Rutile chemistry and thermometry as provenance indicator: An example from Chios Island,Greece

In the present study we focused on detrital rutile separated from 12 psammitic samples that belong to three different sedimentary successions (Carboniferous, Permo-Carboniferous, Permo-Triassic) occurring on Chios Island, Greece. The Ti, Cr, Al, Fe, Nb, Zr, Si, and V contents of the rutiles were obtained by electron-microprobe analyses to trace their provenance.The Cr and Nb concentrations of the analysed rutile grains show a wide range and indicate that this mineral in the Carboniferous succession is mainly derived from metamafic rocks, whereas in the Permo-Carboniferous and Permo-Triassic successions stem from a metapelitic source. The calculated formation temperatures using the Zr-in-rutile thermometer range from ca. 520 to 850 °C with “hotter” rutile being encountered in the Permo-Carboniferous and Permo-Triassic successions. This feature together with the rutile chemistry indicate a change in source-rock lithology through time, which could either reflect an increasing depth of erosion of an exhumed ‘Variscan’ nappe pile of heterogeneous composition in the hinterland or a change in the style of accretion and erosion of different terranes at the southern margin of Laurussia during the subduction of a branch of the Palaeotethys Ocean in the Late Palaeozoic. In general, this study underscores the importance of rutile chemistry and thermometry in quantitative single-mineral provenance analysis and in chemostratigraphic analysis of clastic sedimentary rocks.     

Quartz paramorphs after former stishovite in UHP eclogite from the South Altyn Tagh,Western China and its Significance

The long prism/needle‐shaped polycrystalline quartz aggregates and square/parallelogram‐shaped singlephase quartz inclusions in omphacite and garnet of ultrahigh pressure eclogite were first discovered from the Jiangalesayi area, South Altyn UHP belt. Based on their morphology, these quartz inclusions are quartz paramorphs after stishovite. The minimum peak pressure of the eclogite is estimated to be >8–9 GPa at 800– 1000 °C based on the stability field of stishovite. This new evidence, together with previous stishovite exsolution microstructure in the gneiss from the same region, suggests an ultra‐deep subduction and exhumation of the South Altyn continental rocks to/from mantle depths in stishovite stability field. Evidence of ultra‐deep subduction of continental materials might be more common and diverse than previous thought. Exhumation of subducted continental rocks from≥300 km has been considered impossible because they are denser than mantle at these depths. How did the stishovite bearing continental rocks of the South Altyn exhumated? As we all know, the densities of stishovite (4.3 g/cm³) are much higher than coesite (2.9 g/cm³), and stishovite transforms into coesite with temperature increases. Density calculations were performed for subducted continental rocks along phase transition of stishovite to coesite, using the third‐order Birch‐Murnaghan equation of state based on mineral fractions obtained from experiments and Perple_X. The results show that the density of Siliceous rocks decrease remarkably, lower than the surrounding mantle in coesite stability field, whereas the density of Oligosiliceous and Silicon unsaturated rocks is higher than surrounding mantle. Thus, we propose that the thermal induced transformation could provide an initial driven force for the exhumation of ultra‐deep subducted silica‐enriched felsic continental rocks. Temperature increase could be derived from an increased geothermal gradient from convective mantle or mantle plume. Mafic to ultra‐mafic rocks and silica‐deficient rocks may be captured by the upwelling subducted continental rocks and exhumated together.     

GRIDA3—a shared resources manager for environmental data analysis and applications

GRIDA3 (Shared Resources Manager for Environmental Data Analysis and Applications) is a multidisciplinary project designed to deliver an integrated system to forge solutions to some environmental challenges such as the constant increase of polluted sites, the sustainability of natural resources usage and the forecast of extreme meteorological events. The GRIDA3 portal is mainly based on Web 2.0 technologies and EnginFrame framework. The portal, now at an advanced stage of development, provides end-users with intuitive Web-interfaces and tools that simplify job submission to the underneath computing resources. The framework manages the user authentication and authorization, then controls the action and job execution into the grid computing environment, collects the results and transforms them into an useful format on the client side. The GRIDA3 Portal framework will provide a problem-solving platform allowing, through appropriate access policies, the integration and the sharing of skills, resources and tools located at multiple sites across federated domains.     

Evidence of multiple thermokarst lake generations from an 11 800‐year‐old permafrost core on the northern Seward Peninsula,Alaska

Permafrost degradation influences the morphology, biogeochemical cycling and hydrology of Arctic landscapes over a range of time scales. To reconstruct temporal patterns of early to late Holocene permafrost and thermokarst dynamics, site‐specific palaeo‐records are needed. Here we present a multi‐proxy study of a 350‐cm‐long permafrost core from a drained lake basin on the northern Seward Peninsula, Alaska, revealing Lateglacial to Holocene thermokarst lake dynamics in a central location of Beringia. Use of radiocarbon dating, micropalaeontology (ostracods and testaceans), sedimentology (grain‐size analyses, magnetic susceptibility, tephra analyses), geochemistry (total nitrogen and carbon, total organic carbon, δ¹³C_org) and stable water isotopes (δ¹⁸O, δD, d excess) of ground ice allowed the reconstruction of several distinct thermokarst lake phases. These include a pre‐lacustrine environment at the base of the core characterized by the Devil Mountain Maar tephra (22 800±280 cal. a BP, Unit A), which has vertically subsided in places due to subsequent development of a deep thermokarst lake that initiated around 11 800 cal. a BP (Unit B). At about 9000 cal. a BP this lake transitioned from a stable depositional environment to a very dynamic lake system (Unit C) characterized by fluctuating lake levels, potentially intermediate wetland development, and expansion and erosion of shore deposits. Complete drainage of this lake occurred at 1060 cal. a BP, including post‐drainage sediment freezing from the top down to 154 cm and gradual accumulation of terrestrial peat (Unit D), as well as uniform upward talik refreezing. This core‐based reconstruction of multiple thermokarst lake generations since 11 800 cal. a BP improves our understanding of the temporal scales of thermokarst lake development from initiation to drainage, demonstrates complex landscape evolution in the ice‐rich permafrost regions of Central Beringia during the Lateglacial and Holocene, and enhances our understanding of biogeochemical cycles in thermokarst‐affected regions of the Arctic.     

The Calcium Isotope Composition of Modern Seawater Determined by Thermal Ionisation Mass Spectrometry

The Ca isotopic composition of modern seawater has been determined using a ⁴³Ca-⁴⁸Ca double spike, which was calibrated using a ⁴²Ca/⁴⁴Ca seawater ratio of 0.30587 ± 0.00026. This ratio was determined from a total evaporation experiment in which the ion beam was measured from the beginning to the end of the emission. With integration of the peak intensities, the fractionation effects can be minimised, since total evaporation of the reservoir cancels out the effect of vapour enrichment in the light isotopes. This experiment avoids the gravimetric uncertainty inherent in the double spike calibration. This calibration allows the precise redetermination of the seawater isotopic composition of Ca. A mean ⁴⁰Ca/⁴⁴Ca ratio for two Atlantic water samples of 45.143 (2s_mean= 0.003) was found. The good reproducibility of the Ca isotope ratios in present seawater and the very strong isotopic homogeneity of Ca in the oceans illustrate the advantage of using seawater as the common standard, with the advantage of decreasing interlaboratory bias.     

Dependence of clinopyroxene composition on cooling rate in basaltic magmas: Implications for thermobarometry

The compositional variation of clinopyroxene and the partitioning of major elements between clinopyroxene and melt are estimated as a function of the cooling rate. Clinopyroxenes were crystallized under variable cooling regimes (15, 9.4, 3, 2.1, and 0.5 °C/min from 1250 down to 1000 °C) and at isothermal conditions of 1000 °C from a basaltic composition at a pressure of 500 MPa under anhydrous and hydrous (H₂O = 1.3 wt.%) conditions. The clinopyroxene chemistry shows that, as the cooling rate increases, crystals are progressively depleted in Ca, Mg, Fe²⁺ and Si and enriched in Na, Fe³⁺, Al (mainly Al^IV), and Ti. Di and Hd versus CaTs and CaFeTs form a continuous binary solid solution characterized by higher amounts of tschermakitic components with increasing cooling rate. Two parameters (DH = Di + Hd and TE = CaTs + CaFeTs + En) are calculated to describe the effect of cooling rate on the clinopyroxene composition. The variation of DH/TE with increasing cooling rate evidences the kinetic process induced by rapid cooling in basic rocks under hydrous and anhydrous conditions.Dynamic crystallization conditions affect the partitioning of major elements between clinopyroxene and melt; with increasing cooling rate, the value of crystal–melt partition coefficient departs from that obtained at the isothermal condition. However, in spite of these variations, the values of ^cpx–meltKd_Fe–Mg remain almost constant. Therefore, the Fe²–Mg exchange between clinopyroxene and melt is not suitable to prove the (dis)equilibrium conditions in basaltic cooling magmas, giving rise to possible mismatches in the application of thermobarometers. The results of our study are consistent with that observed at the margin of dikes or in the exterior portions of lavas, where the cooling rate is maximized and disequilibrium compositions of clinopyroxene have been found.     

Satellite microwave detected SST anomalies and hurricane intensification

Sea surface temperature (SST) from the remotely sensed infrared measurements, like the GOES, AVHRR, and MODIS, etc., show missing values of SST over the cloudy regions associated with hurricanes. While satellite microwave measurements, like the Tropical Rainfall Measuring Mission (TRMM) microwave imager (TMI), can provide SST even under cloudy conditions. Both satellite microwave measurements and buoy observations show SST increase in advance of significant hurricane intensification. Moreover, hurricane intensification may also be related to the location of high SST. Our results indicate pre-existing high SST anomaly (SSTA) located at the right side of the storm track for Hurricane Katrina. Numerical simulations also confirm the important impacts of SSTA location on hurricane intensification. Similar situations are also found for Hurricanes Rita and Wilma. In contrast, if there is no high SSTA at the right location, hurricane may not undergo further intensification. This may explain why not all tropical cyclones associated with warm waters can attain peak intensity (categories 4 and 5) during their life cycle, and partially explains why hurricanes do not reach the maximum potential intensity as calculated only according to the magnitude of SST.