Influence of Fluctuating Groundwater Table on Volatile Organic Chemical Emission Flux at a Dissolved Chlorinated-Solvent Plume Site

Groundwater elevation fluctuation has been recognized as one mechanism causing temporal indoor air volatile organic chemical (VOC) impacts in vapor intrusion risk assessment guidance. For dissolved VOC sources, groundwater table fluctuation shortens/lengthens the transport pathway, and delivers dissolved contaminants to soils that are alternating between water saturated and variably saturated conditions, thereby enhancing volatilization potential. To date, this mechanism has not been assessed with field data, but enhanced VOC emission flux has been observed in lab-scale and modeling studies. This work evaluates the impact of groundwater elevation changes on VOC emission flux from a dissolved VOC plume into a house, supplemented with modeling results for cyclic groundwater elevation changes. Indoor air concentrations, air exchange rates, and depth to groundwater (DTW) were collected at the study house during an 86-d constant building underpressurization test. These data were used to calculate changes in trichloroethylene (TCE) emission flux to indoor air, during a period when DTW varied daily and seasonally from about 3.1 to 3.4 m below the building foundation (BF). Overall, TCE flux to indoor air varied by about 50% of the average, without any clear correlation to changes in DTW or its change rate. To complement the field study, TCE surface emission fluxes were simulated using a one-dimensional model (HYDRUS 1D) for conditions similar to the field site. Simulation results showed time-averaged surface TCE fluxes for cyclic water-table elevations were greater than for stationary water-table conditions at an equivalent time-averaged water-table position. The magnitudes of temporal TCE emission flux changes were generally less than 50% of the time-averaged flux, consistent with the field site observations. Simulation results also suggested that TCE emission flux changes due to groundwater fluctuation are likely to be significant at sites with shallow groundwater (e.g., < 0.5 m BF) and permeable soil types (e.g., sand).     

近海地震活动特征及其测震学前兆的某些研究

利用反映震级－频度关系的参量Ｃ值，η值，ｂ值和ｂ值谱以及反映地震空间分布的森下指等研究了近海地震活动的一些主要特征，发现近海强震前地震活动性指标及图象的变化特征与陆地上强震前的特征存在一定差异；给出了新研究的可用于近海及滨海地区强震预报的短期和临震     

基于岩相古地理的黄淮平原原生劣质水发育特征分析

黄淮平原水资源严重短缺,原生劣质水非常发育,水资源供需矛盾十分突出,属于我国典型的资源型缺水和水质型缺水区。文章基于对黄淮平原第四纪各个时期岩相古地理演变的详细刻画,分析了原生劣质水的空间发育特征,旨在研究其与沉积相的相关性。结果表明：原生劣质水基本分布在河间带相、河间洼地相、扇间洼地、浅湖相和沼泽洼地相等古地形闭塞、排水不畅、水平径流滞缓的沉积相中,尤其是溶解性总固体含量（TDS）＞3000 mg/L的咸水、氟化物＞2.0 mg/L的高氟水、铁含量11.98 mg/L的高铁水和锰含量6.43 mg/L的高锰水均分布在上述沉积相范围内,据此充分论证岩相古地理演化对水文地质结构场、水化学场和原生劣质水发育特征的决定性影响。通过分析原生劣质水的成因环境,为进一步详细刻画原生劣质水的平面和垂向发育特征提供依据,并在黄河冲积扇及河道带相、冲积-洪积扇相等主流相内,结合地球物理勘探方法进行洁净地下水勘查,初步形成"岩相古地理分析—主流相圈定靶区—物探确定层位—成井供水"的勘查供水模式,为缺水区安全供水提供新的思路和方法。     

北大巴山逆冲推覆构造带前缘构造特征及变形年代学研究

在北大巴山推覆构造带前缘,北—北东倾斜的城口断裂和南—南西倾斜的高桥断裂形成一背冲式逆冲推覆体系,以两断层为界,其间为一巨型冲起构造。该冲起构造因边界断裂的产状特征、活动强度沿走向的差异,而表现出明显的分段性:其北西段为双向逆冲的"正花状"结构;而南东段为反向逆冲为主的"半花状"结构。同构造低温变质绢云母40Ar-39Ar年龄显示,城口断裂在燕山期(约143.3Ma)存在一次强烈的构造活动,导致北大巴构造带进一步逆冲扩展和强烈隆升。在逆冲-推覆向前扩展过程中,受锋缘外侧阻抗的影响,沿前缘部位形成一系列反向逆冲断层,从而形成巨型冲起构造。     

北极巴罗Elson湖过去450年气候与环境变化记录

北极阿拉斯加巴罗地区Ｅｌｓｏｎ湖长６０ｃｍＡＢ—６７钻孔岩芯提供了过去４５０年连续的高分辨环境变化记录。综合分析２１０Ｐｂ测年、沉积物粒度、有机质、化学元素和微体古生物化石等资料，一致反映出巴罗地区过去４５０年的气候、环境变化过程存在如下３个阶段：１）大约１５４０～１７４０年，为低海面寒冷时期；２）１７４０～１８２７年，为气候转暖－海侵过渡时期；３）１８２７年至今，为继续海侵－气候波动变暖时期。其中１８００年前后和１９４０年前后，气温较高。１９２１～１９９３年巴罗的气温记录说明，北极地区气温不仅有明显的１０ａ和６０ａ周期变化，而且年平均温度变幅极大，达４．５℃。显示极地气候变化特别强烈并不反映大幅度升温。近２０年来的变暖趋势是１８２７年以来自然的气候波动变暖的继续。     

一种胶体光子晶体修饰的光纤

设计了一种胶体光子晶体修饰的光纤. 采用恒温快速蒸发法直接在经切割刀处理后的光纤端面生长胶体晶体,再与另一根切割后的光纤在毛细玻璃管中完成对接,制备成胶体光子晶体修饰的光纤. 用扫描电子显微镜和光谱分析仪对样品的形貌、结构以及光学特性进行分析. 实验结果表明,粒径为640 nm、体积分数约为0.5%的SiO₂胶体微球溶液在60 ℃的情况下沉积,大约12 h后可得到质量较高的胶体光子晶体. 在SEM下,观察到端面的胶体晶体为面心立方(fcc)结构. 透射光谱证明,该结构在(111)面上     

Long-term (1998–2007) trends on the spatial distribution of heterotrophic ciliates in the East China Sea in summer: effect of the Three Gorges Dam construction

The spatial distribution of heterotrophic ciliates, environmental factors and potential food items (bacteria, Synechococcus spp. and nanoflagellates) were measured in the East China Sea to examine which variables contributed importantly to the long-term distribution of ciliates between 1998 and 2007. In July 1998 and June 2003, heterotrophic ciliates were found to be abundant (1,000–2,000 × 10³ cells m⁻³) in regions where surface salinity <32 but extremely low (<500 × 10³ cells m⁻³) in shelf waters of surface salinity >32. After August 2003, shortly after the completion of the Three Gorges Dam, we found no significant areal differences in the abundance of heterotrophic ciliates (HC). However, we found a significantly negative correlation between temperature and HC abundance of surface water after the completion of the dam, suggesting that temperature had a greater influence on HC abundance, once the original saline state had changed. For the long-term trends on the vertical distribution of HC, their abundance was significantly higher in the upper 50 m of the water column than at either 75 or 100 m. Abundance of Synechococcus spp. at these levels varied significantly in regions of surface salinity <32, suggesting that ciliates and picophytoplankton contribute greatly to mediating the transfer of organic matter to higher trophic levels in this marine ecosystem.     

底栖有孔虫(Florilus decors)壳体微量元素/钙比值的LA-ICP-MS原位微区分析方法及应用——以长江口外海域为例

深海沉积物中有孔虫壳体的微量元素、同位素测试技术已较为成熟,而河口近海沉积物中有孔虫壳体元素微区测试却鲜有报道。本文报道了一种利用激光剥蚀电感耦合等离子体质谱（LA-ICP-MS）分析法测试取自长江口外沉积物中的有孔虫壳体元素/钙比值的技术,研究了氦气载气流量、能量密度、束斑大小、激光剥蚀频率等参数对测试结果的影响,优化了活体有孔虫原位分析方法。应用确定的测试条件对2016年7月取自长江口外的底栖有孔虫优美花朵虫样品（Florilus decors）进行测试,发现Mg、Sr等元素/钙比值在壳体不同位置上无显著差异,而Mn的数据较为离散,可能与有孔虫生长过程中经历的水环境及其变化有关。