Volcanic gases, black smokers, and the great oxidation event

This paper proposes that gradual changes in the composition of volatiles that have been added to the atmosphere-ocean system are responsible for the Great Oxidation Event (G.O.E.) ca. 2.3 Ga. Before ca. 2.3 Ga, the composition of these volatiles was probably such that 20% of the carbon gases could be reduced to organic matter and all of the sulfur gases could be reduced to pyrite. Since 2.3 Ga, the composition of these volatiles has been such that 20% of the carbon gases could be reduced to organic matter, but only a fraction of the sulfur gases could be reduced to pyrite. This change led to the oxygenation of the atmosphere and to a large increase in the SO₄⁻² concentration of seawater. A considerable body of observational data supports these proposals.     

The effect of bathymetric filtering on nearshore process model results

Nearshore wave and flow model results are shown to exhibit a strong sensitivity to the resolution of the input bathymetry. In this analysis, bathymetric resolution was varied by applying smoothing filters to high-resolution survey data to produce a number of bathymetric grid surfaces. We demonstrate that the sensitivity of model-predicted wave height and flow to variations in bathymetric resolution had different characteristics. Wave height predictions were most sensitive to resolution of cross-shore variability associated with the structure of nearshore sandbars. Flow predictions were most sensitive to the resolution of intermediate scale alongshore variability associated with the prominent sandbar rhythmicity. Flow sensitivity increased in cases where a sandbar was closer to shore and shallower. Perhaps the most surprising implication of these results is that the interpolation and smoothing of bathymetric data could be optimized differently for the wave and flow models. We show that errors between observed and modeled flow and wave heights are well predicted by comparing model simulation results using progressively filtered bathymetry to results from the highest resolution simulation. The damage done by over smoothing or inadequate sampling can therefore be estimated using model simulations. We conclude that the ability to quantify prediction errors will be useful for supporting future data assimilation efforts that require this information.     

Zonal versus meridional velocity variance in satellite observations and realistic and idealized ocean circulation models

Global, high-quality, satellite-based observation of oceanic currents over the past 13 years has revealed ubiquitous quasi-horizontal eddies in the mesoscale (tens to hundreds of kilometers), confirming the view of a highly turbulent ocean suggested by observational programs in the 1970s. Idealized quasigeostrophic turbulence models suggest mesoscale turbulent flow can vary between isotropic, and highly anisotropic zonal jets. Here we compare the zonal and meridional velocity variance from satellite altimetry. We find that, for an unexplained reason and despite the chaotic nature of turbulence, the surface flow is organized into mesoscale patches where either zonal or meridional velocity variance dominates. The patches persist over 13 years, much longer than the turbulent timescale of a few months. Implications include potentially highly anisotropic redistribution of tracers by the mesoscale flow. Zonally averaged velocity variances reveal a slight preference for meridional over zonal velocity variance. Realistic primitive equation models succeed in reproducing both the patchy structure in local preference for either zonal or meridional velocity variance, and the zonally averaged preference for meridional variance. Idealized models of fully developed, quasigeostrophic turbulence fail in both regards.     

An Overview of CCD Development at Lawrence Berkeley National Laboratory

Fully depleted, back-illuminated charge-coupled devices fabricated at Lawrence Berkeley National Laboratory on high-resistivity silicon are described. Device operation and technology are discussed, as well as the results on telescopes and future plans. This revised version was published online in July 2006 with corrections to the Cover Date.     

In-flight Performance of the Advanced Camera for Surveys CCDs

The Advanced Camera for Surveys (ACS), installed in the Hubble Space telescope in March 2002, will significantly extend HST's deep, survey imaging capabilities. ACS has met, or exceeded, all of its key performance specifications. In this paper we briefly review the in-flight performance of the instrument's CCD detectors and preview early ACS science observations. This revised version was published online in July 2006 with corrections to the Cover Date.     

Practical use of video imagery in nearshore oceanographic fieldstudies

An approach was developed for using video imagery to quantify, in terms of both spatial and temporal dimensions, a number of naturally occurring (nearshore) physical processes. The complete method is presented, including the derivation of the geometrical relationships relating image and ground coordinates, principles to be considered when working with video imagery and the two-step strategy for calibration of the camera model. The techniques are founded on the principles of photogrammetry, account for difficulties inherent in the use of video signals, and have been adapted to allow for flexibility of use in field studies. Examples from field experiments indicate that this approach is both accurate and applicable under the conditions typically experienced when sampling in coastal regions. Several applications of the camera model are discussed, including the measurement of nearshore fluid processes, sand bar length scales, foreshore topography, and drifter motions. Although we have applied this method to the measurement of nearshore processes and morphologic features, these same techniques are transferable to studies in other geophysical settings     

Coupled scattering and reflection measurements in shallow water

The characteristics of shallow-water reverberation are often controlled by scattering from the seabed. While scattering mechanisms are understood in general, the state-of-the-art falls far short of predicting the correct angular and frequency dependence of scattering in a given region. A series of acoustic and supporting geoacoustic measurements were conducted over a large area in the Straits of Sicily in order to study seabed scattering in a complex littoral environment. The hypothesis was that exploiting direct path reflection coefficient measurements, in conjunction with the scattering measurements, could help illuminate the underlying scattering mechanisms. The sediment at the seabed interface was found to be a fine silty clay with nearly uniform properties across the area. Notwithstanding this spatial homogeneity, 1-6-kHz reflection and scattering measurements showed significant spatial variability. The coupled reflection-scattering approach resolved this apparent discrepancy, revealing that the reflection and scattering processes are largely controlled by the sediment properties below, rather than at, the water sediment interface. Measurements at 3600 Hz show that site-to-site variability is in part controlled by the thickness of the silty-clay layer. Layers up to 10 m below the water sediment interface contribute to the scattering at 3600 Hz.     

Petrology and geochemistry of the archean rocks of the malton gneiss complex,British Columbia

Hornblendic and felsic groups of Archean age and each of broadly similar geochemical composition across the Malton Gneiss Complex southeast of Valemount, Bristish Columbia, show detailed mineralogical and chemical variations from one geographical district to another. The complex appears to be composed of meta-igneous rocks which were originally developed as petrologically discrete units on a roughly 10-km scale, but which all belonged to one similar petrographic province. Overall they are characterized by rather high immobile trace and alkali element abundances. Their nearest geochemical equivalent appear to be found in the grey gneiss complexes of the North Atlantic Craton rather than in the granite-greenstone complexes of the Canadian Shield, but no other Archean complex possesses their overall characteristics. Some similarities in A-F-M and Q-Ab-Or content of these gneisses and those of the Laramie Range, Wyoming, are noted.