, the chemical components are not in equilibrium with the minerals in the reservoir. Therefore, log(Q/K) diagrams are used to study the chemical equilibrium for the minerals that are likely to participate. The Na–K–Mg triangular diagram is also applied to evaluate the equilibrium of water with reservoir rocks. Standard curves at the reference temperatures are prepared to reveal which type of silica geothermometer is appropriate for the specified condition. This study shows that water samples from geothermal wells W9 and W12 are in equilibrium with the selective minerals, and chalcedony may control the fluid–silica equilibrium. It is estimated that there is an exploitable low-temperature reservoir with possible temperatures of 80–90°C in the Guanzhong basin.     

坝上高原安固里淖粒度年纹层与环境变化

在安固里淖湖心区获取一未扰动沉积物样柱，分析发现了由冬季风搬运物与湖心沉积共同形成的粒度年纹层，建立了纹层年表，恢复了安固里淖湖区8507aB.P，以来的环境变化过程。8507-5429aB.P。冬季风活动较弱，后期的所波动；5429-3244aB.P.冬季风活动较强，3244-2494aB.P。冬季风活动减弱；2494-1165aB.P。冬季风活动略有增强；1165aB.P以来，冬季风活动减弱。安固里小淖粒度年纹层反映的冬季风变化情况与我国北方地区同期的环境变化和海平面变化有很好的对应关系。     

A general model for estimating actual evaporation from non-saturated surfaces

Based on energy balance equation and mass transfer equation, a general model to estimate actual evaporation from non-saturated surfaces was derived. Making use of two concepts, “relative evaporation” and “relative drying power”, a relationship was established to account for the departure from saturated conditions. Using this model, the actual evaporation (evapotranspiration) can be calculated without the need of potential evaporation estimation. Furthermore, the model requires only a few meteorological parameters that are readily and routinely obtainable at standard weather stations. Based on nearly 30 years data of 432 meteorological stations and 512 hydrological stations in China, in combined with GIS, nine typical river basins were selected. Using the data of the selected river basins, the model was tested. The results show that the actual evaporation rate can be estimated with an error of less than 10% in most areas of China, except few years in the Yellow River Basin.     

基于农用地价格体系的征用地价应用研究

农用地价格体系和估价成果应用是当前农用地定级估价工作的难点和争论焦点，该文提出了农用地价格体系应以资源基准地价为基础，通过一系列修正，得出分级分区的征用基准地价、不转变用途的农地流转价、转变用途的农地转用价；以佛山市南海区的农用地估价成果为例，就其与现行征地补偿标准进行了比较，并与南海城区、广州市区城镇建设用地基准地价的相互衔接性进行了验算，应用成本逆推法，从城镇基准地价导出建设用地生地地价，在内涵一致的条件下相互比较。结果表明，按此地价体系建立的农用地征用价能够与城镇地价相衔接，可为城乡地价一体化的建立提供实证。