贵州河流河水的锶同位素与喀斯特地区化学风化作用

贵州省地处世界岩溶发育最复杂、类型最齐全、分布面积最大的东亚岩溶区域中心, 也是我国碳酸盐岩分布面积最大、岩溶最发育的省区, 同时也是我国水土流失严重的地区之一。由于河水的地球化学反映了流域盆地的化学风化、气候和上地壳的化学组成的重要信息, 本工作对贵州喀斯特地区两条主要水系(乌江水系、沅江水系)河流的主要阴、阳离子和Sr2＋离子及锶同位素组成变化进行了系统研究, 对河水地球化学组成变化特征及其控制因素进行了解释。 贵州喀斯特地区两条主要水系河流的水化学组成代表了典型碳酸盐岩地区河流的相应化学组成, 显示了与世界主要河流不同的水化学特征, 反映了喀斯特环境地表化学风化作用的特点。     

Geochemistry of Subvolcanic-Type Copper-Silver Deposits in Eastern China

The metallogenesis of subvolcanic deposits is controlled by subvolcanic activities. The copper polymetallic deposits are genetically related to intermediate-acid rocks, and the silver polymetallic deposits are more closely related to acid rocks. The abundance of Cu is relatively high in the intermediate-acid rocks and subvolcanic rocks, whereas the abundances of Pb, An and Ag are high in acid rocks, indicating rich ore-forming elements in original magmas. The study of REEs shows that the magmatic type related to copper deposits is the syntectic type, and that related to silver polymetallic deposits is mainly the re-melting type. The deposits were formed under medium-low temperatures and low salinity. The metallogenic times were the late stage of the early Yanshanian or the late Yanshanian, dating 78-147 Ma.     

The δ60/58Ni Values of Twenty‐Six Selected Geological Reference Materials

The high‐precision δ^60/58Ni values of twenty‐six geological reference materials, including igneous rocks, sedimentary rocks, stream sediments, soils and plants are reported. The δ^60/58Ni values of all samples were determined by double‐spike MC‐ICP‐MS (Nu Plasma III). Isotope standard solution (NIST SRM 986) and geological reference materials (BHVO‐2, BCR‐2, JP‐1, PCC‐1, etc.) were used to evaluate the measurement bias and intermediate precision over a period of six months. Our results show that the intermediate precision of Ni isotope determination was 0.05‰ (2s, n = 69) for spiked NIST SRM 986 and typically 0.06‰ for actual samples, and the δ^60/58Ni _{NIST SRM 986} values were in excellent agreement with previous studies. Eighteen high‐precision Ni isotope ratios of geological reference materials are first reported here, and their δ^60/58Ni values varied from ?0.27‰ to 0.52‰, with a mean of 0.13 ± 0.34‰ (2s, n = 18). Additionally, SGR‐1b (0.56 ± 0.04‰, 2s), GSS‐1 (?0.27 ± 0.06‰, 2s), GSS‐7 (?0.11 ± 0.01‰, 2s), GSD‐10 (0.46 ± 0.06‰, 2s) and GSB‐12 (0.52 ± 0.06‰, 2s) could potentially serve as candidate reference materials for Ni isotope fractionation and comparison of Ni isotopic compositions among different laboratories.     

郯庐断裂中段新生代右行走滑位移

依据走滑拉分盆地中盆地沉降（或抬升）速率与边界断层走滑速率之间的数值关系,通过对夹在郯庐断裂中段两分支断层间的潍北凹陷沉积埋藏史的恢复,间接求取郯庐断裂中段新生代右行走滑位移。潍北凹陷内不同构造位置4口井的埋藏史恢复结果表明：凹陷新生代经历了古近纪早、中期的快速沉降,古近纪末-新近纪初的抬升剥蚀和中新世以来的缓慢沉降3个阶段;各阶段的平均沉降速率分别为0.142 9、-0.072 8、0.032 5 km/Ma。通过对太平洋板块与欧亚板块间俯冲速率和方向变化的分析推断,中新世中期（39.5 Ma）太平洋板块由北西向俯冲转而变成正西向俯冲所产生的西南向应力分量是导致新生代郯庐断裂开始右行走滑的主要因素,且走滑活动持续至今。根据走滑活动发生和持续的时间,结合各个时期内潍北凹陷的沉降和抬升速率,计算出郯庐断裂中段新生代右行走滑位移量为15 km左右。     

重熔斑岩型锡多金属矿床蚀变分带特征及其与矿化带的关系

重熔斑岩型锡多金属矿床具有明显的蚀变、矿化分带性,由含矿岩体向外(或从深部到地表)蚀变分带依次为:碱性长石化带→黑鳞云母云英岩化带→黄玉云英岩化带→绢英岩化带→硅化带→似青盘岩化带;矿化分带为:钨(锡、钼、铜)→锡(钼、铋、锌)→钼(锡、铅、锌)→铅、锌(银、锡)。前两个矿化带与黄玉云英岩化带关系十分密切,钼矿化带与绢英岩化带和硅化带有关,铅—锌矿化带主要产于硅化带与似青盘岩化带叠加部位。     

Geochemical characteristics and source analysis of inflow of mine water in Wang’ershan Gold Mine, Shandong

Through a systematic observation of water level and temperature, and a comprehensive analysis of the data on major/trace elements, nitrite, hydrogen-oxygen isotopes, the conclusion has been drawn that there are two relatively independent groundwater systems (cool water and hot water), and the geochemical indicators of hot/cool waters are described. The cool water system is relatively enriched in Ca2 , Mg2 and HCO3-. Its TDS is relatively low, about 1400–1800 mg/L. The hot water system is relatively enriched in K , Na , Cl- and SO42-. Its TDS is relatively high, about 2200–2300 mg/L. The cool water system is enriched in Ba, Ga, Cd, and the hot water system is enriched in B, Ti, Cr, Ni, Cu, Mo, Rb, and Cs, relatively. Especially, the contents of Rb and Cs in the hot water system are more than five times as high as those in the cool water system. The NO3- contents of cool water discharged from the gold mine are relatively high, and those of hot water are extremely low. The δD and δ18O values follow an increasing order of surface water>mine cool water>mine hot water. The cool water comes mainly from the lateral supply of phreatic water, while the hot water comes mainly from the vertical supply of deeply circulating structure-fracture water. The ratio of cool water over hot water was estimated to be about 1:1 by a water quality model..     

假玻状岩研究的新进展

综述了假玻状岩研究的主要进展，假玻状岩形成的磨擦熔融机制与机械磨碎机制实际上不是过去所认为的是两种互相排斥的机制，而是在假玻状岩形成过程中两个密切相关的阶段，磨碎作用是熔融发生的必要的前提条件；假玻状岩不仅可以形成于脆性域（与碎裂岩相关），而且可以形成于脆韧性过渡区（与糜棱岩相关），形成的最大深度可达１８ｋｍ；假玻状岩是围岩中矿物选择性熔融的产物，矿物优先熔融的顺序（从易到难）为：层状硅酸盐、链状     

渭河盆地地温场分布规律及其控制因素

本文以渭河盆地地温场为研究对象,在收集补充新地热井资料及分析测试样品的基础上,通过盆地深部结构、构造特征、地温场特征、热储层特征、地热资源量等分析,建立了盆地不同岩性岩石热导率与深度关系图版,确定了盆地地温场变化规律及地热田控制因素,提出了渭河盆地地热田形成模式。评价了盆地地热资源有利区,为盆地后续的开发利用提供了理论支持。研究认为渭河盆地热地温梯度分布在2.34～5.85℃/100m之间,平均地温梯度为3.50℃/100m,代表性大地热流68.33mw/m²,地温梯度及不同深度地层温度具有东高西低、南高北低的特点。热导率总体上具有随深度的增加,逐渐增大的规律,热导率随深度增加主要受压实程度增强控制。相同深度条件下泥岩热导率最低,砂岩热导率居中、白云岩热导率最高。渭河盆地主要为层状地热田,盆地内地热通过热传导及热对流两种方式进行传递,以热传导为主。渭河盆地地热资源丰富,热储层可分为三种类型:①新生界砂岩孔隙型;②下古生界碳酸盐岩岩溶型;③断裂型。渭河盆地地热资源有利区主要分布于西安凹陷、固市凹陷。盆地地温场及地热田分布与莫霍面、软流圈上隆、岩石圈厚度减薄的深部背景...     

准噶尔盆地腹部侏罗系地层超压成因机制——以东道海子北凹陷为例

准噶尔盆地腹部地区侏罗系地层超压普遍发育,超压层段与声波时差、电阻率两者之间具有较好的响应关系,尤以电阻率响应最为显著,超压层段声波时差表现为异常高值,电阻率为异常低值的特征。利用准噶尔盆地腹部地区大量测井、测试及相关地质资料综合论述超压成因,指出泥岩和砂岩中发育的超压并非由压实不均衡、构造挤压等作用导致,而主要由生烃作用造成的。研究表明有以下几方面主要证据：1）超压泥岩密度不具有异常低值特征;2）超压段泥岩密度与岩石颗粒垂直有效应力之间不存在线性关系;3）超压砂岩不存在异常高地温梯度现象;4）超压顶界面深度范围为3 800～4 300 m,侏罗系烃源岩现今成熟度（Ro%）范围为0.6%～0.9%,温度范围分布在90 ℃～125 ℃;5）超压层段的侏罗系烃源岩现今生烃转化率最高可达70%,现今平均生油率可达90 mg/g·TOC,仍具有较强的生烃能力;6）泥质烃源岩本身对超压具有很好的封闭作用;7）侏罗系烃源岩内发育大量低角度或高角度微裂缝;8）超压储层主要以油层为主,无水层,准噶尔盆地东道海子北凹陷砂岩中超压主要是通过烃源岩中排出的高压流体运移至储层发生超压传递的结果。     

误差受控的多细节层次地形模型的实现

基于视点的细节层次模型对于提高三维GIS中地形模型的漫游速度以及减少地形模型的数据量具有重要的作用。为了提高地形模型的漫游速度,开发与视点相关的细节层次模型的数据结构和算法,推导细节层次模型的误差计算公式,建立误差受控的细节层次模型,同时缝合漫游时细节层次模型中的缝隙现象。试验结果表明,误差受控的细节层次地形模型对于减少三维漫游过程中几何数据的装载量和提高漫游速度具有明显的效果。