Geomorphic and hydrological controls on groundwater dolocrete formation in the semi-arid Hamersley Basin,northwest Australia

Groundwater dolocretes may exert an important geomorphic control on landscape evolution within sub-humid to arid regions. However, the geomorphic and hydrogeological settings of dolocrete remain poorly described. The hydrochemical conditions of dolomite precipitation in groundwater environments are also not well known. Classic models of dolocrete formation explain dolomite precipitation from highly evolved groundwaters at the terminus of major drainage but do not explain dolocrete distributed in regionally elevated landscapes, upgradient of major drainage. This study investigated the mineralogy, micromorphology and stable carbon and oxygen isotope compositions of three dolocrete profiles within a regionally elevated sub-basin of the Hamersley Ranges in the Pilbara region of northwest Australia. We sought to establish the environmental and hydrochemical conditions and present a model for dolocrete formation. We found that dolocrete formed within zones of emerging groundwater under saline-evaporitic conditions within internally draining sub-basins, most likely during the Late Miocene and Pliocene. Saline-evaporitic conditions were indicated by: (i) the mineralogy, dominated by dolomite, palygorskite and smectite; (ii) desiccation features and the presence of phreatic and vadose cements, indicative of a shallow fluctuating water table, and; (iii) dolomite δ¹⁸O values (median = –5.88 ‰). Dolomite precipitation was promoted by evaporation and carbon dioxide degassing from shallow magnesium (Mg)-rich groundwater. These factors appear to have been the major drivers of dolocrete development without a requirement for significant down-dip hydrochemical modification. Primary dolomite precipitation was possible due to the presence of microbial extracellular polymeric substances (EPS). EPS provided negatively charged nucleation sites, which bound Mg²⁺, overcoming kinetic effects. High microbial activity within groundwater systems suggest these processes may be important for dolocrete formation worldwide and that groundwater dolocretes may be more pervasive in landscapes than currently recognized. © 2019 John Wiley & Sons, Ltd. © 2019 John Wiley & Sons, Ltd.     

Geochronological constraints on Caledonian strike–slip displacement in Svalbard,with implications for the evolution of the Arctic

The timing of Svalbard's assembly in relation to the mid‐Paleozoic Caledonian collision between Baltica and Laurentia remains contentious. The Svalbard archipelago consists of three basement provinces bounded by N–S‐trending strike–slip faults whose displacement histories are poorly understood. Here, we report microstructural and mineral chemistry data integrated with ⁴⁰Ar/³⁹Ar muscovite geochronology from the sinistral Vimsodden‐Kosibapasset Shear Zone (VKSZ, southwest Svalbard) and explore its relationship to adjacent structures and regional deformation within the circum‐Arctic. Our results indicate that strike–slip displacement along the VKSZ occurred in late Silurian–Early Devonian and was contemporaneous with the beginning of the main phase of continental collision in Greenland and Scandinavia and the onset of syn‐orogenic sedimentation in Silurian–Devonian fault‐controlled basins in northern Svalbard. These new‐age constraints highlight possible links between escape tectonics in the Caledonian orogen and mid‐Paleozoic terrane transfer across the northern margin of Laurentia.     

Model for prediction of sea dike breaching initiated by breaking wave impact

A computational model system is proposed for the prediction of sea dike breaching initiated from the seaward side by breaking wave impact with the focus on the application of the model system for the estimation failure probability of the defence structure. The described model system is built using a number of existing models for the calculation of grass, clay, and sand erosion. The parameters identified as those having the most significant influence on the estimation of the failure have been described stochastically. Monte Carlo simulations to account for uncertainties of the relevant input parameters and the model itself have been performed and the probabilities of the breach initiation and of the full dike breaching have been calculated. This will form the basis to assess the coastal flood risk due to dike breaching.     

Analysis and modeling of spatial correlation structure in small-scale rainfall in Central Oklahoma

Spatial correlation structure in small-scale rainfall is analyzed based on a dense cluster of raingauges in Central Oklahoma. This cluster, called the EVAC PicoNet, consists of 53 gauges installed in 25 measurement stations covering an area of about 3 km by 3 km. Two raingauges are placed in 24 stations and five in the central station. Three aspects of the estimated spatial correlation functions are discussed: dependence on time-scale ranging from 1 min to 24 h, inter-storm variability, and dependence on rainfall intensity. The results show a regular dependence of the correlogram parameters on the averaging time-scale, large differences of the correlograms in the individual storms, and the dominance of storms with high spatial variability on the average large sample characteristics. The authors also demonstrate and discuss the ambiguities in correlation estimates conditioned on rainfall intensities. The findings of this study have implications for raingauge network design, rainfall modeling, and conclusive evaluation of radar and satellite estimates of rainfall.     

Effects of non-thermal tails in Maxwellian electron distributions on synchrotron and Compton processes

We investigate how the presence of a non-thermal tail beyond a Maxwellian electron distribution affects the synchrotron process as well as Comptonization in plasmas with parameters typical for accretion flows on to black holes. We find that the presence of the tail can significantly increase the net (after accounting for self-absorption) cyclo-synchrotron emission of the plasma, which then provides seed photons for Compton upscattering. Thus, the luminosity in the thermally Comptonized spectrum is enhanced as well. The importance of these effects increases with both increasing Eddington ratio and black hole mass. The enhancement of the Comptonized synchrotron luminosity can be as large as ∼10³ and ∼10⁵ for stellar and supermassive black holes, respectively, when the energy content in the non-thermal tail is 1 per cent.
The presence of the tail only weakly hardens the thermal Comptonization spectrum but it leads to the formation of a high-energy tail beyond the thermal cut-off, which two effects are independent of the nature of the seed photons. Since observations of high-energy tails in Comptonization spectra can constrain the non-thermal tails in the electron distribution and thus the Comptonized synchrotron luminosity, they provide upper limits on the strength of magnetic fields in accretion flows. In particular, the measurement of an MeV tail in the hard state of Cyg X-1 by McConnell et al. implies the magnetic field strength in this source to be at most an order of magnitude below equipartition.