Intraplate deformation and 3D rheological structure of the Rhine Rift System and adjacent areas of the northern Alpine foreland

The lithosphere of the Northern Alpine foreland has undergone a polyphase evolution during which interacting stress-induced intraplate deformation and upper mantle thermal perturbations controlled folding of the thermally weakened lithosphere. In this paper we address relationships among deeper lithospheric processes, neotectonics and surface processes in the Northern Alpine foreland with special emphasis on tectonically induced topography. We focus on lithosphere memory and neotectonics, paying special attention to the thermo-mechanical structure of the Rhine Graben System and adjacent areas of the northern Alpine foreland lithosphere. We discuss implications for mechanisms of large-scale intraplate deformation and links with surface processes and topography evolution.     

Lateral tidal mixing in the Antarctic marginal seas

Tidal mixing plays an important role in the modification of dense water masses around the Antarctic continent. In addition to the vertical (diapycnal) mixing in the near-bottom layers, lateral mixing can also be of relevance in some areas. A numerical tide simulation shows that lateral tidal mixing is not uniformly distributed along the shelf break. In particular, strong mixing occurs all along the Ross Sea and Southern Weddell Sea shelf breaks, while other regions (e.g., the western Weddell Sea) are relatively quiet. The latter regions correspond surprisingly well to areas where indications for cross-shelf exchange of dense water masses have been found. The results suggest that lateral tidal mixing may account for the relatively small contribution of Ross Sea dense water masses to Antarctic Bottom Water.     

Study of Metal Distribution in Raw and Screened Swine Manure

The growth of industrial swine production over the last few years has led to a growth in concern over effluents generated by the activity. Several elements, mainly toxic metals, can be present in swine wastewater and can have a serious environmental impact. It is important, therefore, to know the metal concentration before the discharge of wastewater. In this work the temporal metal distribution in swine manure and its potential reduction using coarse (2 mm) and fine (<0.45 μm) liquid‐solid separation techniques were investigated. In order to do this, different swine manure sample preparation methods for Al, Ba, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sr and Zn determination by Inductively Coupled Plasma Optical Emission Spectrometry (ICP OES) were tested. The acid mixtures used to digest the manure sample significantly affected the metal recovery. Good analyte recoveries were observed with nitric acid/hydrogen peroxide mixtures or nitric acid/perchloric acid mixtures. Sulfuric acid/hydrogen peroxide mixtures produced inconsistent results and poor recoveries, mainly for Ba and Pb. It was observed that metal concentrations in swine manure varied greatly with time, up to one order of magnitude, due to changes in swine production such as feed and animal numbers. Metals concentrations observed in the raw wastewater exceeded Brazilian limits for discharge into water bodies and recommendations for agricultural use. Results obtained from the liquid‐solid separation study showed that metals in the raw swine manure were not removed with coarse screening. However, the major fraction of metals were removed by filtration (0.45 μm), with the exception of Na, K and Sr. Thus, the use of liquid‐solid separation techniques that capture the fine solid fractions (and associated metals) from raw manure can have a favorable impact on the environment and contribute to swine production wastewater treatment.     

A constitutive model for mechanical and chemo‐mechanical compaction in sedimentary basins and finite element analysis

Compaction and associated fluid flow are fundamental processes in sedimentary basin deformation. Purely mechanical compaction originates mainly from pore fluid expulsion and rearrangement of solid particles during burial, while chemo‐mechanical compaction results from Intergranular Pressure‐Solution (IPS) and represents a major mechanism of deformation in sedimentary basins during diagenesis. The aim of the present contribution is to provide a comprehensive 3D framework for constitutive and numerical modeling of purely mechanical and chemo‐mechanical compaction in sedimentary basins. Extending the concepts that have been previously proposed for the modeling of purely mechanical compaction in finite poroplasticity, deformation by IPS is addressed herein by means of additional viscoplastic terms in the state equations of the porous material. The finite element model integrates the poroplastic and poroviscoplastic components of deformation at large strains. The corresponding implementation allows for numerical simulation of sediments accretion/erosion periods by progressive activation/deactivation of the gravity forces within a fictitious closed material system. Validation of the numerical approach is assessed by means of comparison with closed‐form solutions derived in the context of a simplified compaction model. The last part of the paper presents the results of numerical basin simulation performed in one dimensional setting, demonstrating the ability of the modeling to capture the main features in elastoplastic and viscoplastic compaction. Copyright © 2016 John Wiley & Sons, Ltd.     

Simulating future Caspian sea level changes using regional climate model outputs

We report on simulations of present-day climate (1961–1990) and future climate conditions (2071–2100, Special Report on Emissions Scenario A2) over the Caspian sea basin with a regional climate model (RCM) nested in time-slice general circulation model (GCM) simulations. We also calculate changes (A2 scenario minus present-day) in Caspian sea level (CSL) in response to changes in the simulated hydrologic budget of the basin. For the present-day run, both the GCM and RCM show a good performance in reproducing the water budget of the basin and the magnitude of multi-decadal changes in CSL. Compared to present-day climate, in the A2 scenario experiment we find an increase in cold season precipitation and an increase in temperature and evaporation, both over land and over the Caspian sea. We also find a large decrease of CSL in the A2 scenario run compared to the present-day run. This is due to increased evaporation loss from the basin (particularly over the sea) exceeding increased cold season precipitation over the basin. Our results suggest that the CSL might undergo large changes under future climate change, leading to potentially devastating consequences for the economy and environment of the region.     

Ocean tide loading (OTL) displacements from global and local grids: comparisons to GPS estimates over the shelf of Brittany, France

In this paper we examine OTL displacements detected by GPS stations of a dedicated campaign and validate ocean tide models. Our area of study is the continental shelf of Brittany and Cotentin in France. Brittany is one of the few places in the world where tides provoke loading displacements of ∼10–12 cm vertically and a few cm horizontally. Ocean tide models suffer from important discrepancies in this region. Seven global and regional ocean tide models were tested: FES2004 corrected for K2, TPXO.7.0, TPXO.6.2, GOT00.2, CSR4.0, NAO.99b and the most recent regional grids of the North East Atlantic (NEA2004). These gridded amplitudes and phases of ocean tides were convolved in order to get the predicted OTL displacements using two different algorithms. Data over a period of 3.5 months of 8 GPS campaign stations located on the north coast of Brittany are used, in order to evaluate the geographical distribution of the OTL effect. We have modified and implemented new algorithms in our GPS software, GINS 7.1. GPS OTL constituents are estimated based on 1-day batch solutions. We compare the observed GPS OTL constituents of M₂, S₂, N₂ and K₁ waves with the selected ocean tide models on global and regional grids. Large phase-lag and amplitude discrepancies over 20° and 1.5 cm in the vertical direction in the semi-diurnal band of M₂ between predictions and GPS/models are detected in the Bay of Mont St-Michel. From a least squares spectral analysis of the GPS time-series, significant harmonic peaks in the integer multiples of the orbital periods of the GPS satellites are observed, indicating the existence of multipath effects in the GPS OTL constituents. The GPS OTL observations agree best with FES2004, NEA2004, GOT00.2 and CSR4.0 tide models.     

Determining the weights of two types of artificial reefs required to resist wave action in different water depths and bottom slopes

The interaction between waves and artificial reefs (ARs; a hollow cube weighing 8.24 kN (0.84 t) and a water pipe weighing 1.27 kN (0.13 t)) in shallow waters was investigated with respect to variations in design weight, orientation (for cube; 45° and 90° angles, for pipe; 0°, 90°, and 180° angles to flow), depth (1–20 m), and bottom slope (10^?1, 30^?1, and 50^?1). Physics equations and FLUENT software were used to estimate resisting and mobilising forces, and drag coefficients. Drag coefficients for the hollow cube were 0.76 and 0.85 at 45° and 90° angles to the current, respectively, and 0.97, 0.38, and 1.42 for the water pipe at 0°, 90°, and 180° angles to the current, respectively. Deepwater offshore wave conditions at six stations were transformed into shallow nearshore waters representative of the artificial reef site. Waters deeper than 12 and 16 m are safe to deploy blocks with angles of 45° and 90°, respectively. However, water pipes constructed at angles of 90° and 180° to the current were estimated as being unstable for 365 out of 720 cases at all stations (only one station was stable for all cases). Water pipes angled at 0° were found to be stable in all 360 cases. Slope had a significant effect on weight and depth. Results from this study provide an important reference for engineers performing projects aiming to increase the performance and service life of ARs.     

Optical absorption and mössbauer spectra of purple and green yoderite,a kyanite-related mineral

Mössbauer and polarized optical absorption spectra of the kyanite-related mineral yoderite were recorded. Mössbauer spectra of the purple (PY) and green yoderite (GY) from Mautia Hill, Tanzania, show that the bulk of the iron is Fe³⁺ in both varieties, with Fe²⁺/(Fe²⁺+Fe³⁺) ratios near 0.05. Combining this result with new microprobe data for PY and with literature data for GY gives the crystallochemical formulae: $$\begin{gathered} ({\text{Mg}}_{{\text{1}}{\text{.95}}} {\text{Fe}}_{{\text{0}}{\text{.02}}}^{{\text{2 + }}} {\text{Mn}}_{{\text{0}}{\text{.01}}}^{{\text{2 + }}} {\text{Fe}}_{{\text{0}}{\text{.34}}}^{{\text{3 + }}} {\text{Mn}}_{{\text{0}}{\text{.07}}}^{{\text{3 + }}} {\text{Ti}}_{{\text{0}}{\text{.01}}} {\text{Al}}_{{\text{3}}{\text{.57}}} )_{5.97}^{[5,6]} \hfill \\ {\text{Al}}_{{\text{2}}{\text{.00}}}^{{\text{[5]}}} [({\text{Si}}_{{\text{3}}{\text{.98}}} {\text{P}}_{{\text{0}}{\text{.03}}} ){\text{O}}_{{\text{18}}{\text{.02}}} ({\text{OH)}}_{{\text{1}}{\text{.98}}} ] \hfill \\ \end{gathered}$$ and PY and $$\begin{gathered} ({\text{Mg}}_{{\text{1}}{\text{.98}}} {\text{Fe}}_{{\text{0}}{\text{.02}}}^{{\text{2 + }}} {\text{Mn}}_{{\text{< 0}}{\text{.001}}}^{{\text{2 + }}} {\text{Fe}}_{{\text{0}}{\text{.45}}}^{{\text{3 + }}} {\text{Ti}}_{{\text{0}}{\text{.01}}} {\text{Al}}_{{\text{3}}{\text{.56}}} )_{6.02}^{[5,6]} \hfill \\ {\text{Al}}_{{\text{2}}{\text{.00}}}^{{\text{[5]}}} [({\text{Si}}_{{\text{3}}{\text{.91}}} {\text{O}}_{{\text{17}}{\text{.73}}} {\text{(OH)}}_{{\text{2}}{\text{.27}}} ] \hfill \\ \end{gathered}$$ for GY. The Mössbauer spectra at room temperature contain one main doublet with isomer shifts and quadrupole splittings of 0.36 (PY), 0.38 (GY) and 1.00 (PY), 0.92 (GY) mm s^?1, respectively. These values correspond to Fe³⁺ in six or five-fold coordination. The doublet components have anomalously large half widths indicating either accomodation of Fe³⁺ in more than one position (e.g., octahedraA1 and five coordinatedA2) or the yet unresolved superstructure. Besides strong absorption in the ultraviolet (UV) starting from about 25,000 cm^?1, the polarized optical absorption spectra are dominated by strong bands around 16,500 and 21,000 cm^?1 (PY) and a medium strong band at around 13,800 cm^?1 (GY). Position and polarization of these bands, in combination with the UV absorption, explain the colour and pleochroism of the two varieties. The bands in question are assigned to homonuclear metal-to-metal charge transfer transitions: Mn²⁺(A1) Mn³⁺(A1′) ? Mn³⁺(A1) Mn²⁺(A1′) and Mn²⁺(A1) Mn³⁺(A2 ? Mn³⁺(A1) Mn²⁺(A2) in PY and Fe²⁺(A1) Fe³⁺(A1′) ? Fe³⁺(A1) Fe²⁺(A1′) in GY. The evidence for homonuclear Mn²⁺ Mn³⁺ charge transfer (CTF) is not quite clear and needs further study. Heteronuclear FeTi CTF does not contribute to the spectra. In PY, additional weak bands were resolved at energies around 17,700, 18,700, 21,000, and 21,900 cm^?1 and assigned to Mn³⁺ in two positions. Weak bands around 10,000 cm^?1 in both varieties are assigned to Fe²⁺ spin-alloweddd-transitions. Very weak and sharp bands, around 15,400, 16,400, 21,300, 22,100, 23,800, and 25,000 cm^?1 are identified in GY and assigned to Fe³⁺ spin-forbiddendd-transitions.     

Mixed-function oxygenases as biological monitors around petroleum hydrocarbon development sites: Potential for induction by diesel and other drilling mud base oils containing reduced levels of polycyclic aromatic hydrocarbons

The use of oil-based drilling muds has been discouraged in hydrocarbon exploration and production in the marine environment but these muds are presently being used to a considerable degree in the United Kingdom and Norwegian sectors of the North Sea. Field studies in the North Sea have demonstrated only localized impacts around individual drilling sites,^1,2 even including those sites where ‘toxic’ diesel oils were employed as base fluids in drilling muds. Yet the question of disposal of cuttings contaminated with oil from drilling muds remains somewhat controversial. The induction of mixed-function oxygenases (MFO) has been validated on a number of occasions in the field as a sensitive index of low level hydrocarbon exposure (reviewed by Payne),³ including sites in the North Sea where diesel-based muds were used.⁴ The present study demonstrates that any potential for induction by hydrocarbon contaminated cuttings will probably be reduced by substitution of low-aromatic base oils for diesel in drilling mud formulations.