Preferred orientation distribution of shock‐induced planar microstructures in quartz and feldspar

Shocked quartz and feldspar grains commonly exhibit planar microstructures, such as planar fractures, planar deformation features, and possibly microtwins, which are considered to have formed by shock metamorphism. Their orientation and frequency are typically reported to be randomly distributed across a sample. The goal of this study is to investigate whether such microstructures are completely random within a given sample, or whether their orientation might also retain information on the direction of the local shock wave propagation. For this work, we selected samples of shatter cones, which were cut normal to the striated surface and the striation direction, from three impact structures (Keurusselkä, Finland, and Charlevoix and Manicouagan, Canada). These samples show different stages of pre‐impact tectonic deformation. Additionally, we investigated several shocked granite samples, selected at different depths along the drill core recovered during the joint IODP‐ICDP Chicxulub Expedition 364 (Mexico). In this case, thin sections were cut along two orthogonal directions, one parallel and one normal to the drill core axis. All the results refer to optical microscopy and universal‐stage analyses performed on petrographic thin sections. Our results show that such shock‐related microstructures do have a preferred orientation, but also that relating their orientation with the possible shock wave propagation is quite challenging and potentially impossible. This is largely due to the lack of dedicated experiments to provide a key to interpret the observed preferred orientation and to the lack of information on postimpact orientation modifications, especially in the case of the drill core samples.     

Where do fishmeal and fish oil products come from? An analysis of the conversion ratios in the global fishmeal industry

As a result of the stagnation of commercial fishery landings, aquaculture activities are expected to increase over the next decades to match the growing demand for marine protein. Overall, it is expected that the aquaculture sector could reduce some of the fishing pressure applied to wild stocks. However, this development is likely to be limited by the availability of key aquaculture inputs, specifically fishmeal and fish oil products (FMFOP). Aquaculture provided 60 % (fish meal) and 80 % (fish oil) of the world total consumption of these products in 2007. FMFOP are generally derived from small pelagic fish species, but can also be derived from other sources. Identifying the origin of FMFOP is crucial to understanding the effects of this new pressure on marine social-ecological systems. Two factors are of particular importance in the reduction sector transforming wild fish into fishmeal or fish oil: the two “conversion ratios” (i.e. the ratio between the quantity of wild fish harvested and the resulting quantity of FMFOP, and the ratio between the quantity of FMFOP and aquaculture production), and the type of raw material used by the reduction sector. Based on trade and production databases from FAO and the International Fishmeal and Fish oil Organisation (IFFO), this paper proposes an approach to identify the origin of FMFOP. It shows that whereas different countries use different pelagic resources to produce FMFOP, other countries use non-pelagic sources, and some countries use pelagic resources for human consumption.     

Long term changes in Zostera meadows in the Berre lagoon (Provence, Mediterranean Sea)

The Berre lagoon (Provence, France), one of the largest Mediterranean brackish lagoons (155 km²), was occupied, at the turn of the 20th century, by extensive Zostera meadows (Zostera marina and probably Zostera noltii; perhaps over 6000 ha). Subsequently, the lagoon was disturbed by urban and industrial pollution and, from 1966, by the diversion of the Durance River. This resulted in a 10–49-fold and 8–31-fold increase of the freshwater and silt inputs, respectively. By means of digital analysis of aerial photographs for the years 1944, 1992, 1998 and 2004, coupled with ground truth for the last three dates, we mapped the Zostera meadows. The replacement of Z. marina by Z. noltii, the latter species being already dominant in the 1970s, was completed in 1990. In parallel to this substitution, the Zostera beds underwent a dramatic decline. Their depth limit, which was (6–9) m in the early 20th century, withdrew to 3.5, 3, 1 and less than 1 m by 1944, the 1970s, 1992 and 1998, respectively. Since 1998, Zostera must be considered as functionally extinct. The total surface area of Zostera meadows was of the order of 1.5 ha in 2004. In an attempt to alleviate disturbance, the input of freshwater and silt from the Durance River was significantly reduced from the early 1980s and 1990s respectively. Similarly, from the 1970s to the 1990s, urban and domestic pollution was drastically reduced. Despite these steps, Zostera meadows continued to shrink to near extinction. The lagoon has shifted from a system dominated by seagrass beds to a system with bare silt bottoms, which now occupy most of the lagoon. The reasons could be, in addition to continuing nutrient inputs, the resuspension of silt, no longer trapped under the seagrass canopy, during wind episodes, which are frequent in the area, and/or the release of nutrients from the bare silt habitat, which would constitute an indication of a possible hysteresis of the system. However, since 2000, the establishment of the mussel Mytilus galloprovincialis, a drop in turbidity and a slight, inconspicuous progression of Z. noltii could be the harbinger of a reverse shift of the system.     

Mapping ecosystem services at the regional scale: the validity of an upscaling approach

Mapping ecosystem services (ES) over large scales is important for environmental monitoring but is often prohibitively expensive and difficult. We test a hybrid, low-cost method of mapping ES indicators over large scales in Pará State, Brazil. Four ES indicators (vegetation carbon stocks, biodiversity index, soil chemical quality index and rates of water infiltration into soil) were measured in the field and then summarized spatially for regional land-cover classes derived from satellite imagery. The regionally mapped ES values correlated strongly with independent and local measures of ES. For example, regional estimates of the vegetation carbon stocks are strongly correlated with actual measures derived from field samples and validation data (significant anova test – p-value = 4.51^e?9) and differed on average by only 20 Mg/ha from the field data. Our spatially-nested approach provides reliable and accurate maps of ES at both local and regional scales. Local maps account for the specificities of an area while regional maps provide an accurate generalization of an ES’ state. Such up-scaling methods infuse large-scale ES maps with localized data and enable the estimation of uncertainty of at regional scales. Our approach is first step towards the spatial characterization of ES at large and potentially global scales.     

Contribution of long-term hydrothermal experiments for understanding the smectite-to-chlorite conversion in geological environments

The smectite-to-chlorite conversion is investigated through long-duration experiments (up to 9 years) conducted at 300 °C. The starting products were the Wyoming bentonite MX80 (79 % smectite), metallic iron and magnetite in contact with a Na–Ca chloride solution. The predominant minerals in the run products were an iron-rich chlorite (chamosite like) and interstratified clays interpreted to be chlorite/smectite and/or corrensite/smectite, accompanied by euhedral crystals of quartz, albite and zeolite. The formation of pure corrensite was not observed in the long-duration experiments. The conversion of smectite into chlorite over time appears to take place in several steps and through several successive mechanisms: a solid-state transformation, significant dissolution of the smectite and direct precipitation from the solution, which is over-saturated with respect to chlorite, allowing the formation of a chamosite-like mineral. The reaction mechanisms are confirmed by X-ray patterns and data obtained on the experimental solutions (pH, contents of Si, Mg, Na and Ca). Because of the availability of some nutrients in the solution, total dissolution of the starting smectite does not lead to 100 % crystallization of chlorite but to a mixture of two dominant clays: chamosite and interstratified chlorite/smectite and/or corrensite/smectite poor in smectite. The role of Fe/(Fe + Mg) in the experimental medium is highlighted by chemical data obtained on newly formed clay particles alongside previously published data. The newly formed iron-rich chlorite has the same composition as that predicted by the geothermometer for diagenetic to low-grade metamorphic conditions, and the quartz + Fe-chlorite + albite experimental assemblage in the 9-year experiment is close to that fixed by water–rock equilibrium.     

Deterministic modelling of the cumulative impacts of underground structures on urban groundwater flow and the definition of a potential state of urban groundwater flow: example of Lyon,France

Underground structures have been shown to have a great influence on subsoil resources in urban aquifers. A methodology to assess the actual and the potential state of the groundwater flow in an urban area is proposed. The study develops a three-dimensional modeling approach to understand the cumulative impacts of underground infrastructures on urban groundwater flow, using a case in the city of Lyon (France). All known underground structures were integrated in the numerical model. Several simulations were run: the actual state of groundwater flow, the potential state of groundwater flow (without underground structures), an intermediate state (without impervious structures), and a transient simulation of the actual state of groundwater flow. The results show that underground structures fragment groundwater flow systems leading to a modification of the aquifer regime. For the case studied, the flow systems are shown to be stable over time with a transient simulation. Structures with drainage systems are shown to have a major impact on flow systems. The barrier effect of impervious structures was negligible because of the small hydraulic gradient of the area. The study demonstrates that the definition of a potential urban groundwater flow and the depiction of urban flow systems, which involves understanding the impact of underground structures, are important issues with respect to urban underground planning.     

Antimony deposits in the Variscan Armorican belt,a link with mafic intrusives?

The Variscan Armorican belt was the World leading producer of antimony at the beginning of the twentieth century. However, geological controls on the deposits remain unconstrained. Here, we illustrate the field setting of mineralisations and perform a statistical analysis using Geographical Information System software, geophysical and geological data. The analysis shows that Sb deposits are spatially correlated with high‐density and magnetic zones. This may reflect the presence of mafic/ultramafic bodies at depth – a suggestion that is further supported by numerous occurrences of doleritic dykes throughout the region. Future antimony prospecting should focus on the high‐density and high‐magnetic zones which comprise about 18% of the Armorican massif. Links between Sb deposits and mafic intrusions are recognised elsewhere in the West European Variscan belt, emphasising that these may be key for antimony prospecting in deformation belts.