LES of turbulent surface shear stress and pressure-gradient-driven flow on shallow continental shelves

Turbulent shear flows on shallow continental shelves (here shallow means that the interaction with the solid, no-slip bottom is important) are of great importance because tide- and wind-driven flows on the shelf are drivers of the transfer of momentum, heat, and mass (gas) across the air–sea interface. These turbulent flows play an important role because vertical mixing and current are vectors for the transport of sediment and bioactive material on continental shelves. Understanding the dynamics of this class of flows presents complications because of the presence of a free surface and also because the flow can be driven by a pressure gradient (a tidal current), a stress at the free surface (a wind-driven current), or a combination of both. In addition, the flow can be modified by the presence of a wave field that can induce Langmuir circulation (Langmuir, Science 87:119–123, 1938). Large eddy simulation is used to quantify the effects of pressure gradient and wind shear on the distinctive structures of the turbulent flow. From these computations, an understanding of the physics governing the turbulence of pressure-driven and wind-driven flows, how they can interact in a normal or a tangential direction, and the effect of wave forcing on these flows is obtained.     

Late Devonian OIB alkaline gabbro in the Yarlung Zangbo Suture Zone: Remnants of the Paleo-Tethys?

The Yarlung Zangbo Suture Zone (YZSZ) is believed to be composed of material largely derived from the destruction of the Neo-Tethys that occurred from early Mesozoic to early Cenozoic. We report here geochronological and petrological data obtained for newly discovered alkaline gabbro blocks embedded in a mélange zone of the western YZSZ. Single zircon U–Pb analyses from one representative gabbro sample by SIMS (Secondary Ion Mass Spectrometry) yielded a combined crystallization age of about 363.7 ± 1.7 Ma (1σ). In situ Hf isotopic analyses yielded ε_Hf(t) values of + 2.6 to + 5.5, suggesting an enriched mantle source. All of the gabbro samples show typical Ocean Island Basalt (OIB) affinity with little or no continental crust contamination. They also display strong geochemical similarities with the Hawaii basalts and the Xigaze seamount basalts suggestive of their intra-oceanic setting. These observations, in combination with the Early Carboniferous layered gabbros reported at Luobusa, indicate that these rocks could represent remnants of the Paleo-Tethys. We propose that a branch ocean separating the Western Qiangtang terrane and the Lhasa terrane from the Gondwana continent might have been present during the Late Devonian and the Early Carboniferous, providing new constrains on the configuration of Paleo-Tethys in Tibetan Plateau during early Late Paleozoic.     

Review: The Yucat��n Peninsula karst aquifer, Mexico

The Yucatán Peninsula karst aquifer is one of the most extensive and spectacular karst aquifer systems on the planet. This transboundary aquifer system extends over an area of approximately 165,000? km² in México, Guatemala and Belize. The Triassic to Holocene Yucatán limestone platform is located in the vicinity of the North American/Caribbean plate boundary and has been reshaped by a series of tectonic events over its long geologic history. At the end of the Cretaceous period, the Yucatán Peninsula was hit by a large asteroid, which formed the Chicxulub impact crater. The Yucatán Peninsula karst aquifer hosts large amounts of groundwater resources which maintain highly diverse groundwater-dependent ecosystems. Large parts of the aquifer are affected by seawater intrusion. Anthropogenic pollution of the aquifer has been increasing over the past few decades, owing to relentless economic development and population growth on the Peninsula. This review summarizes the state of knowledge on the Yucatán Peninsula karst aquifer and outlines the main challenges for hydrologic research and practical groundwater-resources management on the Peninsula.     

Comparative phylogeography of African rain forest trees: A review of genetic signatures of vegetation history in the Guineo-Congolian region

The biogeographic history of the African rain forests has been contentious. Phylogeography, the study of the geographic distribution of genetic lineages within species, can highlight the signatures of historical events affecting the demography and distribution of species (i.e. population fragmentation or size changes, range expansion/contraction) and, thereby, the ecosystems they belong to. The accumulation of recent data for African rain forests now enables a first biogeographic synthesis for the region. In this review, we explain which phylogeographic patterns are expected under different scenarios of past demographic change, and we give an overview of the patterns detected in African rain forest trees to discuss whether they support alternative hypotheses regarding the history of the African rain forest cover. The major genetic discontinuities in the region support the role of refugia during climatic oscillations, though not necessarily following the classically proposed scenarios. We identify in particular a genetic split between the North and the South of the Lower Guinean region. Finally we provide some perspectives for future study.     

Effect of particle density and inflow concentration of suspended sediment on bedload transport in rill flow

Laboratory flume experiments were carried out to evaluate the effect of particle density on bedload transport of sand‐sized particles and the effect of a suspended load of clay particles (kaolinite) on bedload transport of sand‐sized particles in rill flow conditions. Three materials in the range 400–600 µm were selected to simulate bedload transport of primary particles and aggregates: sand (2650 kg/m³), crushed brick (2450 kg/m³) and anthracite (1300–1700 kg/m³). In the two first experiments, two different methods were applied to determine bedload transport capacity of coarse particles for various conditions of flow discharge (from 2 to 15 L/min) and slope (2.2, 3 and 4%). In the third experiment, clear water was replaced with kaolinite–water mixture and bedload transport capacity of crushed brick particles was determined for a 4% slope and different concentrations of kaolinite (0, 7, 41 and 84 g/L). The results showed that bedload transport increased significantly with the decrease in particle density but the effect of particle density on transport rates was much less important than flow discharge. Velocity measurements of clear flow, flow mixed with coarse particles and coarse particles confirmed the existence of a differentiation between suspended load and bedload. In these experimental conditions, suspended load of kaolinite did not affect bedload rates of crushed brick particles. Three transport capacity formulae were tested against observed bedload rates. A calibration of the Foster formula revealed that the shear stress exponent should be greater than 1.5. The Low and the Govers unit stream power (USP) equations were then evaluated. The Low equation was preferred for the prediction of bedload rates of primary particles but it was not recommended in the case of aggregates of low density because of the limited experimental conditions applied to derive this equation. Copyright © 2008 John Wiley & Sons, Ltd.     

Deterministic sensitivity analysis for a model for flow in porous media

A deterministic method for sensitivity analysis is developed and applied to a mathematical model for the simulation of flow in porous media. The method is based on the singular value decomposition (SVD) of the Jacobian matrix of the model. It is a local approach to sensitivity analysis providing a hierarchical classification of the directions in both the input space and of those in the output space reflecting the degree of sensitiveness of the latter to the former. Its low computational cost, in comparison with that of statistical approaches, allows the study of the variability of the results of the sensitivity analysis due to the variations of the input parameters of the model, and thus it can provide a quality criterion for the validity of more classical probabilistic global approaches. For the example treated here, however, this variability is weak, and deterministic and statistical methods yield similar sensitivity results.     

The snowball Earth aftermath: Exploring the limits of continental weathering processes

Carbonates capping Neoproterozoic glacial deposits contain peculiar sedimentological features and geochemical anomalies ascribed to extraordinary environmental conditions in the snowball Earth aftermath. It is commonly assumed that post-snowball climate dominated by CO₂ partial pressures several hundred times greater than modern levels, would be characterized by extreme temperatures, a vigorous hydrological cycle, and associated high continental weathering rates. However, the climate in the aftermath of a global glaciation has never been rigorously modelled. Here, we use a hierarchy of numerical models, from an atmospheric general circulation model to a mechanistic model describing continental weathering processes, to explore characteristics of the Earth system during the supergreenhouse climate following a snowball glaciation. These models suggest that the hydrological cycle intensifies only moderately in response to the elevated greenhouse. Indeed, constraints imposed by the surface energy budget sharply limit global mean evaporation once the temperature has warmed sufficiently that the evaporation approaches the total absorbed solar radiation. Even at 400 times the present day pressure of atmospheric CO₂, continental runoff is only 1.2 times the modern runoff. Under these conditions and accounting for the grinding of the continental surface by the ice sheet during the snowball event, the simulated maximum discharge of dissolved elements from continental weathering into the ocean is approximately 10 times greater than the modern flux. Consequently, it takes millions of years for the silicate weathering cycle to reduce post-snowball CO₂ levels to background Neoproterozoic levels. Regarding the origin of the cap dolostones, we show that continental weathering alone does not supply enough cations during the snowball melting phase to account for their observed volume.     

Decoupling of arsenic and iron release from ferrihydrite suspension under reducing conditions: a biogeochemical model

High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis. Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted. Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant, or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction revealed vivianite Fe(II)₃(PO₄)₂.8H₂O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results. The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully applied to recent experimental results on the release of arsenic from Bengal delta sediments.