Vorkommen von Serpelriffen Nördlich des Polarkreises an der Norwegischen Küste

Ohne Zusammenfassung     

Möglichkeiten der quantitativen Röntgenanalyse von Mineralgemischen (abgekürzte Zusammenfassung)

Zusammenfassung Es werden die allgemeinen Bedingungen diskutiert, die erfüllt sein müssen, um aus der Intensität von Röntgenlinien die Mineralzusammensetzung von feinen Pulvern zu bestimmen. Im Hinblick auf die Analyse von Tonen werden die bei den einzelnen Tonmineralgruppen auftretenden besonderen Schwierigkeiten besprochen.     

The behaviour of Li and Mg isotopes during primary phase dissolution and secondary mineral formation in basalt

This study presents lithium (Li) and magnesium (Mg) isotope data from experiments designed to assess the effects of dissolution of primary phases and the formation of secondary minerals during the weathering of basalt. Basalt glass and olivine dissolution experiments were performed in mixed through-flow reactors under controlled equilibrium conditions, at low pH (2-4) in order to keep solutions undersaturated (i.e. far-from equilibrium) and inhibit the formation of secondary minerals. Combined dissolution-precipitation experiments were performed at high pH (10 and 11) increasing the saturation state of the solutions (moving the system closer to equilibrium) and thereby promoting the formation of secondary minerals.At conditions far from equilibrium saturation state modelling and solution stoichiometry suggest that little secondary mineral formation has occurred. This is supported by the similarity of the dissolution rates of basalt glass and olivine obtained here compared to those of previous experiments. The δ⁷Li isotope composition of the experimental solution is indistinguishable from that of the initial basalt glass or olivine indicating that little fractionation has occurred. In contrast, the same experimental solutions have light Mg isotope compositions relative to the primary phases, and the solution becomes progressively lighter with time. In the absence of any evidence for secondary mineral formation the most likely explanation for these light Mg isotope compositions is that there has been preferential loss of light Mg during primary phase dissolution.For the experiments undertaken at close to equilibrium conditions the results of saturation state modelling and changes in solution chemistry suggest that secondary mineral formation has occurred. X-ray diffraction (XRD) measurements of the reacted mineral products from these experiments confirm that the principal secondary phase that has formed is chrysotile. Lithium isotope ratios of the experimental fluid become increasingly heavy with time, consistent with previous experimental work and natural data indicating that ⁶Li is preferentially incorporated into secondary minerals, leaving the solution enriched in ⁷Li. The behaviour of Mg isotopes is different from that anticipated or observed in natural systems. Similar to the far from equilibrium experiments initially light Mg is lost during olivine dissolution, but with time the δ²⁶Mg value of the solution becomes increasingly heavy. This suggests either preferential loss of light, and then heavy Mg from olivine, or that the secondary phase preferentially incorporates light Mg from solution. Assuming that the secondary phase is chrysotile, a Mg-silicate, the sense of Mg fractionation is opposite to that previously associated with silicate soils and implies that the fractionation of Mg isotopes during silicate precipitation may be mineral specific. If secondary silicates do preferentially remove light Mg from solution then this could be a possible mechanism for the relatively heavy δ²⁶Mg value of seawater. This study highlights the utility of experimental studies to quantify the effects of natural weathering reactions on the Li and Mg geochemical cycles.     

Phase shift interference microscope study of dissolution-precipitation processes of nonhydrostatically stressed halite crystals in solution

Halite single crystals in saturated solution were used to study dissolution precipitation creep (DPC) at conditions where plastic deformation is negligible. Specifically, the free unloaded surfaces of these crystals were investigated by a novel Linnik-based phase shift interference microscope. The method allows observations of the crystal surface in-situ and with an axial resolution in the nanometer scale. Transport phenomena in open systems, temperature gradients, and gradients in strain energy density were found to cause morphological changes on the free crystal surface by dissolution/reprecipitation. We did not find evidence for DPC by applying a homogeneous stress field to the crystal as long as plastic deformation was avoided. These findings suggest that deformation of rocks by DPC in situations where dislocation creep is not activated, but is rather promoted by fluid transport through the rock or by episodic changes of extensive parameters affecting solubility than by homogeneous stress alone.Editorial responsibility: J. Hoefs     

The microwave opacity of Saturn's rings at wavelengths of 3.6 and 13 cm from Voyager 1 radio occultation

Radio occultation observations of Saturn's rings with Voyager 1 provided independent measurements of complex (amplitude and phase) microwave extinction and near-forward scattering cross section of the rings at wavelengths (λ) of 3.6 and 13 cm. The ring opening was 5.9°. The normal microwave opacities, τ[3.6] and τ[13], provide a measure of the total cross-sectional area of particles larger than about 1 and 4 cm radius, respectively. Ring C exhibits gently undulating (～ 1000 km) structure of normal opacity τ[3.6] ? 0.25 except for several narrow imbedded ringlets of less than about 100 km width and τ[3.6] ～ 0.5 to 1.0. The normalized differential opacity Δτ/τ[3.6], where Δτ = τ[3.6] ? τ[13], is about 0.3 over most of ring C, indicating a substantial fraction of centimeter-size particles. Some narrow imbedded ringlets show marked increases in Δτ/τ[3.6] near their edges, implying an enhancement in the relative population of centimeter-size and smaller particles at those locations. In the Cassini division, several sharply defined gaps separate regions of opacity τ ～ 0.08 and τ ～ 0.25; the opacity in the Cassini Division appears to be nearly independent of λ. The boundary features at the outer edges of ring C and the Cassini Division are remarkably similar in width and opacity profile, suggesting a similar dynamical control. Ring A appears to be nearly homogeneous over much of its width with 0.6 < τ[3.6] < 0.8 but with considerable thickening, to τ[3.6] ～ 1.0, near its inner boundary with the Cassini division. Normalized differential opacity decreases from ～0.3 at the inner and outer edges of ring A to Δτ/τ[3.6] ～ 0 at a point about one-third of the distance from the inner edge to the outer. The inner one-fourth of ring B has τ[3.6] ～ 1.0, except very near the boundary with ring C, where it is greater. The outer three-fourths of ring B has $\text{τ[3.6] ? 1.2}$. The differential opacity for the inner one-fourth of ring B is Δτ/τ[3.6] ～ 0.15. There are no gaps in ring B exceeding about 2 km in width. Ring F was observed at 3.6 cm as a single ringlet of radial width $\text{? 2}\text{km}$, but was not detected in 13 cm data.     

High diffraction efficiency, broadband, diffraction crystals for use in crystal diffraction lenses

A major goal of the MAX program is to detect and measure gamma rays produced following the nuclear reactions that take place in a supernova explosion. To detect a reasonable number of supernovae, sensitivities of the order of a few times 10-7 γ cm-2sec-1 are needed – much better than possible with current instruments. The approach in the MAX program is to use a crystal diffraction lens to collect photons over a large area and concentrate them on a small well-shielded detector, greatly improving the signal to noise ratio. The crystals need to have both high diffraction efficiency and a relatively broad energy bandwidth. With mosaic crystals there is a trade-off between bandwidth and diffraction efficiency – one can have either high efficiency or large bandwidth, but not both without losing too much intensity through atomic absorption. A recent breakthrough in our understanding of crystal diffraction for high-energy gamma rays has made it possible to develop crystals that have both high diffraction efficiency and a relatively broad energy bandwidth. These crystals have near perfect crystal structure, but the crystalline planes are slightly curved. Such curved planes can be obtained in 3 different ways, by using mixed crystals with a composition gradient, by applying a thermal gradient, and by mechanically bending a near perfect crystal. A series of experiments have been performed on all three types of crystals using high-energy x-ray beams from the Advanced Photon Source at the Argonne National Laboratory. Experiments performed at 3 energies, 93 keV, 123 keV and 153 keV, with both the thermal gradient Si crystals and with the mechanically bent Si crystals, demonstrated that one can achieve diffraction efficiencies approaching 100% with moderate energy bandwidths (ΔE/E = 1.4%) and low atomic absorption (transmission = 0.65), in excellent agreement with theory. The use of this type of diffraction crystal is expected to increase the sensitivity of gamma ray telescopes by a factor of 5 over that possible with normal mosaic crystals.     

Laboratory measurements of the microwave opacity of sulfur dioxide and other cloud-related gases under simulated conditions for the middle atmosphere of Venus

Recent papers attributing the observed microwave opacity of the middle atmosphere of Venus to gaseous sulfur dioxide (SO₂) and other cloud-related gases have motivated laboratory measurements of their microwave absorbing properties under simulated conditions for this region. In the pressure range from 1 to 5 atmospheres and in the temperature range from 297 to 355°K, the absorption of SO₂ in a carbon dioxide (CO₂) atmosphere, at 2.257 and 8.342 GHz, has been found to be approximately 50% larger than that calculated from Van Vleck-Weisskopf theory. The measured absorption is about $\text{25 × 10}{}^6\text{q?}{}^2\text{p}{}^{1.20}\text{T}{}^{\mathrm{?3.1}}\text{(}\text{dB km}{}^{\mathrm{?1}}\text{)}$, where q is the sulfur dioxide number mixing ratio, ? is frequency in gigahertz, p is pressure in atmospheres, and T is temperature in degrees Kelvin. This represents the best-fit expression to the observed pressure dependence, while theoretical values of frequency and temperature dependence are accepted as being consistent with the measurements. Another cloud-related gas, sulfur trioxide (SO₃), was also tested in a CO₂ atmosphere and found to be relatively transparent. These results reduce the amount of SO₂ in the Venus middle atmosphere required to explain the opacity measured by radio occulatation, but this amount still exceeds the abundance measured in situ by atmospheric probes, suggesting that there must be another important source of opacity. Preliminary measurements of the 13-cm absorptivity of gaseous sulfuric acid (H₂SO₄) show it to be a strong microwave absorber, and thus likely to be responsible for a significant and possibly major part of the observed opacity.     

The concept of a equilibrium surface applied to particle sources and contaminant distributions in estuarine sediments

Studies have shown that many chemically-reactive contaminants become associated with fine particles in coastal waters and that the rate, patterns, and extent of contaminant accumulation within estuarine systems are extremely variable. In this paper, we briefly review our findings concerning the accumulation patterns of contaminants in several estuarine systems along the eastern coastline of the United States, and have applied a well-established concept in geology, that is “an equilibrium profile,” to explain the observed large variations in these patterns. We show that fine-particle deposition is the most important factor affecting contaminant accumulation in estuarine areas, and that accumulation patterns are governed by physical processes acting to establish or maintain a sediment surface in dynamic equilibrium with respect to sea level, river discharge, tidal currents, and wave activity. Net long-term particle and particle-associated contaminant accumulations are negliglible in areas where the sediment surface has attained “dynamic equilibrium” with the hydraulic regime. Contaminant, accumulation in these areas primarily occurs by the exchange of contaminant-poor sedimentary particles with contaminant-rich suspended particles during physical or biological mixing of the surface sediment. Virtually the entire estuarine particulate and contaminant load bypasses these “equilibrium” areas to accumulate at extremely rapid in relatively small areas that are temporally out of equilibriums as a result of natural processes or human activities. These relatively small areas serve as major sinks for particles from riverine and marine sources, and for biogenic carbon formed in situ within estuaries or on the inner shelf.