Evaluation of the mineral exploration influence on sediment composition in the Gualaxo do Norte River Basin (MG-Brazil) based on geochemical and stratigraphic data

The aim of this study was to investigate the influence of mining on the geochemical composition of the alluvial sediments of the Gualaxo do Norte River Basin, located in the eastern-southeastern portion of the Quadrilátero Ferrífero (Minas Gerais State, Brazil). The analysis of the sedimentological succession was carried out using 16 stratigraphic sections (cutbanks and alluvial terraces) and analysis of 111 sediment samples for major- and trace-elements by ICP-OES. The stratigraphic analysis revealed the deposition history of the collected sediments. Anomalous concentrations of certain elements such as As and Pb were found, which are associated with stratigraphic facies with evidences of gold artisanal mining, and Fe anomalies associated with iron ore mining. The classification of the sections was possible by means of principal component analysis. From the sediment characteristics, three groups were identified: (1) those influenced by iron ore mining and gold artisanal mining; (2) those influenced by iron ore mining and (3) those with no influence of human activities.     

The Serra da Graciosa A-type Granites and Syenites, southern Brazil: Part 2: Petrographic and mineralogical evolution of the alkaline and aluminous associations

The Serra da Graciosa Granites and Syenites comprise five distinct plutons in the Brasiliano/Pan-African Graciosa A-type Province, southern Brazil. Six petrographic series can be identified in these plutons: (1) Alkaline series 1, composed of amphibole-bearing alkali feldspar syenites with varied mafic mineralogy and quartz contents, from alkali feldspar syenites with calcic amphibole, clinopyroxene, olivine and allanite to alkali feldspar quartz syenites with sodic–calcic amphibole and chevkinite–perrierite and to alkali feldspar granites with sodic amphibole; (2) Alkaline series 2, characterized by amphibole-bearing alkali feldspar granites, with limited modal variations but amphibole compositions also varying from calcic to sodic; (3) Alkaline series 3, of limited occurrence, which includes alkali feldspar syenites with olivine and clinopyroxene and no amphibole; (4) Aluminous series 1, of widespread occurrence, with various petrographic facies of biotite granites with amphibole; (5) Aluminous series 2, characterized by alkali feldspar granites with biotite and only minor amphibole; (6) Monzodiorites, typically with biotite, calcic amphibole and augitic clinopyroxene, partially mingled with granitic magmas. The mafic minerals present are, in general, Fe-rich with correspondingly low Mg and Al contents. In Alkaline series 1, amphiboles crystallized in progressively more oxidizing and alkaline conditions, while in Alkaline series 2, the initial conditions were somewhat more oxidizing and shifted to reducing in the final stages. In Aluminous series 1 and Aluminous series 2, amphiboles are calcic and comparatively homogeneous. The amphiboles in the monzodioritic rocks, while also homogeneous, are more Mg-rich and show compositions quite distinct from the calcic varieties in the other associations, and this is also the case for clinopyroxene. Mg# in biotite decreases from the monzodioritic rocks to Aluminous series 1 and further to Aluminous series 2. Contrasting evolution of the various associations suggests that several coeval magmatic series are present in the Serra da Graciosa granites.