Isotopic compositions of oxygen, iron, chromium, and nickel in cosmic spherules: Toward a better comprehension of atmospheric entry heating effects

Large, correlated, mass-dependent enrichments in the heavier isotopes of O, Cr, Fe, and Ni are observed in type-I (metal/metal oxide) cosmic spherules collected from the deep sea. Limited intraparticle variability of oxygen isotope abundances, typically <5‰ in δ¹⁸O, indicates good mixing of the melts and supports the application of the Rayleigh equation for the calculation of fractional evaporative losses during atmospheric entry. Fractional losses for oxygen evaporation from wüstite, assuming a starting isotopic composition equal to that of air (δ¹⁸O = 23.5‰; δ¹⁷O = 11.8‰), are in the range 55%-77%, and are systematically smaller than evaporative losses calculated for Fe (69%-85%), Cr (81%-95%), and especially Ni (45%-99%). However, as δ¹⁸O values increase, fractional losses for oxygen approach those of Fe, Cr, and Ni indicating a shift in the evaporating species from metallic to oxidized forms as the spherules are progressively oxidized during entry heating. The observed unequal fractional losses of O and Fe can be reconciled by allowing for a kinetic isotope mass-dependent fractionation of atmospheric oxygen during the oxidation process and/or that some metallic Fe may have undergone Rayleigh evaporation before oxidation began.In situ measurements of oxygen isotopic abundances were also performed in 14 type-S (silicate) cosmic spherules, 13 from the Antarctic ice and one from the deep sea. Additional bulk Fe and Cr isotopic abundances were determined for two type-S deep-sea spherules. The isotopic fractionation of Cr isotopes suggest appreciable evaporative loss of Cr, perhaps as a sulfide. The oxygen isotopic compositions for the type-S spherules range from δ¹⁸O = −2‰ to + 27‰. The intraspherule isotopic variations are typically small, ∼5% relative, except for the less-heated porphyritic spherules which have preserved large isotopic heterogeneities in at least one case. A plot of δ¹⁷O vs. δ¹⁸O values for these spherules defines a broad parallelogram bounded at higher values of δ¹⁷O by the terrestrial fractionation line, and at lower values of δ¹⁷O by a line parallel to it and anchored near the isotopic composition of δ¹⁸O = −2.5‰ and δ¹⁷O = −5‰. Lack of independent evidence for substantial evaporative losses suggests that much of this variation reflects the starting isotopic composition of the precursor materials, which likely resembled CO, CM, or CI chondrites. However, the enrichments in heavy isotopes indicate that some mixing with atmospheric oxygen was probably involved during atmospheric entry for some of the spherules. Isotopic fractionation due to evaporation of incoming grain is not required to explain most of the oxygen isotopic data for type-S spherules. However spherules with barred olivine textures that are thought to have experienced a more intense heating than the porphyritic ones might have undergone some distillation. Two cosmic spherules, one classified as a radial pyroxene type and the other showing a glassy texture, show unfractionated oxygen isotopic abundances. They are probably chondrule fragments that survived atmospheric entry unmelted.Possible reasons type-I spherules show larger degrees of isotopic fractionation than type-S spherules include: a) the short duration of the heating pulse associated with the high volatile content of the type-S spherule precursors compared to type-I spherules; b) higher evaporation temperatures for at least a refractory portion of the silicates compared to that of iron metal or oxide; c) lower duration of heating of type-S spherules compared to type-I spherules as a consequence of their lower densities.     

The effect of El Niño Southern Oscillation cycles on the decadal scale suspended sediment behavior of a coastal dry‐summer subtropical catchment

Rivers display temporal dependence in suspended sediment–water discharge relationships. Although most work has focused on multi‐decadal trends, river sediment behavior often displays sub‐decadal scale fluctuations that have received little attention. The objectives of this study were to identify inter‐annual to decadal scale fluctuations in the suspended sediment–discharge relationship of a dry‐summer subtropical river, infer the mechanisms behind these fluctuations, and examine the role of El Niño Southern Oscillation climate cycles. The Salinas River (California) is a moderate sized (11 000 km²), coastal dry‐summer subtropical catchment with a mean discharge (Q_mean) of 11.6 m³ s^?1. This watershed is located at the northern most extent of the Pacific coastal North America region that experiences increased storm frequency during El Niño years. Event to inter‐annual scale suspended sediment behavior in this system was known to be influenced by antecedent hydrologic conditions, whereby previous hydrologic activity regulates the suspended sediment concentration–water discharge relationship. Fine and sand suspended sediment in the lower Salinas River exhibited persistent, decadal scale periods of positive and negative discharge corrected concentrations. The decadal scale variability in suspended sediment behavior was influenced by inter‐annual to decadal scale fluctuations in hydrologic characteristics, including: elapsed time since small (~0.1 × Q_mean), and moderate (~10 × Q_mean) threshold discharge values, the number of preceding days that low/no flow occurred, and annual water yield. El Niño climatic activity was found to have little effect on decadal‐scale fluctuations in the fine suspended sediment–discharge relationship due to low or no effect on the frequency of moderate to low discharge magnitudes, annual precipitation, and water yield. However, sand concentrations generally increased in El Niño years due to the increased frequency of moderate to high magnitude discharge events, which generally increase sand supply. Copyright © 2014 John Wiley & Sons, Ltd.     

Kampelite,Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O,a new very complex Ba-Sc phosphate mineral from the Kovdor phoscorite-carbonatite complex (Kola Peninsula,Russia)

Mineralogy and Petrology - Kampelite, Ba3Mg1.5Sc4(PO4)6(OH)3·4H2O, is a new Ba-Sc phosphate from the Kovdor phoscorite-carbonatite complex (Kola Peninsula, Russia). It is orthorhombic, Pnma,...     

Mid-Miocene (post 12 Ma) displacement along the central Karakoram fault zone in the Nubra Valley,Ladakh, India from spot LA-ICPMS U/Pb zircon ages of granites

The Karakoram fault zone is a prominent right lateral fault that connects the frontal thrust of the North Pamir with the Indus suture zone near Mount Kailas. Its nature and age of initiation is controversial. In the Nubra valley, Ladakh, India, a Karakoram range granite is thrust over Cretaceous magmatic arc rocks and this thrust is cut by a western strand of the Karakoram fault zone. Three different lithologies from this granite gave weighted mean zircon U/Pb ages of 12.92±0.77 Ma, 12.41±0.43 Ma, and 11.72±0.31 Ma. The ages indicate a relatively short intrusive history of about 1 Ma for the phases: the geochemistry is practically identical to the Pangong leucogranites in the same tectonic block. The Karakoram fault zone in this area is thus less than ~12 Ma old which supports a post middle Miocene (Serravallian) age of Karakoram fault initiation in this area.     

U–Pb SHRIMP zircon geochronology and T–t–d history of the Kampa Dome, southern Tibet

Structural, petrographic and geochronologic studies of the Kampa Dome provide insights into the tectonothermal evolution of orogenic crust exposed in the North Himalayan gneiss domes of southern Tibet. U–Pb ion microprobe dating of zircons from granite gneiss exposed at the deepest levels within the dome yields concordia ²⁰⁶Pb/²³⁸U age populations of 506 ± 3 Ma and 527 ± 6 Ma, with no evidence of new zircon growth during Himalayan orogenesis. However, the granite contains penetrative deformation fabrics that are also preserved in the overlying Paleozoic strata, implying that the Kampa granite is a Cambrian pluton that was strongly deformed and metamorphosed during Himalayan orogenesis. Zircons from deformed leucogranite sills that cross-cut Paleozoic metasedimentary rocks yield concordant Cambrian ages from oscillatory zoned cores and discordant ages ranging from ca. 491–32 Ma in metamict grains. Since these leucogranites clearly post-date the metasedimentary rocks they intrude, the zircons are interpreted as xenocrysts that are probably derived from the Kampa granite. The Kampa Dome formed via a series of progressive orogenic events including regional ~ N–S contraction and related crustal thickening (D₁), predominately top-to-N ductile shearing and crustal extension (D₂), top-to-N brittle–ductile faulting and related folding on the north limb of the dome, localized top-to-S faulting on the southern limb of the dome, and crustal doming (D₃), and continued N–S contraction, E–W extension and doming (D₄). Structural and geochronologic variability amongst adjacent North Himalayan gneiss domes may reflect changes in the magnitude of crustal exhumation along the North Himalayan antiform, possibly relating to differences in the mid-crustal geometry of the exhuming fault systems.     

Climate change links fate of glaciers and an endemic alpine invertebrate

Climate warming in the mid- to high-latitudes and high-elevation mountainous regions is occurring more rapidly than anywhere else on Earth, causing extensive loss of glaciers and snowpack. However, little is known about the effects of climate change on alpine stream biota, especially invertebrates. Here, we show a strong linkage between regional climate change and the fundamental niche of a rare aquatic invertebrate—the meltwater stonefly Lednia tumana—endemic to Waterton-Glacier International Peace Park, Canada and USA. L. tumana has been petitioned for listing under the U.S. Endangered Species Act due to climate-change-induced glacier loss, yet little is known on specifically how climate impacts may threaten this rare species and many other enigmatic alpine aquatic species worldwide. During 14 years of research, we documented that L. tumana inhabits a narrow distribution, restricted to short sections (~500 m) of cold, alpine streams directly below glaciers, permanent snowfields, and springs. Our simulation models suggest that climate change threatens the potential future distribution of these sensitive habitats and the persistence of L. tumana through the loss of glaciers and snowfields. Mountaintop aquatic invertebrates are ideal early warning indicators of climate warming in mountain ecosystems. Research on alpine invertebrates is urgently needed to avoid extinctions and ecosystem change.     

The use of caesium‐137 to estimate agricultural erosion on steep slopes in a tropical watershed

The estimation of erosion and sediment delivery rates in tropical mountain watersheds is difficult and most of the methods widely used for estimating soil erosion over large areas have serious limitations. The ¹³⁷Cs approach has potential for quantifying soil erosion because it can provide retrospective estimates of long‐term (since 1963) net sediment redistribution relatively quickly. Despite its great potential, ¹³⁷Cs has not yet been used in an extensive, reconnaissance level survey of erosion in complex tropical mountain environments. The objective of this study was to examine the applicability of the ¹³⁷Cs method to estimate erosion on steep tropical agricultural lands (23 to 80% slopes) in the Nizao watershed, a humid, tropical mountain area of the Dominican Republic. In this study we (i) examine the variation of ¹³⁷Cs in ten reference sites—eight coffee groves and two forested sites—and (ii) estimate erosion from 14 cultivated fields. The soil pool of ¹³⁷Cs ranged from to 150 to 192 mBq cm⁻² on reference sites with minimal erosion. Variability among reference sites was less than expected for such complex mountain terrain. The variability within coffee and forested reference (average CV=28%) sites was similar to the variability found on grassland and forested reference sites in the temperate zone. The estimated annual soil loss from 14 sampled fields ranged from 6 to 61 t ha⁻¹ year⁻¹ with an overall mean of 26 t ha⁻¹ year⁻¹. Overall, the soil erosion estimates found using the ¹³⁷Cs method were much lower than those often assumed for such steep tropical hillsides. These erosion estimates account for soil loss since 1963 only and it seems likely that soil losses may have been much higher in earlier decades immediately after initial forest clearing earlier in the 20th century. Copyright © 2000 John Wiley & Sons, Ltd.     

Experimental Measurements of Expected Mass Fraction in a Contaminant Plume

The sudden release of a quantity of gas into the atmospheric boundary layer produces a contaminant cloud. The expected mass fraction function provides a relatively simple measure of the contaminant concentration values found within the cloud and represents the ensemble-averaged fraction of the conserved release mass found at the different contaminant concentration intervals as the cloud evolves. The plume generated by a line source in grid turbulence is used to investigate the expected mass fraction function as it applies to scalar concentration values found on a typical line normal to the plume axis. Simultaneous particle image velocimetry and planar laser induced fluorescence are used to measure velocity and concentration fields, respectively. The measured expected mass fraction functions are observed to be approximately self-similar when concentration values are normalized by the centreline mean concentration. The moments of the expected mass fraction function are observed to be simply related to the centreline moments of the probability density function of scalar concentration. Arguments based on a source fluid, non-source fluid decomposition of the scalar probability density function are used to explain these observations. The results are compared with the theoretical and experimental results established for a line source of scalar in grid turbulence.     

Lichens and the determination of river channel capacity

The identification of channel capacity associated with a particular frequency of peak discharges is necessary for discharge estimation for planning purposes at ungauged sites. Although lichen limits have been suggested to be useful for this purpose, previous studies have not elaborated their hydrological significance. Lichen limits are clearly defined on the sides of rock channels in New England. Australia and they are analyzed in relation to discharge at 6 gauging stations with up to 52 years of continuous record. It is demonstrated that the lowest lichen limit is maintained by peak discharges which occur on average at least once or twice each year. Recurrence intervals based on Annual Series and on Annual Exceedance Series are calculated and for the annual series are fairly consistent for the lowest lichen limit and range from 1·14 to 1·37 years. Lichenometry can be applied to the analysis of river channels in relation to the frequency of peak discharges. By reference to growth curves based upon lichens on Armidale tombstones it is shown that lichenometry may be employed to indicate dates for channel modification due to the removal of blocks and to dam construction and also to date the rock surface between lichen limits. Detailed analysis of the record from gauging stations indicates that where several lichen limits occur in a channel cross section each limit is related to periods when peak discharges exceeded the limits on at least 5 occasions. The lichen-free surfaces were then recolonized by Parmelia spp. and the size of the lichen thalli indicates the time elapsing since these frequent high discharges.     

Geochemistry of polymict ureilite EET83309, and a partially-disruptive impact model for ureilite origin

Abstract— For most elements, polymict ureilite EET83309 shows no significant compositional difference from other ureilites, including ordinary (“monomict”) ureilites. Polymict ureilites appear to be mixtures of a wide variety of ordinary ureilites, with little dilution by “foreign” extra-ureilitic materials. Thus, they apparently were mixed (i.e., the ureilites in general formed) on a very small number of parent bodies. In one respect, polymict ureilites do stand out. Along with the only other polymict ureilite that has been analyzed for REE (Nilpena), EET83309 has much higher concentrations of light-middle REE than most ordinary ureilites. Despite these relative enrichments in LREE, polymict ureilites are nearly devoid of basaltic (Al-rich) material. A basaltic component should have formed along with (and presumably above) the ultramafic ureilites, in any closed-system differentiation of an originally chondritic asteroid. This scarcity of complementary basaltic materials may be an important clue to ureilite origins. We suggest that ureilites originated as paracumulates (mushy, cumulate-like, partial melt residues) deep within a primordially-heated asteroid or asteroids. While still largely molten, the asteroid was severely disrupted, and most of its external basaltic portion was permanently blown away, by impact of a large, C-rich projectile. This partially-disruptive impact tended to permeate the paracumulates with C-rich, noble-gas-rich, and ¹⁶O-rich magma derived mainly from shock-melting of the projectile. After reaccumulation and cooling, the resultant mixtures of cumulus mafic silicates with essentially “foreign” C-matrix became “monomict” ureilites. Further small impacts produced polymict ureilites as components of a newly-developed, basalt-poor megaregolith. The consistently moderate pyroxene/olivine ratios of the ureilites are as expected for partial melt residues, but not for cumulate (sensu stricto) rocks. The final projectile/target mixing ratio tended to be greatest among the more magnesian and pyroxene-rich portions of the paracumulate, because these portions were lowest in density, and thus concentrated toward the upper surface of the paracumulate layer. As a result, ureilites show correlations among C, Δ¹⁷O, and silicate-core mg. This model appears to reconcile many paradoxical aspects of ureilite composition (primitive, near-chondritic, except depleted in basalt, diverse Δ¹⁷O) and petrography (igneous, cumulate-like).