Concurrent tectonic and climatic changes recorded in upper Tortonian sediments from the Eastern Mediterranean

The upper Tortonian Metochia marls on the island of Gavdos provide an ideal geological archive to trace variations in Aegean sediment supply as well as changes in the North African monsoon system. A fuzzy-cluster analysis on the multiproxy geochemical and rock magnetic dataset of the astronomically tuned sedimentary succession shows a dramatic shift in the dominance of 'Aegean tectonic' clusters to 'North African climate' clusters. The tectonic signature, traced by the starvation of the Cretan sediment, now enables to date the late Tortonian basin foundering on Crete, related to the tectonic break-up of the Aegean landmass, at c.  8.2 Ma. The synchronous decrease in the North African climate proxies is interpreted to indicate a change in the depositional conditions of the sink rather than a climatic change in the African source. This illustrates that interpretations of climate proxies require a multiproxy approach which also assesses possible contributions of regional tectonism.     

Non-chondritic Sm/Nd ratio in the terrestrial planets: Consequences for the geochemical evolution of the mantle-crust system

Super-chondritic ¹⁴²Nd signatures are ubiquitous in terrestrial, Martian and lunar samples, and indicate that the terrestrial planets may have accreted from material with Sm/Nd ratio higher than chondritic. This contradicts the long-held view that chondrites represent a reference composition for the ¹⁴⁷Sm-¹⁴³Nd system. Using coupled ¹⁴⁶Sm-¹⁴²Nd and ¹⁴⁷Sm-¹⁴³Nd systematics in planetary samples, we have proposed a new set of values for the ¹⁴⁷Sm/¹⁴⁴Nd and ¹⁴³Nd/¹⁴⁴Nd ratios of the bulk silicate Earth (Caro et al., 2008). Here, we revise the Bulk Silicate Earth estimates for the ⁸⁷Rb-⁸⁷Sr and ¹⁷⁶Lu-¹⁷⁶Hf systems using coupled Sr-Nd-Hf systematics in terrestrial rocks. These estimates are consistent with Hf-Nd systematics in lunar samples. The implications of a slightly non-chondritic silicate Earth with respect to the geochemical evolution of the mantle-crust system are then examined. We show that the Archean mantle has evolved with a composition indistinguishable from that of the primitive mantle until about 2 Gyr. Positive ε¹⁴³Nd and ε¹⁷⁶Hf values ubiquitous in the Archean mantle are thus accounted for by the non-chondritic Sm/Nd and Lu/Hf composition of the primitive mantle rather than by massive early crustal formation, which solves the paradox that early Archean domains only have a limited extension in the present-day continents. The Sm-Nd and Lu-Hf evolution of the depleted mantle for the past 3.5 Gyr can be entirely explained by continuous extraction of the continents from a well-mixed mantle. Thus, in contrast to the chondritic Earth model, Sm-Nd mass balance relationships can be satisfied without the need to call upon hidden reservoirs or layered mantle convection. This new Sm-Nd mass balance yields a scenario of mantle evolution consistent with trace element and noble gas systematics. The high ³He/⁴He mantle component is associated with ¹⁴³Nd/¹⁴⁴Nd compositions indistinguishable from the bulk silicate Earth, suggesting that the less degassed mantle sources did not experience significant fractionation for moderately incompatible elements.     

Global land water storage change from GRACE over 2002–2009; Inference on sea level

Global change in land water storage and its effect on sea level is estimated over a 7-year time span (August 2002 to July 2009) using space gravimetry data from GRACE. The 33 World largest river basins are considered. We focus on the year-to-year variability and construct a total land water storage time series that we further express in equivalent sea level time series. The short-term trend in total water storage adjusted over this 7-year time span is positive and amounts to 80.6 ± 15.7 km³/yr (net water storage excess). Most of the positive contribution arises from the Amazon and Siberian basins (Lena and Yenisei), followed by the Zambezi, Orinoco and Ob basins. The largest negative contributions (water deficit) come from the Mississippi, Ganges, Brahmaputra, Aral, Euphrates, Indus and Parana. Expressed in terms of equivalent sea level, total water volume change over 2002–2009 leads to a small negative contribution to sea level of –0.22 ± 0.05 mm/yr. The time series for each basin clearly show that year-to-year variability dominates so that the value estimated in this study cannot be considered as representative of a long-term trend. We also compare the interannual variability of total land water storage (removing the mean trend over the studied time span) with interannual variability in sea level (corrected for thermal expansion). A correlation of ∼0.6 is found. Phasing, in particular, is correct. Thus, at least part of the interannual variability of the global mean sea level can be attributed to land water storage fluctuations.     

Reactivity at (nano)particle-water interfaces,redox processes,and arsenic transport in the environment

Massive deleterious impacts to human health are resulting from the use of arsenic-bearing groundwaters in South-East Asia deltas and elsewhere in the world for drinking, cooking and/or irrigation. In Bangladesh alone, a fifth of all deaths are linked to arsenicosis. In the natural and engineered subsurface environment, the fate of arsenic is, to a large extent, controlled by redox potential, pH, as well as total iron, sulfur and carbonate content, via sorption and coprecipitation on a variety of natural and engineered (nano)particles. In the present article, we address: (1) new insights in the sorption mechanisms of As on Fe(II) and Fe(III) nanophases recognized to play an important role in the microbial cycling of As and Fe; (2) artifacts often encountered in field and laboratory studies of As speciation due to the extreme redox sensitivity of the Fe-As-O-H phases; and (3) as a conclusion, the implications for water treatment. Indeed the specific reactivity of nanoparticles accounts not only for the As bioavailability within soils and aquifers, but also opens new avenues in water treatment.     

Pollen analyses off Senegal: Evolution of the coastal palaeoenvironment during the last deglaciation

Pollen and dinoflagellate cysts from marine sediments in core A180-48 (15°19′N, 18°06′W; 2450 m water depth; 530 cm length) are used to reconstruct palaeoenvironmental conditions of nearshore tropical west Africa during the last deglaciation. High concentrations and influxes of pollen and dinoflagellate cysts between 11 000 and 10 000 yr BP are interpreted as reflecting an increase in continental trade-wind circulation and related coastal upwelling at 15°N latitude. The sea-surface temperature difference between glacial and interglacial times was not as strong as previously suggested. Together with local (fresh) ground-water input, this smaller temperature difference may explain the persistence of the Rhizophora mangrove and Guinean gallery forests near the shore until their massive extension during the early Holocene humid maximum around 9500 yr BP. Pollen data from the core are compared with data from Rosilda N110-Z, from the continental shelf at the same latitude.     

GRACE-derived surface water mass anomalies by energy integral approach: application to continental hydrology

We propose an unconstrained approach to recover regional time-variations of surface mass anomalies using Level-1 Gravity Recovery and Climate Experiment (GRACE) orbit observations, for reaching spatial resolutions of a few hundreds of kilometers. Potential differences between the twin GRACE vehicles are determined along short satellite tracks using the energy integral method (i.e., integration of orbit parameters vs. time) in a quasi-inertial terrestrial reference frame. Potential differences residuals corresponding mainly to changes in continental hydrology are then obtained after removing the gravitational effects of the known geophysical phenomena that are mainly the static part of the Earth’s gravity field and time-varying contributions to gravity (Sun, Moon, planets, atmosphere, ocean, tides, variations of Earth’s rotation axis) through ad hoc models. Regional surface mass anomalies are restored from potential difference anomalies of 10 to 30-day orbits onto 1^◦ continental grids by regularization techniques based on singular value decomposition. Error budget analysis has been made by considering the important effects of spectrum truncation, the time length of observation (or spatial coverage of the data to invert) and for different levels of noise.     

Analysis of the tropical climate variability in a two-column framework

This work examines the relevance of a classical two-column modeling framework of the tropical climate in terms of observed natural variability. A method is developed to analyze the observed tropical climate in a simple framework that features a moist, ascending column and a dry, subsiding one. This method is used to analyze the natural variability of the tropical climate in the ERA40 reanalysis and in ISCCP satellite data. It appears that the seasonal cycle of the tropic-wide sea surface temperature (SST) is almost linearly linked to the seasonal cycle of the relative area of the moist regions, as predicted by the sensitivity of the two-column models. A more detailed analysis shows that this link is the product of a complex interaction and adjustments between the moist and dry regions. The seasonal cycle of low-cloud cover in the dry regions also appears to interact with the SST seasonal cycle: the low-cloud cover influences the tropic-wide SST via its direct radiative forcing on the local SST and it appears to be controlled by the SST difference between moist and dry regions. By contrast, the SST interannual variability appears to be driven by the El Ni?o Southern Oscillation (ENSO), with no significant impact from the changes in the relative area of the moist regions or in the low-cloud cover in the dry regions independently of the ENSO. ENSO-related changes in the area of moist regions and low-cloud cover constitute negative feedbacks on the ENSO-related SST variability.     

Performance of intertidal topography video monitoring of a meso-tidal reflective beach in South Portugal

This study discusses site-specific system optimization efforts related to the capability of a coastal video station to monitor intertidal topography. The system consists of two video cameras connected to a PC, and is operating at the meso-tidal, reflective Faro Beach (Algarve coast, S. Portugal). Measurements from the period February 4, 2009 to May 30, 2010 are discussed in this study. Shoreline detection was based on the processing of variance images, considering pixel intensity thresholds for feature extraction, provided by a specially trained artificial neural network (ANN). The obtained shoreline data return rate was 83%, with an average horizontal cross-shore root mean square error (RMSE) of 1.06 m. Several empirical parameterizations and ANN models were tested to estimate the elevations of shoreline contours, using wave and tidal data. Using a manually validated shoreline set, the lowest RMSE (0.18 m) for the vertical elevation was obtained using an ANN while empirical parameterizations based on the tidal elevation and wave run-up height resulted in an RMSE of 0.26 m. These errors were reduced to 0.22 m after applying 3-D data filtering and interpolation of the topographic information generated for each tidal cycle. Average beach-face slope tan(β) RMSE were around 0.02. Tests for a 5-month period of fully automated operation applying the ANN model resulted in an optimal, average, vertical elevation RMSE of 0.22 m, obtained using a one tidal cycle time window and a time-varying beach-face slope. The findings indicate that the use of an ANN in such systems has considerable potential, especially for sites where long-term field data allow efficient training.