Microbially induced calcite precipitation along a circular flow channel under a constant flow condition

Biogrouting is a new ground improvement method that has been studied in recent years. This method involves mainly the use of a microbially induced calcite precipitation process to bind soil particles to increase the strength or to fill in the pores of soil or joints of rock for seepage control. There are two major challenges in the use of biogrout for seepage control through rock joints. The first is how to inject the biogrout solutions, and the second is to understand the mechanisms for the formation of calcite under seepage flow. In this paper, a study on the injection of biogrout solution and the formation of precipitates along a circular 1D flow channel is presented. To minimize the influence of flow, a new one-phase injection method to inject bacterial solution and cementation agents simultaneously was adopted in this study. Factors affecting the formation and distribution of precipitates along the flow channel such as flow velocity, flow rate, and aperture of flow channel were investigated. The experimental results indicated that less calcite was precipitated at locations further away from the injection point due to depletion of the reactants’ concentrations along the flow path. Using the one-phase injection method, the bacterial activity had a major effect on the accumulation of the calcite on the inner surface of the flow channel. The total calcite precipitated on the surface of the flow channel increased slightly with increasing bacterial activity or flow rate. An equation to predict the distance travelled by the biosolution has been derived based on the testing results.

     

云南老王寨金矿的深部地质过程——来自显微岩相学和元素地球化学的证据

通过老王寨金矿围岩、蚀变岩石、矿石的显微岩相学和元素地球化学的系统研究发现：伴随硅化、碳酸盐化等蚀变和硫化物矿化,岩（矿）石中发育沿粒间、裂隙或角闪石解理纹贯入或穿插的黑色不透明超显微隐晶,经电子探针、扫描电镜和能谱分析鉴定,该固体物质主要由超显微晶石英、硅酸盐、碳酸盐、硫化物以及呈熔离交生关系的金红石、白钨矿和镜铁矿（磁铁矿）组成;熔离交生结构与沉淀共晶结构共存的特有岩相学特征指示成矿流体具备由熔体性质向热液性质转化的特性。结合岩（矿）石稀土微量元素研究,认为这种在透射光显微镜下呈黑色不透明的超显微隐晶固体物质,是具熔浆流体特点和超临界流体性质的地幔流体引发交代蚀变的直接微观表现之一;在交代蚀变过程中其性质由熔浆向地壳热液过渡,同时与地壳物质发生混染而有利于成矿作用的进行。     

长江经济带土壤质量评价及产地适宜性初步研究

开展土壤质量评价对科学划定永久基本农田及统筹优化农业生产布局具有重要指导意义。本文采用内梅罗综合污染指数法、分级法、累积频率法和综合判定法,参照《土壤环境质量农用地土壤污染风险管控标准》(试行)(GB 15618—2018)和《绿色食品产地环境质量》(NY/T 391—2013),对长江经济带土壤重金属污染、酸碱度、有益元素丰缺和绿色农产品产地适宜性进行评价。研究区土壤质量总体良好,清洁土壤面积34.84万km²,其重金属含量继承了自然背景特征; 三级及以下土壤面积6.94万km²,呈斑块及星点状分布于赣东北、赣南、湖南长沙—郴州一带、沿江及贵阳、昆明等地,其重金属为自然富集或受矿业开发、煤炭和石油的燃烧及工业“三废”排放的影响。酸性土壤面积33.56万km²,分布于江西、湖南、宁波—台州沿海和金华衢州盆地,碱性土壤面积15.69万km²,分布于苏北平原、环洞庭湖、成都平原以及沿长江一线,其土壤酸碱度与土壤类型有关。土壤有益元素丰缺与第四系沉积物成土母质有关,土壤有益元素适量及以上区域面积34.44万km²,分布于四川阿坝、成都盆地、环洞庭湖、环鄱阳湖、安徽沿江、苏北沿海和杭嘉湖平原; 土壤有益元素缺乏区面积13.89万km²,分布于赣南、江淮、鄂东北以及云南玉溪等地。绿色农产品产地最适宜区、适宜区和不适宜区面积分别为22.49万km²、18.78万km²和18.28万km²。依据区内绿色农产品产地适宜性、土壤环境质量和立地条件划分出7片永久农田保护建议区。     

Broader pattern of tandem repeats in the mitochondrial control region of Perciformes

Perciformes, the largest order of vertebrates with 20 suborders, is the most diverse fish order that dominates vertebrate ocean life. The complete mitochondrial control region (CR) of Trichiurus japonicus (Trichiuridae, Scombroidei) and Pampus sp. (Stromateidae, Stromateoidei) were amplified and sequenced. Together with data from GenBank, the tandem repeats in the mitochondrial CR from 48 species, which covered nine suborders of Perciformes, are reported in this study. The tandem repeats tend to be long in the suborder Percoidei and Stromateoidei. The identical repeats in 21 species of Cichlidae suggest a common origin and have existed before species divergence. Larimichthys crocea shows tandem repeats instead of the typical structure of the central conserved sequence blocks, which was first reported in Perciformes and vertebrates. This might have resulted from interruption of the polymerase activity during the H-strand synthesis. The four broader patterns presented here for the tandem repeats, including those in both the 5′ and 3′ ends, only in the either 5′ or 3′ end, and in the central conserved domain of the control region, will be useful for understanding the evolution of species.     

南京降水氢氧同位素监测特征

基于2018年7月—2019年6月南京降水同位素观测数据和中国气象局气象观测数据,研究南京降水稳定同位素组成的变化特征,对比热带气旋降水、梅雨降水和其他降水的降水同位素组成特征,研究降水同位素组成与热带气旋移动路径关系。结果表明：南京降水氧同位素组成(δ18O)和氢同位素组成(δ2H)的变化范围分别为-16.3‰~4.0‰和-103.0‰~32.9‰,雨季降水氢氧同位素组成相对贫化,非雨季相对富集;降水氘盈余的降水加权平均值为15.5‰,表明南京降水受陆面过程影响大。从降水量权重看,热带气旋降水和梅雨降水强度大,降水氢氧同位素组成严重贫化;其他降水的强度相对较弱,降水氢氧同位素组成比较富集;受水汽源地和陆面循环等过程的综合影响,热带气旋降水氘盈余小于全球平均值(10‰),梅雨降水氘盈余略高于全球平均值,其他降水氘盈余远高于全球平均值。登陆前仅在海洋上移动的热带气旋,降水氘盈余维持在7.5‰~8.6‰,但二次登陆的热带气旋降水氘盈余远大于10‰,可能是受到陆地蒸散过程的影响。     

Ab initio prediction of 29Si-NMR chemical shifts

The ability of several ab initio models to predict experimental ²⁹Si-NMR chemical shift is examined. The shielding values of trimethylsilyl chloride (A), t-butyldimethylsilyl chloride (B) and allytrimethylsilane (C) are calculated by GIAO, CSGT and IGAIM methods, using HF/6–31G^*, B3LYP/6-31G^*, HF/6–311+G^**, B3LYP/6–311+G^** and MPW1PW91/6–311+G^** models respectively. The ²⁹Si chemical shifts calculated by GIAO method using HF/6–311+G^** model are highly in agreement with those obtained experimentally. All of the models above reproduce the trends of chemical shifts in all cases studied, suggesting that the models are of practical value.     

内蒙古敖汉旗七家金矿闪长玢岩锆石U-Pb年代学、地球化学及地质意义

内蒙古敖汉旗七家金矿构造位置上处于兴蒙造山带与华北克拉通北缘的结合部位, 靠近兴蒙造山带一侧, 是近年来新发现的石英脉型金矿床.区内岩脉以闪长玢岩为主, 且与石英脉型矿体空间关系密切.根据岩脉与矿体的穿插关系, 将其分为成矿前闪长玢岩和成矿后闪长玢岩.LA-ICP-MS锆石U-Pb年代学表明, 成矿前闪长玢岩加权平均年龄为166.3±3.4 Ma, 成矿后闪长玢岩加权平均年龄为128.6±4.5 Ma, 与区域上两期构造-岩浆活动时间(分别为160 Ma左右和128 Ma左右)近似吻合.主量元素特征显示: 二者均属于准铝质, 高钾钙碱性系列; 微量元素特征显示: 二者均富集轻稀土元素、大离子亲石元素(Rb、K)和活泼的不相容元素(U、Pb), 相对亏损重稀土元素和高场强元素(Nb、Ta、Ti), 反映出岩浆来源具壳源特征.主微量元素特征均显示出二者具有岛弧岩浆岩的地球化学属性.另外, 成矿后闪长玢岩有较高的Nb/Ta(18.66~20.27)和Zr/Hf(37.16~39.23)比值, 暗示其岩浆来源具明显的幔源特征.岩石地球化学特征表明, 成矿前闪长玢岩可能起源于太平洋板块俯冲导致的下地壳部分熔融岩浆; 成矿后闪长玢岩可能起源于俯冲流体交代的地幔楔熔融岩浆, 并在其演化侵位过程中伴有地壳物质的混染.结合闪长玢岩成岩时代、岩石成因及区域构造演化, 反映出七家金矿的形成与太平洋板块的西向俯冲密切相关, 矿床在地壳由挤压增厚向伸展减薄的转换过程中形成.     

基于高分影像的松嫩低平原地区生态环境问题解析——以黑龙江省肇源县为例

基于高分辨率卫星影像数据,利用遥感、GIS技术获取黑龙江省肇源县内自然资源与生态地质环境各因子分布现状数据,其中：耕地2 541.75 km²、林地161.88 km²、草地349.00 km²、河流128.05 km²、湖泊215.80 km²、沼泽109.17 km²、其他水域84.65 km²、建设用地191.25 km²、未利用地329.94 km²;湿地1 334.54 km²、荒漠化土地775.47 km²。利用地类覆盖率、人均占有量以及景观指数（破碎度指数、平均斑块分形指数、分形维数、多样性指数、均匀度指数）量化分析后,得出两类生态地质环境因子中湿地资源尤其是自然湿地受人类活动干扰程度较大、荒漠化土地受人类活动干扰程度较小的结论。并选取老山村等典型地区进行了多期次遥感动态监测及野外核查,揭示了松嫩低平原典型地区目前存在的湿地退化、土地荒漠化等生态地质环境问题。     

海相火山岩区地质填图方法——以北祁连山东段白银矿田古火山机构厘定为例

20世纪90年代以来,火山机构控矿理论在海相火山岩区块状硫化物矿床研究中得到了越来越多的关注,基于该理论的指导,在北祁连山东段的白银矿田取得了找矿突破性进展。其间,详细的海相火山岩相地质填图工作为白银矿田火山机构与成矿联系的研究及找矿突破奠定了坚实的基础。反映出在海相火山岩区推行合理可行的火山岩相地质填图方法至关重要。以白银矿田海相火山岩区为例,首先,对该区大比例尺火山岩相填图及古火山机构厘定成果进行介绍;其次,通过分析、借鉴此成功案例,总结海相火山岩区填图内容和技术方法;最后,阐述应用该方法在北祁连山中段祁连县一带海相火山岩区进行大比例尺填图的成功尝试。     

黄陵背斜的构造几何形态及其成因探讨

黄陵背斜位于扬子克拉通的东缘,其核部出露的崆岭群被认为是扬子克拉通的基底岩石,并成为华南地质学研究的热点地区。从区域上看,黄陵背斜紧邻江汉盆地,东西两侧分别是荆当盆地与秭归盆地,黄陵背斜和周缘盆地构成明显的隆起—坳陷相互对应的构造。详细的野外观察和构造几何学的剖析表明,黄陵背斜的两翼西陡东缓,构成不对称背形的穹隆构造。在穹隆形成过程中,相应的岩石变形以顺层滑脱及相关的褶皱和小规模的逆冲断层为主,在早三叠世薄层灰岩、志留纪龙马溪组页岩、奥陶纪灰岩、寒武纪炭质灰岩以及震旦纪陡山沱组薄层灰岩广泛发育,并具有垂向缩短的重力滑脱特点,构造叠加关系指示了其形成于晚侏罗—早白垩纪之间。在构造变形分析的基础上,并深入探讨了黄陵背斜成因的3种可能的动力学背景。