伊拉克哈勒法耶油田Mishrif组滩相储层特征及其成因分析

伊拉克哈勒法耶油田Mishrif组滩相储层发育,是研究区内最主要的产油层位。利用岩心、薄片、测井资料对Mishrif组沉积相进行了研究,结果表明该组发育局限台地、开阔台地、台内洼地和台地边缘4种沉积相,滩相储层主要发育在开阔台地和台地边缘相带。并综合利用铸体薄片、物性实验数据及压汞曲线等资料对滩相储层特征和成因进行了分析。滩相储层岩石类型多样,发育生屑灰岩、生屑泥粒/粒泥灰岩、砂屑灰岩等多种岩石类型,岩石颗粒较粗。孔隙类型多样,主要以铸模孔、粒间孔、溶孔和体腔孔为主,其中以粒间孔和铸模孔发育最为广泛。各类滩相储层孔隙度较高,渗透率差异明显,平均渗透率为(2.35~139.17)×10~(-3)μm~2。整体孔隙结构较好,排驱压力较低,大喉道较为发育。滩相储层发育受沉积环境控制和成岩作用改造程度影响,有利的沉积条件是滩相储层原生孔隙发育的基础,同生期溶蚀作用的改造形成大量次生孔隙,从而提高了储层的储集性能。     

Recharge source and hydrogeochemical evolution of shallow groundwater in a complex alluvial fan system,southwest of North China Plain

Many cities around the world are developed at alluvial fans. With economic and industrial development and increase in population, quality and quantity of groundwater are often damaged by over-exploitation in these areas. In order to realistically assess these groundwater resources and their sustainability, it is vital to understand the recharge sources and hydrogeochemical evolution of groundwater in alluvial fans. In March 2006, groundwater and surface water were sampled for major element analysis and stable isotope (oxygen-18 and deuterium) compositions in Xinxiang, which is located at a complex alluvial fan system composed of a mountainous area, Taihang Mt. alluvial fan and Yellow River alluvial fan. In the Taihang mountainous area, the groundwater was recharged by precipitation and was characterized by Ca–HCO₃ type water with depleted δ¹⁸O and δD (mean value of −8.8‰ δ¹⁸O). Along the flow path from the mountainous area to Taihang Mt. alluvial fan, the groundwater became geochemically complex (Ca–Na–Mg–HCO₃–Cl–SO₄ type), and heavier δ¹⁸O and δD were observed (around −8‰ δ¹⁸O). Before the surface water with mean δ¹⁸O of −8.7‰ recharged to groundwater, it underwent isotopic enrichment in Taihang Mt. alluvial fan. Chemical mixture and ion exchange are expected to be responsible for the chemical evolution of groundwater in Yellow River alluvial fan. Transferred water from the Yellow River is the main source of the groundwater in the Yellow River alluvial fan in the south of the study area, and stable isotopic compositions of the groundwater (mean value of −8.8‰ δ¹⁸O) were similar to those of transferred water (−8.9‰), increasing from the southern boundary of the study area to the distal end of the fan. The groundwater underwent chemical evolution from Ca–HCO₃, Na–HCO₃, to Na–SO₄. A conceptual model, integrating stiff diagrams, is used to describe the spatial variation of recharge sources, chemical evolution, and groundwater flow paths in the complex alluvial fan aquifer system.     

Mineral and fluid inclusions in zircon of UHP metamorphic rocks from the CCSD-main drill hole: A record of metamorphism and fluid activity

The Chinese Continental Scientific Drilling (CCSD) main drill hole (0–3000 m) in Donghai, southern Sulu orogen, consists of eclogite, paragneiss, orthogneiss, schist and garnet peridotite. Detailed investigations of Raman, cathodoluminescence, and microprobe analyses show that zircons from most eclogites, gneisses and schists have oscillatory zoned magmatic cores with low-pressure mineral inclusions of Qtz, Pl, Kf and Ap, and a metamorphic rim with relatively uniform luminescence and eclogite-facies mineral inclusions of Grt, Omp, Phn, Coe and Rt. The chemical compositions of the UHP metamorphic mineral inclusions in zircon are similar to those from the matrix of the host rocks. Similar UHP metamorphic P–T conditions of about 770 °C and 32 kbar were estimated from coexisting minerals in zircon and in the matrix. These observations suggest that all investigated lithologies experienced a joint in situ UHP metamorphism during continental deep subduction. In rare cases, magmatic cores of zircon contain coesite and omphacite inclusions and show patchy and irregular luminescence, implying that the cores have been largely altered possibly by fluid–mineral interaction during UHP metamorphism.

Abundant H₂O–CO₂, H₂O- or CO₂-dominated fluid inclusions with low to medium salinities occur isolated or clustered in the magmatic cores of some zircons, coexisting with low-P mineral inclusions. These fluid inclusions should have been trapped during magmatic crystallization and thus as primary. Only few H₂O- and/or CO₂-dominated fluid inclusions were found to occur together with UHP mineral inclusions in zircons of metamorphic origin, indicating that UHP metamorphism occurred under relatively dry conditions. The diversity in fluid inclusion populations in UHP rocks from different depths suggests a closed fluid system, without large-scale fluid migration during subduction and exhumation.     

库车坳陷侏罗系煤成气动力学模拟研究

应用黄金管—高压釜封闭体系热模拟实验与GC、GC-IRMS分析技术,结合KINETICS专用软件,对库车坳陷侏罗系煤成气进行了动力学模拟研究。库车坳陷侏罗系煤具有高的产气性,在高演化阶段主要产甲烷气;侏罗系煤热解气甲烷碳同位素为-36‰～-25‰,乙烷碳同位素为-28‰～-16‰;甲烷、C2-C5气态烃的生成活化能分别为(47～64k)calm/ol、(55～72k)calm/ol,频率因子各为5.265×1013s-1、5.388×1018s-1。在此基础上,进一步探讨了克拉2气田天然气的成因。研究认为,克拉2气田天然气属阶段捕获的煤成气,主要聚集了5～1Ma时期的天然气,其成熟度Ro分布范围为1.3%～2.5%。     

磷处理粉煤灰可作农业土壤磷源

粉煤灰(简称CCP或ash)具有改良土壤,增加植物产量的功能。此外,由于它特殊的多孔结构,也可用作吸纳并承载植物养分的载体。用NaH2PO4配制成含磷0.10mol/L浓度的溶液,对采自加拿大西安大略省Sarnia地区Lambton电厂的底灰(bottomash)进行振荡浸渍处理。结果表明,振荡浸渍66h后的粉煤灰中磷含量可达784×10-6。以磷处理粉煤灰、未进行磷处理的粉煤灰和石英砂按比例混合,作为基本生长介质进行玉米种植实验,其中实验配方设计为生长介质中含磷量分别为标准含磷浓度(50×10-6)的10%、25%、50%、75%和100%。生长26、34和46d后分别与不含磷的空白配方、施加含氮-磷-钾为0-20-0标准磷肥并控制磷含量为标准浓度(50×10-6)配方进行生物产量对比。生长实验结果表明,以磷处理粉煤灰供磷的生长介质,当含磷量为标准浓度的25%至100%时,其植物生长量就比添加标准浓度磷肥的配方好。种植46d后的生物生长量统计结果显示,含磷分别为标准浓度50%、75%和100%的实验介质中,玉米杆的鲜重较施标准磷肥介质中玉米分别增长39.46%、42.73%和46.13%;玉米杆干重依次增加29.71%、13.39%和28.87%;根鲜重平均增加16.62%;根干重平均增加14.03%。上述实验结果启示,粉煤灰可以很好地吸纳承载磷养分,并持续供给植物吸收生长,如果采用吸纳磷(或其他养分)的粉煤灰改良砂质土壤将有重要意义。     

Geology of Gold Ore Deposits in Western Linyi of Shandong Province,China

1IntroductionWestern Linyi of Shandong Province is one of the most important gold ore mineralization concen-tration areas. Tongjing skarn type gold copper de-posit, Jinchang skarn type gold copper deposit and Duijinshan porphyry type gold deposit were found in 1960's (Edited committee, 1996). Following the discovery of Guilaizhuang gold ore deposit related to alkaline rocks in 1988, the western Linyi region becomes one of the extensively studied areas of gold deposits in China (Lin etal.,…     

Tectonics,magmatism, and mineralization of Circum–Balkash–Junggar area in the Central Asian Orogenic Belt

ABSTRACT

The Circum–Balkhash–Junggar area, including mostly Kazakhstan, NW China, Russia, Kyrgyzstan, Tajikistan, Uzbekistan, and Mongolia, occupies an important tectonic position of the Central Asian Orogenic Belt (CAOB) (Figure 1). Tectonically, this vast area records the complicated geodynamic processes, among which the most prominent stages are the formation of the U-shaped Kazakhstan Orocline and its interactions with adjacent Altai (Altay), Junggar (West Junggar, Junggar Basin, and East Junggar), and Tianshan orogenic collages in the Palaeozoic, bearing large-scale mineral deposits. The formation of the Late Palaeozoic mineral deposits is related to the tectonic evolution of the Devonian and Carboniferous–Permian volcano-magmatic arcs in the region. However, the link between the metallogeny and the evolution of the volcano-magmatic arcs is not well understood and existing geodynamic models have not explained satisfactorily the mechanism of the huge metallogenic belt. Therefore, this special issue focuses on the formation of the Late Palaeozoic porphyry Cu deposits and their link to the tectonic evolution of the Devonian and Carboniferous–Permian volcano-magmatic arcs with emphasis on comparative studies across the international borders.     

Mineralization Ages of the Jiapigou Gold Deposits,Jilin

The Jiapigou gold deposits are typical vein type deposits associated withArchaean greenstone belts in China. According to the crosscutting relationships between dykesand auriferous veins, single hydrothermal zircon U-Pb dating and quartz K-Ar,~(40)Ar-~(39)Ar andRb-Sr datings, the main mineralization stage of the Jiapigou deposit has been determined to be2469-2475 Ma, while mineralization superimposition on the gold deposit occurred in1800-2000 Ma and 130-272 Ma. They form a mineralization framework of one oldermetallogenic epoch (Late Archaean-Early Proterozoic) and one younger metallogenic epoch(Mesozoic) of gold deposits in Archaean greenstone belts in China.     

高温热田井筒热力学及地层参数计算方法

在高温热田的井孔施工及测试实践中,通常由于高温热水在地层或井简内闪蒸汽化,形成复杂的两相流动而无法直接从单井放喷资料中计算地层参数。西藏羊八井属于高温热水型地热田,第四系热储内热液温度约介于140—155℃之间,埋藏深度大略为70—200米左右,井口闭井压力大多在2—4个大气压之间。热储流体在上述深度、温度和压力的配置下,在地层内处于单相液态,而在开发动态下则在大部分井筒上部达到饱和点而汽化,形成相对稳定的汽化面,构成双相流和单相流之间的界面。     

地球化学块体与大型矿集区的关系——以东天山为例

通过在东天山15万km2的战略性深穿透地球化学调查共圈出大于1000km2以上的地球化学块体18处,其中铜-铅-锌-银地球化学块体5处,铜地球化学块体3处,铜-镍地球化学块体1处,金的地球化学块体4处,铀的地球化学块体3处,铂-钯地球化学块体1处,钨地球化学块体1处。有6处地球化学块体与已知矿集区相对应,新圈定的地球化学块体12处,其中有3处发现了新的矿床。根据这些块体与矿集区的对比得出如下结论:所有的已知矿集区都位于地球化学块体的范围之内,地球化学块体为矿集区的形成提供了丰富的物质基础;有矿集区的存在一定有地球化学块体的存在,但反过来有地球化学块体的存在不一定有矿集区的存在,地球化学块体是客观存在的,而矿集区是已经发现了一系列矿床并勘探到一定程度才能称作矿集区,因此,地球化学块体内可能会存在潜在的矿集区,这为利用地球化学块体预测新的矿集区提供了依据。