稻虾轮作模式面源污染排放特征及其能值评估

为探明稻虾轮作模式面源污染排放特征并合理评价该模式的环境可持续性,通过对江汉平原稻虾轮作模式小龙虾养殖排放尾水中总氮(TN)、总磷(TP)、COD和氨氮(NH₃-N)浓度进行监测,对稻虾轮作模式稻田养殖小龙虾的排污系数进行了估算,并采用等标污染负荷法进行了主要污染物解析。运用能值分析方法对稻虾轮作模式进行了包含面源污染的能值评估,对比单季稻模式,对其可持续发展能力进行了定量评价。结果表明：江汉平原稻虾轮作模式小龙虾养殖排放尾水中TN、TP、COD和NH₃-N的浓度范围分别为0.53～5.36、0.12～0.70、6.60～78.39和0.34～1.75 mg/L,TN、TP和COD平均排放浓度高于《地表水环境质量标准》(GB 3838-2002)Ⅲ类水质标准。等标污染负荷法分析结果表明TN的等标负荷比最高,是稻虾轮作模式面源污染控制的关键污染物。稻虾轮作模式小龙虾养殖排放尾水中TN、TP、COD和NH₃-N的排污系数分别为2.994、0.458、35.132和1.405 kg/t,表明稻虾轮作模式面源污染排放系数较低,对...     

The Late Triassic I–Type Granites from the Longmu Co–Shuanghu Suture Zone in the interior of Tibetan Plateau, China: Petrogenesis and Implication for Slab Break–Off

The Jiangaidarina granitic mass(JM) is an important part of the magmatic belt in Longmu CoShuanghu Suture Zone(LSSZ) in the central Tibetan Plateau. An integrated research involving wholerock geochemistry, zircon LA-ICP-MS U-Pb ages and Hf isotopic compositions was carried out to define the timing, genesis and tectonic setting of the JM. Zircon LA-ICP-MS U-Pb ages have been obtained ranging from 210 to 215 Ma, rather than the Early Jurassic as previously thought. Fifteen granite samples contain hornblendes and show a negative correlation between P_2 O_5 and SiO_2, indicating that the JM is an I-type granite. All the granites are enriched in LREE relative to HREE, with negative Eu anomalies(Eu/Eu*=0.56-0.81), and have similar trace elements patterns, with depletion of Ba, Nb, Sr and P. These suggest that the JM was fractionated, and this is also proved by the characteristic of negative correlations between oxide elements(TiO_2, MgO, FeOt, MnO, CaO) and SiO_2. Almost all ε_(Hf)(t) values of the granites are between-10.3 and-5.8, implying that the JM has a crustal source intimately related with the South Qiangtang Block(SQB), except for one(+10.2), showing a minor contribution from mantle source.Moreover, relatively low Na_2 O/K_2 O ratios(0.42-0.93) and high A/CNK values(0.91-1.50) reflect that the JM was predominately derived from the medium-high potassium basaltic crust, interacted with greywacke. Our new geochemical data and geochronological results imply that the Late Triassic magmas were generated in a post-collisional tectonic setting, probably caused by slab break-off of the Longmu Co-Shuanghu Tethyan Ocean(LSTO). This mechanism caused the asthenosphere upwelling, formed extension setting, offered an enormous amount of heat, and provided favorable conditions for emplacement of voluminous felsic magmas. Furthermore, the LSTO could be completely closed during the Middle Triassic, succeed by continental collision and later the slab broke off in the Late Triassic.     

原子荧光光谱法测定地球化学样品中的砷、锑和汞的方法改进

在原子荧光光谱法中，通过改进地球化学样品的分解条件，预还原条件及测定条件，使砷、锑和汞能在同一介质中测定，而且实现了砷与汞的双道同时测定。方法的检测出限、准确度及精密度均能达到行业要求。     

多年冻土区青藏铁路列车荷载作用下路基振动响应研究

针对多年冻土区青藏铁路列车荷载振动作用下的动稳定性,通过对北麓河和二道沟三个典型铁路路基横断面振动响应的二分量加速度观测,对比分析客运列车和货运列车引起的路基振动特性和衰减规律,研究不同防护形式路基的列车振动响应。结果表明,路基上的振动作用主要集中在40～80Hz频率范围内;防护形式对路基的列车动力响应有明显影响,热棒加碎石路基动力响应最小,其次为碎石防护路基,未采取任何防护的路基铁轨上的动力响应最大,建议对未采取防护的路基进行防护。分析结论为青藏铁路列车作用下的路基动稳定性评估提供实测依据,对多年冻土区的路基稳定性研究提供参考。     

甘肃阿尔金成矿带安南坝青砂沟大型贫锰矿发现及意义

张新虎等人在区域成矿地质背景研究过程中,通过对比分析甘肃阿尔金成矿带成矿特征,认为在已知安南坝苦水泉锰矿外围具有寻找沉积型锰矿的地质条件,建议在该带安排锰矿勘查项目,提出"以1:5万面积性物化探扫面入手,加强含锰层位对比研究,及时开展化探异常查证,追索矿化线索"的指导方针。经项目实施,发现了阿克塞县安南坝青砂沟、赛马沟锰矿床(点),其中青砂沟锰矿已达大型规模,实现了锰矿勘查新突破,成为甘肃西部阿尔金成矿带找矿突破的成功案例。该矿床主要是通过水系沉积物测量异常查证发现的。本文从区域成矿背景、化探异常特征、含锰层位追索、勘查评价方法等方面进行总结。文章反映了该矿床选矿试验结果,确认该锰矿是具有一定经济意义的大型低品位锰矿床,对阿尔金成矿带锰铁矿勘查评价和方法技术组合应用具有借鉴意义。     

Designing a spatial pattern to rebalance the orientation of development and protection in Wuhan

Patterns of spatial development and protection form a basic category of geoscience,and redesigning them is a popular subject of research in regional sustainable development that is important for ecological civilization construction.The authors here report a case study of Wuhan city using the circuit theory model and minimum cumulative resistance(MCR)model to rebalance its spatial protection and development.The results show the following:(1)Using the density of the gross domestic product(GDP),density of population,rate of urbanization,and access to transportation as evaluation indicators,seven core areas of development in Wuhan were identified,accounting for 59%of the total number of streets,that exhibited a “circular-satellite”spatial structure.(2)According to the importance of ecosystem services,ecological sensitivity,land use type,and slope of the terrain,the resistance surface of spatial development in Wuhan had a stereoscopic spatial form of an“inverted pyramid,”with high surroundings and a low center.The area of low resistance accounted for 6.64%of the total area of Wuhan.(3)Based on coupling analysis using the MCR and spatial morphological characteristics of current,nine axes of spatial development with a total area of 427.27 km2 and eight key strategic points with a total area of 40.02 km2 were identified.Streets that were prioritized for development accounted for 9.63%of Wuhan's total area.(4)By combining the characterization of the development axis with the structure of the three-level core area,we extracted the structure of spatial development of "one heart,two wings,and three belts" in Wuhan.The research framework and empirical results can provide scientific guidance for the urban spatial layout,the development of regional linkages,and ecological environmental protection in China.     

田口方法用于地质样品中痕量超痕量金三种分析方法的对比

目前测定地质样品痕量、超痕量金常用的三种方法是活性炭吸附富集-发射光谱法、泡塑吸附富集-石墨炉原子吸收光谱法、活性炭吸附富集-电感耦合等离子体质谱法,这三种方法的检出限在0.1~0.3ng/g之间,由于矿石矿物的组成非常复杂,因此在有效富集和分离的基础上,采用合适的分析手段,能够对地质样品提供满意的分析结果。为保证试样要求的灵敏度和准确性,分析方法的选择需求应根据具体试样情况和实验室条件而定。根据田口玄一博士在测量工程学中提出的信噪比(S/N)能测量系统抗干扰能力,评价测量系统的稳健性和可靠性这一观点,本文利用田口测量质量控制理论,评价地质样品中痕量、超痕量金常用的上述三种分析测试方法,对这三种分析方法三个金标准物质的测试数据进行分类处理,计算S/N值和相对标准不确定度,通过比较三者的S/N值和相对标准不确定度值,确定更为可靠的测试体系。分析结果表明,对于地质样品中痕量金(含量大于1 ng/g)的测试,三种分析方法均能够满足要求;对于超痕量金(含量小于1 ng/g)的测试,活性炭吸附富集-电感耦合等离子体质谱法是较好的测试方案。     

Structural differences between the western and eastern Qiongdongnan Basin: evidence of Indochina block extrusion and South China Sea seafloor spreading

Located at the intersection between a NW-trending slip system and NE-trending rift system in the northern South China Sea, the Qiongdongnan Basin provides key clues for us to understand the proposed extrusion of the Indochina Block along with Red River Fault Zone and extensional margins. In this paper we for the first time systematically reveal the striking structural differences between the western and eastern sector of the Qiongdongnan Basin. Influenced by the NW-trending slip faults, the western Qiongdongnan Basin developed E–W-trending faults, and was subsequently inverted at 30–21 Ma. The eastern sector was dominated by faults with NE orientation before 30 Ma, and thereafter with various orientations from NE, to EW and NW during the period 30–21 Ma; rifting display composite symmetric graben instead of the composite half graben or asymmetric graben in the west. The deep and thermal structures in turn are invoked to account for such deformation differences. The lithosphere of the eastern Qiongdongnan Basin is very hot and thinned because of mantle upwelling and heating, composite symmetric grabens formed and the faults varied with the basal plate boundary. However, the Southern and Northern Uplift area and middle of the central depression is located on normal lithosphere and formed half grabens or simple grabens. The lithosphere in the western sector is transitional from very hot to normal. Eventually, the Paleogene tectonic development of the Qiongdongnan Basin may be summarized into three stages with dominating influences, the retreat of the West Pacific subduction zone (44–36 Ma), slow Indochina block extrusion together with slab-pull of the Proto-South China Sea (36–30 Ma), rapid Indochina block extrusion together with the South China Sea seafloor spreading (30–21 Ma).     

威海市近海海域表层沉积物环境质量评价

对威海近海海域127站位表层沉积物中的重金属元素进行分析测试,采用单因子污染指数法、综合污染指数法、超标分类法和潜在生态危害法等多种评价方法对研究区环境质量进行评价。认为研究区海底表层沉积物的单因子污染物指数偏低,只有Cu和Cr两种重金属出现一类沉积物质量超标情况;海底表层沉积物环境质量在整体上处于清洁和尚清洁状态,个别站位处于允许状态;污染类型主要以Ⅰ类、Ⅱ类为主,含少量Ⅲ类,Ⅱ类又分为Ⅱ1Cr和Ⅱ2Cu两个污染亚类,Ⅲ类又分为Ⅲ1Cr-Cu和Ⅲ2Cu-Cr两个污染亚类;各种重金属的生态危害程度均低。     

地壳对海洋潮汐的响应

应用三维动态有限元方法研究了中国北部地区的地壳对邻近的渤海与黄海海平面变化的响应。虽然此应力场过于微弱不足以引发地震，但发现应力集中的位置及应力场变化较大的位置恰好与某些现代地震的震中一致。这一结果表明研究地壳对广泛分布的载荷的响应对研究区域地震构造是有帮助的。